ID | 67490 |
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Author |
Mitsudo, Koichi
Division of Applied Chemistry, Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
ORCID
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Osaki, Atsushi
Division of Applied Chemistry, Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
Inoue, Haruka
Division of Applied Chemistry, Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
Sato, Eisuke
Division of Applied Chemistry, Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
Shida, Naoki
Graduate School of Engineering Science and Advanced Chemical Energy Research Center, Yokohama National University
Atobe, Mahito
Graduate School of Engineering Science and Advanced Chemical Energy Research Center, Yokohama National University
Suga, Seiji
Division of Applied Chemistry, Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
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Abstract | An electrocatalytic hydrogenation of cyanoarenes, nitroarenes, quinolines, and pyridines using a proton-exchange membrane (PEM) reactor was developed. Cyanoarenes were then reduced to the corresponding benzylamines at room temperature in the presence of ethyl phosphate. The reduction of nitroarenes proceeded at room temperature, and a variety of anilines were obtained. The quinoline reduction was efficiently promoted by adding a catalytic amount of p-toluenesulfonic acid (PTSA) or pyridinium p-toluenesulfonate (PPTS). Pyridine was also reduced to piperidine in the presence of PTSA.
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Keywords | cyanoarene
nitroarene
PEM reactor
pyridine
quinoline
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Published Date | 2024-07-11
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Publication Title |
Beilstein Journal of Organic Chemistry
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Volume | volume20
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Publisher | Beilstein-Institut
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Start Page | 1560
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End Page | 1571
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ISSN | 1860-5397
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Content Type |
Journal Article
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language |
English
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OAI-PMH Set |
岡山大学
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Copyright Holders | © 2024 Mitsudo et al.
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File Version | publisher
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PubMed ID | |
DOI | |
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Related Url | isVersionOf https://doi.org/10.3762/bjoc.20.139
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License | https://creativecommons.org/licenses/by/4.0
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Citation | Mitsudo, K.; Osaki, A.; Inoue, H.; Sato, E.; Shida, N.; Atobe, M.; Suga, S. Beilstein J. Org. Chem. 2024, 20, 1560–1571. doi:10.3762/bjoc.20.139
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Funder Name |
Japan Science and Technology Agency
Japan Society for the Promotion of Science
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助成番号 | JP65R1204400
JP22H02122
JP23K17917
JP22K05115
JP21H05214
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