| ID | 34216 |
| FullText URL | |
| Author |
Yoshida, Kenta
Morimoto, Ichiro
Tanaka, Hideo
|
| Abstract | The RhCl3-3H(2)O/i-Pr2NEt-catalyzed [2+2+2] cyclotrimerization of alkynes has been achieved. The reaction can be widely used for various alkynes and provides tri- OF hexa-substituted benzenes regioselectively in high yields. The [2+2+2] cycloaddition of diynes and alkynes is also developed, and it affords benzene derivatives in moderate to high yields. |
| Keywords | Rh/amine catalyst
cyclotrimerization
hexa-substituted benzene
|
| Note | Published with permission from the copyright holder.
This is a author's copy,as published in Tetrahedron , 2008 Vol.64 Issue.24 pp.5800-5807 Publisher URL: http://dx.doi.org/10.1016/j.tet.2008.03.079 Direct access to Thomson Web of Science record Copyright © 2008 by Elsevier Ltd. |
| Published Date | 2008-06-23
|
| Publication Title |
Tetrahedron
|
| Volume | volume64
|
| Issue | issue24
|
| Start Page | 5800
|
| End Page | 5807
|
| Content Type |
Journal Article
|
| language |
English
|
| Refereed |
True
|
| DOI | |
| Web of Science KeyUT | |
| Submission Path | organic_chemistry/5
|
