ID | 61460 |
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Author |
Kataoka, Noriyuki
Graduate School of Natural Science and Technology, Okayama University
ORCID
Tanaka, Masashi
Graduate School of Engineering, Kyushu Institute of Technology
Hosoda, Wataru
Graduate School of Natural Science and Technology, Okayama University
Taniguchi, Takumi
Graduate School of Natural Science and Technology, Okayama University
Fujimori, Shin-ichi
Materials Sciences Research Center, Japan Atomic Energy Agency
Wakita, Takanori
Graduate School of Natural Science and Technology, Okayama University
Kaken ID
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Muraoka, Yuji
Graduate School of Natural Science and Technology, Okayama University
Kaken ID
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Yokoya, Takayoshi
Graduate School of Natural Science and Technology, Okayama University
ORCID
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Abstract | We have performed soft x-ray spectroscopy in order to study the photoirradiation time dependence of the valence band structure and chemical states of layered transition metal nitride chloride TiNCl. Under the soft x-ray irradiation, the intensities of the states near the Fermi level (EF) and the Ti3+ component increased, while the Cl 2p intensity decreased. Ti 2p–3d resonance photoemission spectroscopy confirmed a distinctive Fermi edge with Ti 3d character. These results indicate the photo-induced metallization originates from deintercalation due to Cl desorption, and thus provide a new carrier doping method that controls the conducting properties of TiNCl.
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Note | This fulltext is available in Oct. 2021.
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Published Date | 2020-10-16
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Publication Title |
Journal of Physics: Condensed Matter
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Volume | volume33
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Issue | issue3
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Publisher | IOP Publishing
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Start Page | 035501
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ISSN | 0953-8984
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NCID | AA10672168
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Content Type |
Journal Article
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language |
English
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OAI-PMH Set |
岡山大学
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File Version | author
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PubMed ID | |
DOI | |
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Related Url | isVersionOf https://doi.org/10.1088/1361-648X/abbbc3
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Funder Name |
Ministry of Education, Culture, Sports, Science and Technology
Japan Society for the Promotion of Science
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助成番号 | JP 18KK0076
A-19-AE-0019
2019A-E19
JP18K04707
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