| ID | 34216 |
| フルテキストURL | |
| 著者 |
Yoshida, Kenta
Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University,
Morimoto, Ichiro
Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
Mitsudo, Koichi
Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
ORCID
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Tanaka, Hideo
Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
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| 抄録 | The RhCl3-3H(2)O/i-Pr2NEt-catalyzed [2+2+2] cyclotrimerization of alkynes has been achieved. The reaction can be widely used for various alkynes and provides tri- OF hexa-substituted benzenes regioselectively in high yields. The [2+2+2] cycloaddition of diynes and alkynes is also developed, and it affords benzene derivatives in moderate to high yields. |
| キーワード | Rh/amine catalyst
cyclotrimerization
hexa-substituted benzene
|
| 備考 | Published with permission from the copyright holder.
This is a author's copy,as published in Tetrahedron , 2008 Vol.64 Issue.24 pp.5800-5807 Publisher URL: http://dx.doi.org/10.1016/j.tet.2008.03.079 Direct access to Thomson Web of Science record Copyright © 2008 by Elsevier Ltd. |
| 発行日 | 2008-06-23
|
| 出版物タイトル |
Tetrahedron
|
| 巻 | 64巻
|
| 号 | 24号
|
| 開始ページ | 5800
|
| 終了ページ | 5807
|
| 資料タイプ |
学術雑誌論文
|
| 言語 |
英語
|
| 査読 |
有り
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| DOI | |
| Web of Science KeyUT | |
| Submission Path | organic_chemistry/5
|
