ID | 46985 |
フルテキストURL | |
著者 |
Kuninobu, Yoichiro
Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
Kaken ID
publons
researchmap
Nakahara, Takahiro
Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
Yu, Peng
Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
Takai, Kazuhiko
Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
ORCID
Kaken ID
publons
researchmap
|
抄録 | Treatment of aromatic aldimines with terminal alkenes in the presence of a rhenium catalyst, [HRe(CO)(4)](n), gives 2-alkenylbenzylamines in good to excellent yields. This reaction proceeds via the insertion of the alkene into a C-H bond at the ortho-position of the imino group of the aromatic aldimine followed by sequential beta-hydride elimination from the formed alkyl rhenium intermediate and then by hydrogenation of the imino group of the aldimine.
|
キーワード | Rhenium
Insertion
Hydrogen transfer
Aldimine
Alkene
|
発行日 | 2011-01-01
|
出版物タイトル |
Journal of Organometallic Chemistry
|
巻 | 696巻
|
号 | 1号
|
出版者 | Elsevier Science SA.
|
開始ページ | 348
|
終了ページ | 351
|
ISSN | 0022-328X
|
NCID | AA00704122
|
資料タイプ |
学術雑誌論文
|
言語 |
英語
|
OAI-PMH Set |
岡山大学
|
著作権者 | © 2011 Elsevier B.V. All rights reserved.
|
論文のバージョン | author
|
DOI | |
Web of Science KeyUT |