| ID | 62392 |
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| Author |
Hayakawa, Ichiro
Graduate School of Integrated Basic Sciences, Nihon University, 3-25-40 Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan
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Matsumaru, Naochika
Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-naka, Kita-ku, Okayama 700-8530, Japan
Sakakura, Akira
Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-naka, Kita-ku, Okayama 700-8530, Japan
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| Abstract | The core scaffold of paspaline-type indole-terpenes was synthesized by using the House–Meinwald rearrangement as a key step. Rearrangement of the epoxide methyl group in the precursor with MABR (methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide)) as a Lewis acid proceeded smoothly to construct contiguous asymmetric quaternary carbon centers by a 1,2-chirality transfer.
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| Note | This is an Accepted Manuscript of an article published by American Chemical Society
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| Published Date | 2021-7-7
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| Publication Title |
The Journal of Organic Chemistry
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| Volume | volume86
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| Issue | issue14
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| Publisher | American Chemical Society (ACS)
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| Start Page | 9802
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| End Page | 9810
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| ISSN | 0022-3263
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| NCID | AA00704100
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| Content Type |
Journal Article
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| language |
English
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| OAI-PMH Set |
岡山大学
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| File Version | author
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| Related Url | isVersionOf https://doi.org/10.1021/acs.joc.1c01193
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| Funder Name |
Japan Society for the Promotion of Science
Naito Foundation
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| 助成番号 | 20H02867
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