| ID | 57801 |
| FullText URL | |
| Author |
Niwa, Yutaro
Graduate School of Natural Science and Technology, Okayama University
Miyake, Mayu
Graduate School of Natural Science and Technology, Okayama University
Hayakawa, Ichiro
Graduate School of Natural Science and Technology, Okayama University
ORCID
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Sakakura, Akira
Graduate School of Natural Science and Technology, Okayama University
ORCID
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publons
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| Abstract | A catalytic enantioselective Hosomi–Sakurai reaction of α-ketoesters has been developed. A copper(II) complex with a chiral bis(oxazoline) ligand bearing methanesulfonamide groups shows excellent catalytic activity to give α,α-disubstituted α-hydroxyesters in high yields with high enantioselectivities. This is the first successful method for the catalytic enantioselective 1,2-addition of α-ketoesters with allylic silanes.
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| Published Date | 2019-04-07
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| Publication Title |
Chemical Communications
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| Volume | volume55
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| Issue | issue27
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| Publisher | Royal Society of Chemistry
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| Start Page | 3923
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| End Page | 3926
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| ISSN | 1359-7345
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| NCID | AA11071130
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| Content Type |
Journal Article
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| language |
English
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| OAI-PMH Set |
岡山大学
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| File Version | author
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| PubMed ID | |
| DOI | |
| Web of Science KeyUT | |
| Related Url | isVersionOf https://doi.org/10.1039/c9cc01159e
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| License | https://creativecommons.org/licenses/by-nc-nd/4.0/
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| Funder Name |
Japan Society for the Promotion of Science
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| 助成番号 | 18K05123
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