ID | 34210 |
FullText URL | |
Author |
Kawafuchi, Hiroyuki
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Abstract | Sodium 2,2,6,6-tetramethylpiperidine-N-oxide (TEMPO−Na+), generated by reduction of TEMPO· with sodium naphthalenide in THF, reacted with alkyl halides or acyl halides to produce O-alkylated or acylated TEMPOs, which were in turn oxidized with mCPBA or reduced with DIBAL-H to afford the corresponding aldehydes, thus accomplishing a new protocol for the halides-carbonyls conversion. |
Keywords | TEMPO and compounds
Oxidation
Reduction
mCPBA
DIBAL-H
Aldehyde
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Note | Digital Object Identifer: 10.1016/j.tet.2004.09.067
Published with permission from the copyright holder. This is the author's copy, as published in Tetrahedron, 13 December 2004, Volume 60, Issue 51, Pages 11969-11975. Publisher URL: http://dx.doi.org/10.1016/j.tet.2004.09.067 Direct access to Thomson Web of Science record Copyright © 2004 Elsevier. Ltd. All rights reserved. |
Published Date | 2004-12
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Publication Title |
Tetrahedron
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Volume | volume60
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Issue | issue51
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Start Page | 11969
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End Page | 11975
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Content Type |
Journal Article
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language |
English
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Refereed |
True
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DOI | |
Web of Science KeyUT | |
Submission Path | organic_chemistry/3
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