Palladium-Catalyzed Regio- and Stereoselective Carbothiolation of Terminal Alkynes with Azolyl Sulfides

Iwasaki, Masayuki; Topolovčan, Nikola; Hu, Hao; Nishimura, Yugo; Gagnot, Glwadys; nakorn, Rungsaeng Na; Yuvacharaskul, Ramida; Nakajima, Kiyohiko; Nishihara, Yasushi

doi:10.1021/acs.orglett.6b00503

Permalink : https://ousar.lib.okayama-u.ac.jp/55377

ID	55377
フルテキストURL	Org_Lett_18_7_1642.pdf 220 KB
著者	Iwasaki, Masayuki Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap Topolovčan, Nikola Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University Hu, Hao Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University Nishimura, Yugo Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University Gagnot, Glwadys Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University nakorn, Rungsaeng Na Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University Yuvacharaskul, Ramida Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University Nakajima, Kiyohiko Department of Chemistry, Aichi University of Education Nishihara, Yasushi Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
抄録	Palladium-catalyzed carbothiolation of terminal alkynes with azolyl sulfides affords various 2-(azolyl)alkenyl sulfides with perfect regio- and stereoselectivities. The present addition reaction proceeded through a direct cleavage of carbon-sulfur bonds in azolyl sulfides. The resulting adducts that are useful intermediates in organic synthesis are further transformed to multisubstituted olefins containing azolyl moieties.
備考	This is an Accepted Manuscript of an article published by American Chemical Society
発行日	2016-03-21
出版物タイトル	Organic Letters
巻	18巻
号	7号
出版者	American Chemical Society
開始ページ	1642
終了ページ	1645
ISSN	1523-7060
NCID	AA11347843
資料タイプ	学術雑誌論文
言語	英語
OAI-PMH Set	岡山大学
著作権者	https://creativecommons.org/licenses/by-nc-nd/4.0/deed.ja
論文のバージョン	author
PubMed ID	26998829
DOI	10.1021/acs.orglett.6b00503
Web of Science KeyUT	000373519600037
関連URL	https://doi.org/10.1021/acs.orglett.6b00503