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ID 66230
フルテキストURL
fulltext.pdf 3.47 MB
著者
Sato, Eisuke Division of Applied Chemistry Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
Fujii, Mayu Division of Applied Chemistry Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
Mitsudo, Koichi Division of Applied Chemistry Graduate School of Environmental, Life, Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
Suga, Seiji Division of Applied Chemistry Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
抄録
Alkynylation of aldehydes initiated by cathodic reduction was performed. The cathodic alkynylation required only a semi-catalytic amount of electricity to consume the starting material completely. Cyclic voltammetry and some control experiments suggest that the electron-generated base derived from the cathodic reduction of benzaldehyde promotes alkynylation.
キーワード
Alkynylation
Catalytic electrolysis
Cathodic reduction
Electrochemical synthesis
Trimethylsilylacetylene
発行日
2023-12-12
出版物タイトル
ChemElectroChem
11巻
1号
出版者
Wiley
開始ページ
e202300499
ISSN
2196-0216
資料タイプ
学術雑誌論文
言語
英語
OAI-PMH Set
岡山大学
著作権者
© 2023 The Authors.
論文のバージョン
publisher
DOI
Web of Science KeyUT
関連URL
isVersionOf https://doi.org/10.1002/celc.202300499
ライセンス
https://creativecommons.org/licenses/by/4.0/
Citation
E. Sato, M. Fujii, K. Mitsudo, S. Suga, ChemElectroChem 2024, 11, e202300499. https://doi.org/10.1002/celc.202300499
助成機関名
Japan Society for the Promotion of Science
助成番号
JP23K13748
JP22H02122
JP22K05115
21A204