ID | 46985 |
FullText URL | |
Author |
Nakahara, Takahiro
Yu, Peng
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Abstract | Treatment of aromatic aldimines with terminal alkenes in the presence of a rhenium catalyst, [HRe(CO)(4)](n), gives 2-alkenylbenzylamines in good to excellent yields. This reaction proceeds via the insertion of the alkene into a C-H bond at the ortho-position of the imino group of the aromatic aldimine followed by sequential beta-hydride elimination from the formed alkyl rhenium intermediate and then by hydrogenation of the imino group of the aldimine.
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Keywords | Rhenium
Insertion
Hydrogen transfer
Aldimine
Alkene
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Published Date | 2011-01-01
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Publication Title |
Journal of Organometallic Chemistry
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Volume | volume696
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Issue | issue1
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Publisher | Elsevier Science SA.
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Start Page | 348
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End Page | 351
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ISSN | 0022-328X
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NCID | AA00704122
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Content Type |
Journal Article
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language |
English
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OAI-PMH Set |
岡山大学
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Copyright Holders | © 2011 Elsevier B.V. All rights reserved.
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File Version | author
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DOI | |
Web of Science KeyUT |