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JaLCDOI 10.18926/40312
Title Alternative o-PHENANTHROLINE METHOD APPLIED TO THE DETERMINATION OF IRON IN NATURAL WATERS
FullText URL pitsr_017_001_007.pdf
Author Tanaka, Shigeo|
Abstract The o-phenanthroline method was tested as to its applicability to the separate determination of iron in natural water: ionic ferrous iron, reducible iron, snd colloidally dispersed iron. In connection with this, the results of the following experiments are given in this paper. 1. Determination of the absorption curve of o-phenanthroline ferrous complex. (Figure 1.) 2. Construction of the calibration curve for a Purfrich's photometer with filter S 50, 15 cm cuvettes. (Figure 2.) 3. Examination of the effects of coexisting anions on the determination of iron by the method of three way layout. (Table 1., Table 2.) 4. Trial determinations of iron in three different states in solution. (Table 3., Table 4. ) 5. Test of the applicability of this method to the determination of ionic ferrous iron and reducible iron in thermal water. (Table 5., Table 6.) From the above, it was revealed that ionic ferrous iron and reducible iron in natural water are separately determinable with sufficient accuracy by the o-phenanthroline method, and that ionic iron and colloidally dispersed iron are also separately determinable, when the dispersed iron is present in amount more than 1.3% of the total iron.
Publication Title 岡山大学温泉研究所報告
Published Date 1956-03
Volume volume17
Start Page 1
End Page 7
ISSN 0369-7142
Related Url http://ousar.lib.okayama-u.ac.jp/metadata/40311
language Japanese
File Version publisher
NAID 120002462897
JaLCDOI 10.18926/40272
Title Alternative THE CHANGE IN CONCENTRATION OF FERROUS IRON AND REDUCIBLE IRON, DISSOLVED IN SPRING WATER AT MISASA HOT SPRINGS, JAPAN, DURING PRESERVATION OF THE WATER SAMPLE IN A SEALED BOTTLE
FullText URL pitsr_020_048_054.pdf
Author Tanaka, Shigeo|
Abstract The two sprigns called "Tanaka-no-Yu" and "Hisui-no-Yu" at Misasa Hot Springs, japan (Fig. 1), suitable for sampling the unpolluted water, the locations of which, are shown in Fig. 2, were chosen for this study. The o-phenanthroline method, details of which were discussed in the previous report by the author (Repts. Balneol. Lab. Okyama Univ., 17, 1, (1956)) was used for the determination of ferrous iron, ferrous iron + reducible iron, and ferrous iron + reducible iron + colloidally dispersed iron (to be referred to as "total irons" in this report). For comparison, the change in concentratin of iron dissolved in distilled water during preservation in a sealed bottle was observed, and the results obtained for the solutions with the pH values of 5.4 and 5.8 are illustrated in Fig.3 and Fig.5, rspectively. Both ferrous and reducible iron disappear within 5 minutes, when the pH of the solution is 6.4. The hydrogen ion concentration was thus seen to give a sensitive effects on the speed of diminution of ferrous and reducible iron dissolved in the distilled water. It should be noticed that no appreciable diminution was observed during the period from 60 min. to 120 min,. It is probable that the diminution of total iron is caused by the adsorption of colloidal iron hydroxides on the wall of glass bottle. The effects of charged anion (SO(4)(--)) on the change in concentration of iron during preservation was also investigated, but no appreciable effect was found. (Fig. 5 and Fig. 6). Fig.7, Fig.8, and Fig.9 show the change in concentration of iron during preservation of the spring water at "Tanaka-no-Yu". The content of iron in the spring water is about 0.3 mg/l, and its pH value is about 7.1. For the first 30 minutes, ferrous iron diminishes rapidly, the slope of the diminution curve being sharp and almost straight. Thereafter the slope becomes gentler, and, after an hour, the slope approaches nearly zero. On the other hand, ferrous iron dissolved in distilled water disappears in a moment at the same pH 7.1. Fig.10, Fig.11, and Fig.12 show the change in concentration of iron during preservation of the spring water at "Hisui-no-Yu". The content of iron in the spring water is about 1.0 mg/l, and its pH value is about 6.4. In this case, the diminution of ferrous iron is not remarkable, and only 20% of the initial quantity diminishes within 2 days. Whereas, in the case of distilled water, the diminution is very rapid at the same pH 6,4, and the ferrous iron disappears completely within 5 minutes. In Fig.13 the speed of diminution of iron in distilled water and that in spring water are compared. The difference here seen may probably be due either to that the ferrous iron in spring water is in a certain complex form not easily oxidizable, or to that the spring water contains some reducing substances.
Publication Title 岡山大学温泉研究所報告
Published Date 1958-01
Volume volume20
Start Page 48
End Page 54
ISSN 0369-7142
language Japanese
File Version publisher
NAID 120002462895
JaLCDOI 10.18926/40271
FullText URL pitsr_020_042_047.pdf
Author Tanaka, Shigeo|
Abstract Differential thermal investigation was made of amorphous hydrous ferric oxides, precipitated on neutralization of ferric chloride solution under different laboratory conditions, ranging from DOC to 85°C in temperature, and from 3 to 12 in pH. Each of the differential thermal curves obtained shows an endothermic peak due to the release of adsorbed water, followed by a exothermic peak due to crystallization of anhydrous ferric oxide to hematite. The temperature corresponding to the exothermic peak varies in the range from 240°C to 460°C accrding to the temperatures and pH values of the solution from which the hydrous ferric oxide is precipitated.
Publication Title 岡山大学温泉研究所報告
Published Date 1958-01
Volume volume20
Start Page 42
End Page 47
ISSN 0369-7142
language English
File Version publisher
NAID 120002462894
JaLCDOI 10.18926/40259
Title Alternative Study of Togo -Matsuzaki Hot Springs, Tottori Prefecture
FullText URL pitsr_023_001_022.pdf
Author Umemoto, Shunji| Harada, Mitsuru| Okabe, Shigeru| Miyakoshi, Junichiro| Sakanoue, Masanobu| Tanaka, Masaya| Mifune Masaaki|
Abstract 1. Layers containing thermal water in this district are thin, and lie at different depths (about 35, 55, and 60 meters) from the ground surface. There are evidences to show that these layers are intimately connected with one another. 2. The authors may suppose the existence of a structurally weak zone, along the line from Matsuzaki to Asozu, within which the issuing spots of thermal springs are located. 3. The head water levels of the thermal springs in this district are closely related with that of Lake Togo. Keeping pace with the variations of the water levels of Lake Togo and of artesian wells in its vicinity, the rate of flow of thermal springs vary; and the correlation between these variations is apparent. 4. The pumping suction of thermal water at one spring affects the flow of water at other springs within distances of 150 to 200 meters therefrom, though the direct sources of thermal water supply for the latter springs may be different from that of the former. 5. The spring water in this district is considered to be a mixture of hot water, containing sodium, calcium, chloride, and sulfate ions, and cold water, containing bicarbonate ion. The diversity of chemical constitutions of different spring waters is explained as due to the difference in proportion in which the hot and cold waters are mixed.
Publication Title 岡山大学温泉研究所報告
Published Date 1958-10
Volume volume23
Start Page 1
End Page 22
ISSN 0369-7142
Related Url http://ousar.lib.okayama-u.ac.jp/metadata/40258
language Japanese
File Version publisher
NAID 120002462891
JaLCDOI 10.18926/40162
Title Alternative Isotopic study of Hot Springs in Japan, I Techniques for oxygen isotopic analysis of spring water
FullText URL pitsr_040_033_040.pdf
Author Matsubaya, Osamu| Sakai, Hitoshi| Tanaka, Hinako| Uemura, Tazue|
Abstract The CO(2)-H(2)O isotopic equilibration technique was studied for the routine analyses of the oxygen isotopic ratios of hot spring water. A reaction vessel containing 2 ml of water and 0.16 m mole of tank CO(2) was shaken for 18 hrs. in a constant-temperature bath at 25.0℃ (Figs. 1, 2, and 3), and the CO(2) was analyzed for the oxygen isotopic ratio by a MCKINNEY type mass spectrometer. Several aliquots of 1, 2 and 5 ml from a same water were each analyzed three times by successive equilibration (Table 1). The observed values differ depending on the volume of water but the corrected values by equation (6) indicate excellent agreement, implying the whole processes to be well controlled. The reproducibility of the isotopic analyses is better than ± 0.1‰ (Table 2) in most cases, and the accuracy would not be worse than ± 0.2‰ as demonstrated by the interlaboratory comparison of some standard samples (Table 3). Oxygen isotopic ratios of water from more than 70 hot springs in Japan are presented (Table 5). Although the results will be discussed in the following issues of this series of paper, most hot spring water have the δ(18)O values similar to those of meteoric waters in Japan. However, spring water from Arima Hot Springs, Hyogo-Pref., which has been known by its abnormally high chloride and low sulfate concentrations is of an exceptionally high δ(18)O value.
Publication Title 岡山大学温泉研究所報告
Published Date 1971-03-26
Volume volume40
Start Page 33
End Page 40
ISSN 0369-7142
language Japanese
File Version publisher
NAID 120002398154
Author Tanaka, Masamichi|
Published Date 2010-06-30
Publication Title
Content Type Thesis or Dissertation
JaLCDOI 10.18926/bgeou/40070
Title Alternative Physics Education for Gymnasium in the Swiss Gernlan Zone, Canton of Bern
FullText URL bgeou_144_093_104.pdf
Author Tanaka, Kenji|
Abstract スイス―ドイツ語圏ベルン邦―のギムナジウム(通算呼称で第9~12学年)における物理教育の現状を,いわば学校教育法,同施行規則,学習指導要領などから,明らかにした。ギムナジウムにおける物理教育の教科の種類や性格(目標)などは,そもそも大枠では,学校調整に関する邦間の協定(学習指導要領の大綱)に従っていること,一方,具体的な授業時間数や内容からは,第10学年と第11学年で分岐するが,最低でも3年間,過授業時間数合計で6時間,学ばれること,物理の3教科(基礎,重点,補充教科)の違いは,履修学年,授業時間数,目標だけでなく,最後の学習内容,現代物理の範囲と程度,その他の分野という内容の違いに,現れていることを明らかにした。
Keywords スイス連邦 ドイツ語圏 ベルン邦 ギムナジウム 物理教育
Publication Title 岡山大学大学院教育学研究科研究集録
Published Date 2010-06-25
Volume volume144
Start Page 93
End Page 104
ISSN 1883-2423
language Japanese
File Version publisher
NAID 120002314158
Author Hiramatsu, Yuji|
Published Date 2010-08-02
Publication Title 岡山医学会雑誌
Volume volume122
Issue issue2
Content Type Article
Author Nagasaka, Takeshi| Tanaka, Noriaki| Sun, Dong-Sheng| Naomoto, Yoshio| Mastubara, Nagahide| Yagi, Takahito| Fujiwara, Toshiyoshi|
Published Date 2010-08-02
Publication Title 岡山医学会雑誌
Volume volume122
Issue issue2
Content Type Journal Article
JaLCDOI 10.18926/AMO/40014
FullText URL fulltext.pdf
Author Sugimoto, Yoshihisa| Ito, Yasuo| Tomioka, Masao| Shimokawa, Tetsuya| Shiozaki, Yasuyuki| Mazaki, Tetsuro| Tanaka, Masato|
Abstract Correct screw placement is especially difficult in the upper thoracic vertebrae. At the cervicothoracic junction (C7-T2), problems can arise because of the narrowness of the pedicle and the difficulty of using a lateral image intensifier there. Other upper thoracic vertebrae (T3-6) pose a problem for screw insertion also because of the narrower pedicle. We inserted 154 pedicle screws into 78 vertebrae (C7 to T6) in 38 patients. Screws were placed using intraoperative data acquisition by an isocentric C-arm fluoroscope (Siremobile Iso-C3D) and computer navigation. Out of 90 pedicle screws inserted into 45 vertebrae between C7 and T2, 87 of the 90 (96.7%) screws were classified as grade 1 (no perforation). Of 64 pedicle screws inserted into 33 vertebrae between T3 and T6, 61 of 64 (95.3%) screws were classified as grade 1. In this study, we reduced pedicle screw misplacement at the level of the C7 and upper thoracic (T1-6) vertebrae using the three-dimensional fluoroscopy navigation system.
Keywords Iso-C3D three-dimensional fluoroscopy navigation upper thoracic pedicle screw
Amo Type Original Article
Publication Title Acta Medica Okayama
Published Date 2010-06
Volume volume64
Issue issue3
Publisher Okayama University Medical School
Start Page 209
End Page 212
ISSN 0386-300X
NCID AA00508441
Content Type Journal Article
language English
Copyright Holders Okayama University Medical School
File Version publisher
Refereed True
PubMed ID 20596133
Web of Science KeyUT 000279094300008
Author Tanaka, Hideki| Koga, Kenichiro|
Published Date 2005-09-01
Publication Title Journal of Chemical Physics
Volume volume123
Issue issue9
Content Type Journal Article
Author Koga, Kenichiro| Tanaka, Hideki|
Published Date 2006-04-07
Publication Title Journal of Chemical Physics
Volume volume124
Issue issue13
Content Type Journal Article
Author Koga, Kenichiro| Tanaka, Hideki|
Published Date 2005-03-08
Publication Title Journal of Chemical Physics
Volume volume122
Issue issue10
Content Type Journal Article
Author Hamada, Yoshinobu| Koga, Kenichiro| Tanaka, Hideki|
Published Date 2007-08-28
Publication Title Journal of Chemical Physics
Volume volume127
Issue issue8
Content Type Journal Article
Author Katsumasa, Keisuke| Koga, Kenichiro| Tanaka, Hideki|
Published Date 2007-07-28
Publication Title Journal of Chemical Physics
Volume volume127
Issue issue4
Content Type Journal Article
Author Koyama, Yuji| Tanaka, Hideki| Koga, Kenichiro|
Published Date 2005-02-15
Publication Title Journal of Chemical Physics
Volume volume122
Issue issue7
Content Type Journal Article
Author Tanaka, Hideki| Nakatsuka, Takeharu| Koga, Kenichiro|
Published Date 2004-09-15
Publication Title Journal of Chemical Physics
Volume volume121
Issue issue11
Content Type Journal Article
Author Ishikawa, Kazuhiro| Tanaka, Hiroshi| Tanaka, Katsumi|
Published Date 2002-01
Publication Title Mathematical Journal of Okayama University
Volume volume44
Issue issue1
Content Type Journal Article
JaLCDOI 10.18926/mjou/33123
JaLCDOI 10.18926/AMO/32889
FullText URL fulltext.pdf
Author Nakanishi, Kazuo| Tanaka, Masato| Sugimoto, Yoshihisa| Ozaki, Toshifumi|
Abstract

We performed fixation using laminar screws in 2 patients in whom lateral mass screws, pedicle screws or transarticular screws could not be inserted. One was a 56-year-old woman who had anterior atlantoaxial subluxation (AAS). When a guide wire was inserted using an imaging guide, the hole bled massively. We thought the re-insertion of a guide wire or screw would thus increase the risk of vascular injury, so we used laminar screws. The other case was an 18-year-old man who had a hangman fracture. Preoperative magnetic resonance angiography showed occlusion of the left vertebral artery. A laminar screw was inserted into the patent side (i.e., the right side of C2). Cervical pedicle screws are the most biomechanically stable screws. However, their use carries a high risk of neurovascular complications during screw insertion, because the cervical pedicle is small and is adjacent laterally to the vertebral artery, medially to the spinal cord, and vertically to the nerve roots. Lateral mass screws are also reported to involve a risk of neurovascular injuries. The laminar screw method was thus thought to be useful, since arterial injuries could thus be avoided and it could also be used as a salvage modality for the previous misinsertion.

Keywords laminar screw neurovascular complications lateral mass screw pedicle screw transarticular
Amo Type Case Report
Publication Title Acta Medica Okayama
Published Date 2007-04
Volume volume61
Issue issue2
Publisher Okayama University Medical School
Start Page 115
End Page 119
ISSN 0386-300X
NCID AA00508441
Content Type Journal Article
language English
File Version publisher
Refereed True
PubMed ID 17471313
Web of Science KeyUT 000245875600010
JaLCDOI 10.18926/AMO/31849
FullText URL fulltext.pdf
Author Tanaka, Masato| Nakahara, Shinnosuke| Ito, Yasuo| Kunisada, Toshiyuki| Misawa, Haruo| Koshimune, Koichiro| Ozaki, Toshifumi|
Abstract

Surgical treatment of metastatic spinal cord compression is controversial. The purpose of this study was to investigate the effectiveness of our current surgical treatments and the use of spinal instrumentation. In this retrospective study covering the years between 1990 and 2006, 100 patients with spinal metastases which were secondary to various cancers underwent posterior and/or anterior decompression with spinal stabilization for the purposes of reduction of pain, and/or to help correct or improve neurological deficits. The group was made up of 60 men and 40 women whose ages ranged from 16 to 83 years (average of 60 years), and the average follow-up period was 14 months. The effect of treatment upon pain relief and neural deficits was assessed, and the cumulative survival rate was calculated by the Kaplan-Meier method. The average surgical time was 185min. This was calculated based on the following times, listed here with the surgery type:178min for posterior surgery;245min for anterior surgery;465 min for combined surgery;and 475min for total en bloc spondylectomy. Average blood loss during surgery was 1,630 ml for posterior surgery, 1,760 ml for anterior surgery, 1,930 ml for combined surgery, and 3,640 ml for total en bloc spondylectomy. Preoperative pain and paralysis were improved by 88% and 53%, respectively. In regards to surgical complications, postoperative epidural hematoma was observed in 2 patients, and instrumentation-related infection was observed in 1. Only 2 patients died within 2 months of surgery. In conclusion, posterior and/or anterior decompression with spinal stabilization is a safe and effective treatment for patients with spinal metastases, and can improve their quality of life.

Keywords spinal metastasis spinal surgery instrumentation
Amo Type Original Article
Publication Title Acta Medica Okayama
Published Date 2009-06
Volume volume63
Issue issue3
Publisher Okayama University Medical School
Start Page 145
End Page 150
ISSN 0386-300X
NCID AA00508441
Content Type Journal Article
language English
File Version publisher
Refereed True
PubMed ID 19571901
Web of Science KeyUT 000267388200004