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ID 57801
FullText URL
Author
Niwa, Yutaro Graduate School of Natural Science and Technology, Okayama University
Miyake, Mayu Graduate School of Natural Science and Technology, Okayama University
Hayakawa, Ichiro Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
Sakakura, Akira Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
Abstract
A catalytic enantioselective Hosomi–Sakurai reaction of α-ketoesters has been developed. A copper(II) complex with a chiral bis(oxazoline) ligand bearing methanesulfonamide groups shows excellent catalytic activity to give α,α-disubstituted α-hydroxyesters in high yields with high enantioselectivities. This is the first successful method for the catalytic enantioselective 1,2-addition of α-ketoesters with allylic silanes.
Published Date
2019-04-07
Publication Title
Chemical Communications
Volume
volume55
Issue
issue27
Publisher
Royal Society of Chemistry
Start Page
3923
End Page
3926
ISSN
1359-7345
NCID
AA11071130
Content Type
Journal Article
language
英語
OAI-PMH Set
岡山大学
File Version
author
PubMed ID
DOI
Web of Science KeyUT
Related Url
isVersionOf https://doi.org/10.1039/c9cc01159e
License
https://creativecommons.org/licenses/by-nc-nd/4.0/
Funder Name
Japan Society for the Promotion of Science
助成番号
18K05123