ID | 57749 |
FullText URL | |
Author |
Hoang, Que D.
The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry, Institute for Planetary Materials, Okayama University
Kunihiro, Tak
The Pheasant Memorial Laboratory, Institute for Planetary Materials, Okayama University
Kaken ID
Sakaguchi, Chie
The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry, Institute for Planetary Materials, Okayama University
publons
Yamanaka, Masahiro
The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry, Institute for Planetary Materials, Okayama University
Kitagawa, Hiroshi
The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry, Institute for Planetary Materials, Okayama University
ORCID
publons
researchmap
Nakamura, Eizo
The Pheasant Memorial Laboratory, Institute for Planetary Materials, Okayama University
Kaken ID
publons
researchmap
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Abstract | To precisely determine the abundances of fifty-two elements found within natural water samples, with mass fractions down to fg g(-1) level, we have developed a method which combines freeze-drying pre-concentration (FDC) and isotope dilution internal standardisation (ID-IS). By sublimation of H2O, the sample solution was reduced to < 1/50 of the original volume. To determine element abundance with accuracy better than 10%, we found that for solutions being analysed by mass spectrometry the HNO3 concentration should be > 0.3 mol l(-1) to avoid hydrolysis. Matrix-affected signal suppression was not significant for the solutions with NaCl concentrations lower than 0.2 and 0.1 cg g(-1) for quadrupole ICP-MS and sector field ICP-MS, respectively. The recovery yields of elements after FDC were 97-105%. The detection limits for the sample solutions prepared by FDC were <= 10 pg g(-1), except for Na, K and Ca. Blanks prepared using FDC were at pg-levels, except for eleven elements (Na, Mg, Al, P, Ca, Mn, Fe, Co, Ni, Cu and Zn). The abundances of fifty-two elements in bottled drinking water were determined from five different geological sources with mass fractions ranging from the fg g(-1) to mu g g(-1) level with high accuracy.
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Keywords | pre-concentration
freeze-drying
ID-IS
natural water
drinking water
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Published Date | 2018-10-25
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Publication Title |
Geostandards and Geoanalytical Research
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Volume | volume43
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Issue | issue1
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Publisher | Wiley
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Start Page | 147
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End Page | 161
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ISSN | 1639-4488
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NCID | AA11984494
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Content Type |
Journal Article
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language |
English
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OAI-PMH Set |
岡山大学
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File Version | author
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DOI | |
Web of Science KeyUT | |
Related Url | isVersionOf https://doi.org/10.1111/ggr.12245
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