| ID | 34210 |
| FullText URL | |
| Author |
Kawafuchi, Hiroyuki
|
| Abstract | Sodium 2,2,6,6-tetramethylpiperidine-N-oxide (TEMPO−Na+), generated by reduction of TEMPO· with sodium naphthalenide in THF, reacted with alkyl halides or acyl halides to produce O-alkylated or acylated TEMPOs, which were in turn oxidized with mCPBA or reduced with DIBAL-H to afford the corresponding aldehydes, thus accomplishing a new protocol for the halides-carbonyls conversion. |
| Keywords | TEMPO and compounds
Oxidation
Reduction
mCPBA
DIBAL-H
Aldehyde
|
| Note | Digital Object Identifer: 10.1016/j.tet.2004.09.067
Published with permission from the copyright holder. This is the author's copy, as published in Tetrahedron, 13 December 2004, Volume 60, Issue 51, Pages 11969-11975. Publisher URL: http://dx.doi.org/10.1016/j.tet.2004.09.067 Direct access to Thomson Web of Science record Copyright © 2004 Elsevier. Ltd. All rights reserved. |
| Published Date | 2004-12
|
| Publication Title |
Tetrahedron
|
| Volume | volume60
|
| Issue | issue51
|
| Start Page | 11969
|
| End Page | 11975
|
| Content Type |
Journal Article
|
| language |
English
|
| Refereed |
True
|
| DOI | |
| Web of Science KeyUT | |
| Submission Path | organic_chemistry/3
|
