ID | 65021 |
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Author |
Takahashi, Masakuni
Graduate School of Natural Science and Technology, Okayama University
Sakuma, Ryo
Graduate School of Natural Science and Technology, Okayama University
Hashimoto, Hideki
Graduate School of Natural Science and Technology, Okayama University
Kaken ID
publons
Fujii, Tatsuo
Graduate School of Natural Science and Technology, Okayama University
Kaken ID
publons
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Takada, Jun
Graduate School of Natural Science and Technology, Okayama University
Kaken ID
publons
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Abstract | Recently, Fe2O3 has been considered as an alternative anode material for lithium-ion batteries (LIBs) owing to its high theoretical capacity (approximately 1000 mA h g-1), low cost, and nontoxicity. However, its rate performance remains poor relative to that of the conventional graphite anode. In this study, Fe2O3-based anodes were prepared through the annealing of biogenous Fe2O3 (L-BIOX) samples produced by an aquatic Fe-oxidizing bacterium. The effect of the annealing temperature on the performance of the synthesized Fe2O3-based material as the anode of an LIB was investigated. Electrochemical measurements revealed that the annealed L-BIOX samples at 300-700 degrees C exhibited higher rate performances than the unannealed material. Particularly, the sample annealed at 700 degrees C exhibited the highest capacity among the synthesized materials and showed a higher performance than the previously reported Fe2O3-based anodes. It exhibited a capacity of 923 mA h g-1 even at a high current density of 2 A g-1. After annealing at 700 degrees C and discharging, the synthesized biogenous material had a uniform nanocomposite structure composed of alpha-Fe2O3 nanoparticles dispersed in an amorphous matrix of Li-Si-P oxide. To form this uniform nanostructure, the solid-state diffusion resistance of the Li+ ions in the active material was reduced, which consequently improved the rate performance of the electrode. Therefore, this study provides substantial insights into the development and improvement of the performance of novel Fe2O3-based nanomaterials as the anode of LIBs.
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Note | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Physical Chemistry C, copyright © 2023 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.jpcc.2c08380
This full-text file will be available in Jan. 2024.
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Published Date | 2023-01-24
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Publication Title |
The Journal of Physical Chemistry C
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Volume | volume127
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Issue | issue5
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Publisher | American Chemical Society (ACS)
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Start Page | 2223
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End Page | 2230
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ISSN | 1932-7447
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NCID | AA1217589X
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Content Type |
Journal Article
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language |
English
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OAI-PMH Set |
岡山大学
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Copyright Holders | © 2023 American Chemical Society
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File Version | author
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DOI | |
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Related Url | isVersionOf https://doi.org/10.1021/acs.jpcc.2c08380
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