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ID 57801
フルテキストURL
著者
Niwa, Yutaro Graduate School of Natural Science and Technology, Okayama University
Miyake, Mayu Graduate School of Natural Science and Technology, Okayama University
Hayakawa, Ichiro Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
Sakakura, Akira Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
抄録
A catalytic enantioselective Hosomi–Sakurai reaction of α-ketoesters has been developed. A copper(II) complex with a chiral bis(oxazoline) ligand bearing methanesulfonamide groups shows excellent catalytic activity to give α,α-disubstituted α-hydroxyesters in high yields with high enantioselectivities. This is the first successful method for the catalytic enantioselective 1,2-addition of α-ketoesters with allylic silanes.
発行日
2019-04-07
出版物タイトル
Chemical Communications
55巻
27号
出版者
Royal Society of Chemistry
開始ページ
3923
終了ページ
3926
ISSN
1359-7345
NCID
AA11071130
資料タイプ
学術雑誌論文
言語
English
OAI-PMH Set
岡山大学
論文のバージョン
author
PubMed ID
DOI
Web of Science KeyUT
関連URL
isVersionOf https://doi.org/10.1039/c9cc01159e
ライセンス
https://creativecommons.org/licenses/by-nc-nd/4.0/
助成機関名
日本学術振興会
助成番号
18K05123