| ID | 57490 |
| FullText URL | |
| Author |
Iwasaki, Masayuki
Research Institute for Interdisciplinary Science, Okayama University
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Xu, Jie
Graduate School of Natural Science and Technology, Okayama University
Tani, Yukari
Graduate School of Natural Science and Technology, Okayama University
Fu, Liyan
Graduate School of Natural Science and Technology, Okayama University
Ikemoto, Yuichi
Graduate School of Natural Science and Technology, Okayama University
Ura, Yasuyuki
Department of Chemistry, Biology, and Environmental Science, Faculty of Science, Nara Women’s University
Nishihara, Yasushi
Research Institute for Interdisciplinary Science, Okayama University
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| Abstract | A copper-catalyzed chloroamination of alkenes with chlorotrimethylsilane and N-fluorobenzenesulfonimide has been developed. The reactions were complete within 1 h at 120 degrees C by means of microwave heating. The present chloroamination proceeds with a perfect regioselectivity and is compatible with various functional groups. The preliminary mechanistic investigation revealed that the reaction involves a radical process. The utility of the present method was demonstrated by scalable, operationally simple and safe system.
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| Keywords | Chloroamination
Copper catalyst
Alkenes
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| Published Date | 2019-01-10
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| Publication Title |
Chemistry Letters
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| Volume | volume48
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| Issue | issue3
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| Publisher | Chemical Society of Japan
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| Start Page | 281
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| End Page | 283
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| ISSN | 03667022
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| NCID | AA00603318
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| Content Type |
Journal Article
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| language |
English
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| OAI-PMH Set |
岡山大学
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| File Version | author
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| DOI | |
| Web of Science KeyUT | |
| Related Url | isVersionOf https://doi.org/10.1246/cl.180937
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| Funder Name |
Japan Society for the Promotion of Science
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| 助成番号 | 16K17901
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