ID | 33016 |
フルテキストURL | |
著者 |
Komagoe, Keiko
Graduate School of Medicine, Dentistry and Pharmaceutical Sciences, Okayama University
Takeuchi, Hiroaki
Graduate School of Medicine, Dentistry and Pharmaceutical Sciences, Okayama University
Katsu, Takashi
Graduate School of Medicine, Dentistry and Pharmaceutical Sciences, Okayama University
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抄録 | An oxygen electrode was applied to determine hydroxyl radical ((OH)-O-center dot) levels for the first time. The method is based on the determination of (OH)-O-center dot generated by the Fenton reaction using the reaction of (OH)-O-center dot with a scavenger and the resulting radical consuming an oxygen molecule stoichiometrically. Thus, the (OH)-O-center dot-scavenging abilities of antioxidant reagents, as well as the concentration of (OH)-O-center dot, can be determined by the measurement of consumption of dissolved oxygen using an oxygen electrode. A good correlation between the present method and conventional colorimetry was obtained for the estimation of the (OH)-O-center dot-scavenging activities of antioxidants. Furthermore, the results correlated with the (OH)-O-center dot-scavenging rate constants of the reagents evaluated by a "cupric ion reducing antioxidant capacity (CUPRAC)" assay. We applied the present method to estimate the (OH)-O-center dot-scavenging abilities of commercially available alcoholic drinks. |
キーワード | Oxygen electrode
Oxygen consumption
Hydroxyl radical
Hydroxyl radical-scavenger
Antioxidant
Alcoholic drink
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備考 | Published with permission from the copyright holder.
This is published in Sensors and Actuators B-Chemical , 2008 Vol.134 Issue.2 pp.516-520 Publisher URL: http://dx.doi.org/10.1016/j.snb.2008.05.033 Direct access to Thomson Web of Science record (C)2008 by Elsevier B.V. |
発行日 | 2008-05-30
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出版物タイトル |
Sensors and Actuators B-Chemical
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巻 | 134巻
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号 | 2号
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開始ページ | 516
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終了ページ | 520
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資料タイプ |
学術雑誌論文
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言語 |
英語
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査読 |
有り
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DOI | |
Web of Science KeyUT | |
Submission Path | analytical_chemistry/41
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