ID | 34180 |
フルテキストURL | |
著者 |
Hayashi, N
Kyoto University
Takehara, Z
Kyoto University
Katagiri, A
Kyoto University
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抄録 | The acid-base properties of the ZnBr[2]-NaBr melts at 623 K were investigated on the basis of the electromotive force measurements of a zinc-zinc concentration cell. The following two chemical equilibria were postulated to describe the acid-base character of the melts ZBnr[2]+Br[-]=ZnBr[3][-] K[1] ZnBr[3][-]+Br[-] =ZnBr[4][2+] K[2] The equilibrium constants K[1] and K[2], were determined to be 5.0×10, and 1.0×10[2], respectively, at 623 K |
キーワード | liquid mixtures
aluminium compounds
sodium compounds
bromine compounds
chemical equilibrium
electrochemical analysis
thermodynamic properties
thermochemistry
electric potential
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備考 | Digital Object Identifer:10.1149/1.2097508
Published with permission from the copyright holder. This is the institute's copy, as published in Journal of the Electrochemical Society, February 1989, Volume 136, Issue 9, Pages 2606-2608. Publisher URL:http://dx.doi.org/10.1149/1.2097508 Copyright © 1989 The Electrochemical Society, Inc. All rights reserved. |
発行日 | 1988-11-30
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出版物タイトル |
Journal of the Electrochemical Society
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巻 | 136巻
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号 | 9号
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開始ページ | 2606
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終了ページ | 2608
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資料タイプ |
学術雑誌論文
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言語 |
英語
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査読 |
有り
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DOI | |
Submission Path | physical_and_theoretical_chemistry/22
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