ID | 57914 |
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Author |
Iwasaki, Masayuki
Research Institute for Interdisciplinary Science, Okayama University
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Nonaka, Kosei
Graduate School of Natural Science and Technology, Okayama University
Zou, Song
Sawanaka, Yuta
Graduate School of Natural Science and Technology, Okayama University
Shinozaki, Takaaki
Graduate School of Natural Science and Technology, Okayama University
Fujii, Tomoya
Graduate School of Natural Science and Technology, Okayama University
Nakajima, Kiyohiko
Graduate School of Natural Science and Technology, Okayama University
Nishihara, Yasushi
Research Institute for Interdisciplinary Science, Okayama University
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Abstract | Copper-catalyzed regioselective aminothiolation of terminal and internal alkenes with N-fluorobenzenesulfonimide and thiols has been developed. The three-component reaction is promoted by the addition of dimethyl sulfide. In addition to aromatic alkenes, aliphatic alkenes are subjected to the reaction, affording various aminothiolation adducts as single regioisomers. The radical process is proposed by preliminary mechanistic studies, involving radical trap and radical clock experiments.
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Published Date | 2019-11-04
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Publication Title |
Journal of Organic Chemistry
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Volume | volume84
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Issue | issue23
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Publisher | American Chemical Society
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Start Page | 15373
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End Page | 15379
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ISSN | 0022-3263
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NCID | AA00704100
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Content Type |
Journal Article
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language |
English
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OAI-PMH Set |
岡山大学
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File Version | author
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Related Url | isVersionOf https://doi.org/10.1021/acs.joc.9b02392
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Citation | J. Org. Chem. 2019, 84, 23, 15373-15379 Publication Date:November 7, 2019 https://doi.org/10.1021/acs.joc.9b02392
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Funder Name |
Japan Society for the Promotion of Science
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助成番号 | 16K17901
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