岡山大学環境理工学部研究報告 ISSN 2187-6940
Published by Faculty of Environmental Science and Technology, Okayama University

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六方晶フォージャサイトの格子空間でのポリチオフェンクラスターの合成

Matsuda, Motohide
Yagi, Katsuhito
Uehara, Hirofumi
Sato, Mitsuo
Abstract
Encapsulation of thiophen and bithiophen in two kinds of hexagonal faujasites (Na-EMT and H-EMT) with various concentration of Cu(2+) ions have been investigated and characterized by means of themoanalytic and spectroscopic methods. From the results, it was found that the progress of polymerization of thiophen and bithiophen in the lattice space depended on Cu(2+) contents, and the encapsulation of thiophen in Na-EMT and H-EMT with Cu(2+) ions yielded polythiophen clusters with electron states of bipolaron. On the other hand, polythiophen clusters synthesized by the encapsulation of bithiophen in H-EMT were found to be mostly polaron states.
Keywords
encapsulation
cluster
host-guest reaction
hexagonal faujasite
polythiophen
ISSN
1341-9099
NCID
AN10529213