ID | 57801 |
フルテキストURL | |
著者 |
Niwa, Yutaro
Graduate School of Natural Science and Technology, Okayama University
Miyake, Mayu
Graduate School of Natural Science and Technology, Okayama University
Hayakawa, Ichiro
Graduate School of Natural Science and Technology, Okayama University
ORCID
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Sakakura, Akira
Graduate School of Natural Science and Technology, Okayama University
ORCID
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publons
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抄録 | A catalytic enantioselective Hosomi–Sakurai reaction of α-ketoesters has been developed. A copper(II) complex with a chiral bis(oxazoline) ligand bearing methanesulfonamide groups shows excellent catalytic activity to give α,α-disubstituted α-hydroxyesters in high yields with high enantioselectivities. This is the first successful method for the catalytic enantioselective 1,2-addition of α-ketoesters with allylic silanes.
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発行日 | 2019-04-07
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出版物タイトル |
Chemical Communications
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巻 | 55巻
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号 | 27号
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出版者 | Royal Society of Chemistry
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開始ページ | 3923
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終了ページ | 3926
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ISSN | 1359-7345
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NCID | AA11071130
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資料タイプ |
学術雑誌論文
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言語 |
英語
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OAI-PMH Set |
岡山大学
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論文のバージョン | author
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PubMed ID | |
DOI | |
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関連URL | isVersionOf https://doi.org/10.1039/c9cc01159e
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ライセンス | https://creativecommons.org/licenses/by-nc-nd/4.0/
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助成機関名 |
日本学術振興会
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助成番号 | 18K05123
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