ID | 11478 |
JaLCDOI | |
Sort Key | 21
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FullText URL | |
Author |
Nakatsu Shogo
Tsuboi, Sadao
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Abstract | Diels-Alder reactions of 5,5,5-trichloro-3-penten-2-one and ethyl 4,4,4-trichloro-2-butenoate with cyclopentadiene in the presence of a chiral Lewis acid gave exo-2-acetyl-endo-3-trichloromethyl-bicyclo[2.2.1]hept-5-ene and exo-2-ethoxycarbonyl-endo-3-trichloromethylbicyclo[2.2.1]hept-5-ene with 40% and 7% e.e., respectively.
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Keywords | asymmetric reaction
Diels-Alder reaction
asymmetric Diels-Alder reaction
chiral Lewis acid
trichloromethy group
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Publication Title |
岡山大学環境理工学部研究報告
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Published Date | 2004-02-27
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Volume | volume9
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Issue | issue1
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Publisher | 岡山大学環境理工学部
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Publisher Alternative | Faculty of Environmental Science and Technology, Okayama University
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Start Page | 163
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End Page | 166
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ISSN | 1341-9099
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NCID | AN10529213
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Content Type |
Departmental Bulletin Paper
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OAI-PMH Set |
岡山大学
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language |
English
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File Version | publisher
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NAID | |
Eprints Journal Name | fest
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