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ID 57242
フルテキストURL
著者
Kunishige, Takahiro Graduate School of Medicine, Dentistry and Pharmaceutical Sciences, Okayama University
Sawada, Daisuke Graduate School of Medicine, Dentistry and Pharmaceutical Sciences, Okayama University Kaken ID researchmap
抄録
A new procedure for the iron-catalyzed synthesis of enamides from ketoximes was developed, and its mechanism was proposed. A unique reduction system, with the concerted use of KI and Na2S2O4, was involved. The reaction exhibited a wide substrate scope and gave good yields in a short reaction time. The procedure is operationally simple and also applicable for the large-scale synthesis.
キーワード
Ketoxime
Enamide synthesis
Iron catalyst
One-electron reduction
備考
This fulltext will be available in May 2021
発行日
2019-06-13
出版物タイトル
Tetrahedron Letters
60巻
24号
出版者
PERGAMON-ELSEVIER SCIENCE
開始ページ
1562
終了ページ
1565
ISSN
00404039
資料タイプ
学術雑誌論文
言語
英語
OAI-PMH Set
岡山大学
論文のバージョン
author
DOI
Web of Science KeyUT
関連URL
isVersionOf https://doi.org/10.1016/j.tetlet.2019.05.006
Citation
Takahiro Kunishige, Daisuke Sawada, Efficient and practical synthesis of N-acetyl enamides from ketoximes by unique iron catalytic system, Tetrahedron Letters, Volume 60, Issue 24, 2019, Pages 1562-1565, ISSN 0040-4039, https://doi.org/10.1016/j.tetlet.2019.05.006.
助成機関名
日本学術振興会
助成番号
17H06173
オープンアクセス(出版社)
非OA
オープンアーカイブ(出版社)
非OpenArchive