| ID | 66230 |
| FullText URL | |
| Author |
Sato, Eisuke
Division of Applied Chemistry Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
Fujii, Mayu
Division of Applied Chemistry Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
Mitsudo, Koichi
Division of Applied Chemistry Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
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Suga, Seiji
Division of Applied Chemistry Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
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| Abstract | Alkynylation of aldehydes initiated by cathodic reduction was performed. The cathodic alkynylation required only a semi-catalytic amount of electricity to consume the starting material completely. Cyclic voltammetry and some control experiments suggest that the electron-generated base derived from the cathodic reduction of benzaldehyde promotes alkynylation.
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| Keywords | Alkynylation
Catalytic electrolysis
Cathodic reduction
Electrochemical synthesis
Trimethylsilylacetylene
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| Published Date | 2023-12-12
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| Publication Title |
ChemElectroChem
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| Volume | volume11
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| Issue | issue1
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| Publisher | Wiley
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| Start Page | e202300499
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| ISSN | 2196-0216
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| Content Type |
Journal Article
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| language |
English
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| OAI-PMH Set |
岡山大学
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| Copyright Holders | © 2023 The Authors.
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| File Version | publisher
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| DOI | |
| Web of Science KeyUT | |
| Related Url | isVersionOf https://doi.org/10.1002/celc.202300499
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| License | https://creativecommons.org/licenses/by/4.0/
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| Citation | E. Sato, M. Fujii, K. Mitsudo, S. Suga, ChemElectroChem 2024, 11, e202300499. https://doi.org/10.1002/celc.202300499
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| Funder Name |
Japan Society for the Promotion of Science
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| 助成番号 | JP23K13748
JP22H02122
JP22K05115
21A204
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