start-ver=1.4
cd-journal=joma
no-vol=56
cd-vols=
no-issue=2
article-no=
start-page=1
end-page=16
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2024
dt-pub=20241125
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Why Is Intermediate Organization Necessary?
kn-title=なぜ中間組織が必要なのか
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract= This paper challenges a fundamental question, ‘Why is an intermediate organization necessary?’ Due to transaction costs and market failures on the one hand and the limitations of organizational control mechanisms on the other hand, many‘ intermediate organizations’ are observed in the real world. How can we tackle to explain the governance mechanism considered to be‘ intermediate?’
If we are to discuss such socioeconomic orders, this paper assumes that we should not be able to link micro-level explanations and macro-level ones concerning the third mode of governance mechanisms all at once. We need to stick to the meso-level at fi rst. The theoretical elaboration since Ouchi’s（1980） discussion of clan-type governance and cumulative empirical research on industrial agglomerations have allowed us to construct a more sophisticated theory called community capital.
In effective communities, members are ‘embedded as insiders’ who serve the purpose of the community, share experiences of failures and successes, and find and deepen their common identity. This limited membership is bound by‘ mutual trust to rely on each other’ for‘ distribution of short-term risks.’ In contrast to social norms that need to be abstract enough to be widely shared, the communal norms that are concrete enough to allow the members to understand without hesitation how they should behave in localized contexts are cumulatively cultivated along socializing process. Among the norms, sense of mutual obligation to incur intermittent costs for the whole community is a crucial norm for the sustainable development of the community. However, as a practical matter, membership control, mutual trust and short-term risk allocation may serve the communities in the short run, but they do not guarantee long-term accumulation of shared capital. As a result, the limits of community capital may need to be discussed once again, especially today when market liquidity is increasing, and its failures tend to become more apparent in a variety of areas.
en-copyright=
kn-copyright=
en-aut-name=FujiiDaiji
en-aut-sei=Fujii
en-aut-mei=Daiji
kn-aut-name=藤井大児
kn-aut-sei=藤井
kn-aut-mei=大児
aut-affil-num=1
ORCID=
en-aut-name=OshimaTamako
en-aut-sei=Oshima
en-aut-mei=Tamako
kn-aut-name=大島珠子
kn-aut-sei=大島
kn-aut-mei=珠子
aut-affil-num=2
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学学術研究院ヘルスシステム統合科学学域
affil-num=2
en-affil=
kn-affil=国際医療福祉大学小田原保健医療学部看護学科
en-keyword=中間組織
kn-keyword=中間組織
en-keyword=内部組織の経済学
kn-keyword=内部組織の経済学
en-keyword=産業集積
kn-keyword=産業集積
en-keyword=コミュニティ・キャピタル
kn-keyword=コミュニティ・キャピタル
END
start-ver=1.4
cd-journal=joma
no-vol=10
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2018
dt-pub=20180323
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Newsletter from Course for Prospective Museum Workers, Faculty of Letters, Okayama University
kn-title=学芸員課程 Newsletter 第10号
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=光本順
kn-aut-sei=光本
kn-aut-mei=順
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=三井絵莉子
kn-aut-sei=三井
kn-aut-mei=絵莉子
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=山岡隆太
kn-aut-sei=山岡
kn-aut-mei=隆太
aut-affil-num=3
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=田中陽子
kn-aut-sei=田中
kn-aut-mei=陽子
aut-affil-num=4
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=泉岳志
kn-aut-sei=泉
kn-aut-mei=岳志
aut-affil-num=5
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島友子
kn-aut-sei=大島
kn-aut-mei=友子
aut-affil-num=6
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=片山由奈
kn-aut-sei=片山
kn-aut-mei=由奈
aut-affil-num=7
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=額田千夏
kn-aut-sei=額田
kn-aut-mei=千夏
aut-affil-num=8
ORCID=
affil-num=1
en-affil=
kn-affil=文学部
affil-num=2
en-affil=
kn-affil=文学部 哲学芸術学専修コース
affil-num=3
en-affil=
kn-affil=文学部 歴史文化学専修コース
affil-num=4
en-affil=
kn-affil=文学部 言語文化学専修コース
affil-num=5
en-affil=
kn-affil=文学部 哲学芸術学専修コース
affil-num=6
en-affil=
kn-affil=文学部 行動科学専修コース
affil-num=7
en-affil=
kn-affil=文学部 芸術学・美術史分野
affil-num=8
en-affil=
kn-affil=文学部 歴史学・考古学分野
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2023
dt-pub=20230324
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=日本における性別と年齢ごとの性別違和の有病割合： ユトレヒト性別違和スケールを用いた人口ベースのインターネット調査
kn-title=Prevalence of Gender Dysphoria by Gender and Age in Japan: A Population-Based Internet Survey Using the Utrecht Gender Dysphoria Scale
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=OSHIMAYoshitaka
en-aut-sei=OSHIMA
en-aut-mei=Yoshitaka
kn-aut-name=大島義孝
kn-aut-sei=大島
kn-aut-mei=義孝
aut-affil-num=1
ORCID=
affil-num=1
en-affil=Graduate School of Medicine, Dentistry and Pharmaceutical Sciences, Okayama University
kn-affil=岡山大学大学院医歯薬学総合研究科
END
start-ver=1.4
cd-journal=joma
no-vol=134
cd-vols=
no-issue=1
article-no=
start-page=22
end-page=27
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2022
dt-pub=20220401
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Developing a scale to measure nurses' difficulty related to the treatment of gender dysphoric patients
kn-title=看護師の性別違和への関わりにくさについての尺度作成
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract= This study aimed to develop a scale to measure the perceived difficulty experienced by nurses in treating and caring for patients diagnosed with gender dysphoria and examine its reliability and validity. We developed a 26-item preliminary scale through discussions with experts in gender dysphoria treatment. We administered a questionnaire including this scale to 1,010 nurses working at Okayama University Hospital and analyzed the data of 346 nurses who had been involved in the treatment of gender dysphoria and had no missing responses.
A total of 20 items consisting of two factors, “relationship building” and “negative emotion for gender dysphoria,” were extracted by exploratory factor analysis, and we used them in the final version of the scale. Cronbach's alpha coefficient for the entire scale was 0.879, indicating a high degree of internal consistency.
However, the correlations with a communication skills scale (ENDCOREs) and the Scale of Gender Conception were limited, and the external validity could not be proven. This scale may be useful for evaluating nursing practice and educational support for nurses; however, there is room for further study on the scale validation.
en-copyright=
kn-copyright=
en-aut-name=MiyakeMaki
en-aut-sei=Miyake
en-aut-mei=Maki
kn-aut-name=三宅麻希
kn-aut-sei=三宅
kn-aut-mei=麻希
aut-affil-num=1
ORCID=
en-aut-name=OshimaYoshitaka
en-aut-sei=Oshima
en-aut-mei=Yoshitaka
kn-aut-name=大島義孝
kn-aut-sei=大島
kn-aut-mei=義孝
aut-affil-num=2
ORCID=
en-aut-name=NambaShihoko
en-aut-sei=Namba
en-aut-mei=Shihoko
kn-aut-name=難波志穂子
kn-aut-sei=難波
kn-aut-mei=志穂子
aut-affil-num=3
ORCID=
en-aut-name=MatsumotoYosuke
en-aut-sei=Matsumoto
en-aut-mei=Yosuke
kn-aut-name=松本洋輔
kn-aut-sei=松本
kn-aut-mei=洋輔
aut-affil-num=4
ORCID=
en-aut-name=HoriuchiMakiko
en-aut-sei=Horiuchi
en-aut-mei=Makiko
kn-aut-name=堀内真希子
kn-aut-sei=堀内
kn-aut-mei=真希子
aut-affil-num=5
ORCID=
en-aut-name=YamadaNorihito
en-aut-sei=Yamada
en-aut-mei=Norihito
kn-aut-name=山田了士
kn-aut-sei=山田
kn-aut-mei=了士
aut-affil-num=6
ORCID=
affil-num=1
en-affil=Department of Nursing, Okayama University Hospital
kn-affil=岡山大学病院 看護部
affil-num=2
en-affil=Department of Neuropsychiatry, Okayama University Hospital
kn-affil=岡山大学病院 精神科神経科
affil-num=3
en-affil=Department of Center for Innovative Clinical Medicine, Okayama University Hospital
kn-affil=岡山大学病院 新医療研究開発センター
affil-num=4
en-affil=Department of Gender Center, Okayama University Hospital
kn-affil=岡山大学病院 ジェンダーセンター
affil-num=5
en-affil=Department of Medical Support, Clinical Psychology section, Okayama University Hospital
kn-affil=岡山大学病院 医療技術部 臨床心理部門
affil-num=6
en-affil=Department of Neuropsychiatry, Okayama University Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
kn-affil=岡山大学学術研究院医歯薬学域 精神神経病態学
en-keyword=性別違和 (gender dysphoria)
kn-keyword=性別違和 (gender dysphoria)
en-keyword=関わりにくさ (difficulty in relating)
kn-keyword=関わりにくさ (difficulty in relating)
en-keyword=コミュニケーション (communication)
kn-keyword=コミュニケーション (communication)
en-keyword=性差観 (gender conception)
kn-keyword=性差観 (gender conception)
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=1
article-no=
start-page=1
end-page=14
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2020
dt-pub=20200327
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=The meaning of “independence” and “burden” from FUKUZAWA Yukichi’s viewpoint
kn-title=福沢諭吉における「独立」と「負担」 一家族・介護・老いを考える端緒として一
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=ShimadaYuichiro
en-aut-sei=Shimada
en-aut-mei=Yuichiro
kn-aut-name=島田雄一郎
kn-aut-sei=島田
kn-aut-mei=雄一郎
aut-affil-num=1
ORCID=
affil-num=1
en-affil=National Institute of Technology, Oshima College
kn-affil=大島商船高等専門学校
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=
dt-pub=
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Canna indica L. var. flava (Roscoe) Baker
kn-title=キバナダンドク
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-keyword=カンナ科 (Cannaceae)
kn-keyword=カンナ科 (Cannaceae)
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=
dt-pub=
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Fimbristylis diphylloides Makino
kn-title=クロテンツキ
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-keyword=カヤツリグサ科 (Cyperaceae)
kn-keyword=カヤツリグサ科 (Cyperaceae)
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=
dt-pub=
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Cyperus nipponicus Franch. et Sav.
kn-title=アオガヤツリ
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-keyword=カヤツリグサ科 (Cyperaceae)
kn-keyword=カヤツリグサ科 (Cyperaceae)
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=
dt-pub=
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Cyperus difformis L.
kn-title=タマガヤツリ
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-keyword=カヤツリグサ科 (Cyperaceae)
kn-keyword=カヤツリグサ科 (Cyperaceae)
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=
dt-pub=
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Emilia sonchifolia (L.) DC. var. javanica (Burm.f.) Mattf.
kn-title=ウスベニニガナ
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-keyword=キク科 (Asteraceae)
kn-keyword=キク科 (Asteraceae)
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=
dt-pub=
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Abelmoschus moschatus Medik.
kn-title=リュウキュウトロロアオイ
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-keyword=アオイ科 (Malvaceae)
kn-keyword=アオイ科 (Malvaceae)
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2020
dt-pub=20200325
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=非弁膜症性心房細動患者におけるワルファリンと比較したダビガトランの脳卒中/全身性塞栓発症抑制効果評価
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=OhshimaAyako
en-aut-sei=Ohshima
en-aut-mei=Ayako
kn-aut-name=大島礼子
kn-aut-sei=大島
kn-aut-mei=礼子
aut-affil-num=1
ORCID=
affil-num=1
en-affil=Graduate School of Medicine, Dentistry and Pharmaceutical Sciences, Okayama University
kn-affil=岡山大学大学院医歯薬学総合研究科
END
start-ver=1.4
cd-journal=joma
no-vol=19
cd-vols=
no-issue=6
article-no=
start-page=566
end-page=573
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2019
dt-pub=20190227
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Clinical characteristics of elderly depressive patients with low metaiodobenzylguanidine uptake
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=BACKGROUND:
Recently, depression with Lewy body pathology before the appearance of parkinsonism and cognitive dysfunction has been drawing attention. Low cardiac metaiodobenzylguanidine (MIBG) uptake is helpful for early differentiation of Lewy body disease (LBD) from late-onset psychiatric disorders even before parkinsonism or dementia appears. In this study, we used MIBG uptake as a tool in suspected LBD, and evaluated the relationship of MIBG results to clinical characteristics and depressive symptoms.
METHODS:
Fifty-two elderly inpatients with depression were included in this study. The Hamilton Depression Rating Scale (HDRS) was administered at admission, and 123 I-MIBG cardiac scintigraphy was performed. Of 52 patients, 38 had normal and 14 had reduced MIBG uptake.
RESULTS:
Correlation analyses of the late phase heart-to-mediastinum (H/M) ratio on the MIBG test and each item of the HDRS revealed that the H/M ratio was significantly correlated with scores of 'agitation', 'anxiety-somatic', and 'retardation' on the HDRS. Mean HDRS composite scores of 'somatic and psychic anxiety (Marcos)' and 'somatic anxiety/somatization factor (Pancheri)' were higher in the low uptake group than in the normal uptake group.
CONCLUSION:
Elderly patients with depression who manifested an obvious somatic anxiety tend to show low MIBG uptake, and are more likely to have Lewy body pathology.
en-copyright=
kn-copyright=
en-aut-name=TakenoshitaShintaro
en-aut-sei=Takenoshita
en-aut-mei=Shintaro
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=TeradaSeishi
en-aut-sei=Terada
en-aut-mei=Seishi
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaEtsuko
en-aut-sei=Oshima
en-aut-mei=Etsuko
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=
en-aut-name=YamaguchiMegumi
en-aut-sei=Yamaguchi
en-aut-mei=Megumi
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=4
ORCID=
en-aut-name=HayashiSatoshi
en-aut-sei=Hayashi
en-aut-mei=Satoshi
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=5
ORCID=
en-aut-name=HinotsuKenji
en-aut-sei=Hinotsu
en-aut-mei=Kenji
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=6
ORCID=
en-aut-name=EsumiSatoru
en-aut-sei=Esumi
en-aut-mei=Satoru
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=7
ORCID=
en-aut-name=ShinyaTakayoshi
en-aut-sei=Shinya
en-aut-mei=Takayoshi
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=8
ORCID=
en-aut-name=YamadaNorihito
en-aut-sei=Yamada
en-aut-mei=Norihito
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=9
ORCID=
affil-num=1
en-affil=Department of Neuropsychiatry, Okayama University Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
kn-affil=
affil-num=2
en-affil=Department of Neuropsychiatry, Okayama University Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
kn-affil=
affil-num=3
en-affil=Department of Neuropsychiatry, Okayama University Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
kn-affil=
affil-num=4
en-affil=Department of Neuropsychiatry, Okayama University Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
kn-affil=
affil-num=5
en-affil=Department of Neuropsychiatry, Okayama University Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
kn-affil=
affil-num=6
en-affil=Department of Neuropsychiatry, Okayama University Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
kn-affil=
affil-num=7
en-affil=Department of Pharmacy, Okayama University Hospital
kn-affil=
affil-num=8
en-affil=Department of Pediatric Radiology, Okayama University Hospital
kn-affil=
affil-num=9
en-affil=Department of Neuropsychiatry, Okayama University Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
kn-affil=
en-keyword=depression
kn-keyword=depression
en-keyword=elderly
kn-keyword=elderly
en-keyword=Lewy body disease
kn-keyword=Lewy body disease
en-keyword=metaiodobenzylguanidine
kn-keyword=metaiodobenzylguanidine
en-keyword=somatic anxiety
kn-keyword=somatic anxiety
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=
dt-pub=
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Fallopia convolvulus (L.) Á.Löve
kn-title=ソバカズラ
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-keyword=タデ科 (Polygonaceae)
kn-keyword=タデ科 (Polygonaceae)
END
start-ver=1.4
cd-journal=joma
no-vol=20
cd-vols=
no-issue=
article-no=
start-page=31
end-page=39
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2018
dt-pub=201803
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Ordinances and Human Rights in the Decentralized Society : From Japanese Constitutional Law’s Perspective
kn-title=地方分権時代の条例と人権保障のあり方 : 憲法と条例の関係に着目して
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=OshimaKayoko
en-aut-sei=Oshima
en-aut-mei=Kayoko
kn-aut-name=大島佳代子
kn-aut-sei=大島
kn-aut-mei=佳代子
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=同志社大学
END
start-ver=1.4
cd-journal=joma
no-vol=128
cd-vols=
no-issue=3
article-no=
start-page=191
end-page=196
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2016
dt-pub=20161201
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Our experience with the significance of collaborative medical and dental surgeries at the Head and Neck Cancer Center, Okayama University Hospital
kn-title=岡山大学病院頭頸部がんセンターにおける医科歯科合同手術の現状解析とその意義
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract= We have been collaborating with head and neck surgeons, plastic surgeons and oral surgeons in surgeries for many patients with head and neck carcinomas（ especially oral carcinomas） since 2006（ fiscal year 2005）. The Head and Neck Cancer Center was established at Okayama University Hospital in 2012.
This Center was the first of its kind at a national university hospital in Japan.
At the Center, 174 operations on head and neck carcinomas and 96 reconstructive operations were performed in 2014（ fiscal year）.
Medical and dental collaborative operations have been increasing almost every year since the 2005 fiscal year. There were 45 collaborative operations in the 2014 fiscal year, which included 30 cases of bone or metal plate reconstruction or plate reinforcement of the jaws.
There were 76 medical and dental collaborative operations in the 7 years before the establishment of the Center, with a mean of 10.9 operations per year. Since the establishment of the Center, there have been 112 cases over 3 years with a mean of 37.3 operations per year. The number of surgeries has been markedly increased by the establishment of the Head and Neck Cancer Center.
en-copyright=
kn-copyright=
en-aut-name=MizukawaNobuyoshi
en-aut-sei=Mizukawa
en-aut-mei=Nobuyoshi
kn-aut-name=水川展吉
kn-aut-sei=水川
kn-aut-mei=展吉
aut-affil-num=1
ORCID=
en-aut-name=OnodaTomoo
en-aut-sei=Onoda
en-aut-mei=Tomoo
kn-aut-name=小野田友男
kn-aut-sei=小野田
kn-aut-mei=友男
aut-affil-num=2
ORCID=
en-aut-name=MatsumotoHiroshi
en-aut-sei=Matsumoto
en-aut-mei=Hiroshi
kn-aut-name=松本洋
kn-aut-sei=松本
kn-aut-mei=洋
aut-affil-num=3
ORCID=
en-aut-name=TakedaSeiko
en-aut-sei=Takeda
en-aut-mei=Seiko
kn-aut-name=武田斉子
kn-aut-sei=武田
kn-aut-mei=斉子
aut-affil-num=4
ORCID=
en-aut-name=NodaYouhei
en-aut-sei=Noda
en-aut-mei=Youhei
kn-aut-name=野田洋平
kn-aut-sei=野田
kn-aut-mei=洋平
aut-affil-num=5
ORCID=
en-aut-name=OnodaSatoshi
en-aut-sei=Onoda
en-aut-mei=Satoshi
kn-aut-name=小野田聡
kn-aut-sei=小野田
kn-aut-mei=聡
aut-affil-num=6
ORCID=
en-aut-name=FukushimaMai
en-aut-sei=Fukushima
en-aut-mei=Mai
kn-aut-name=福島麻衣
kn-aut-sei=福島
kn-aut-mei=麻衣
aut-affil-num=7
ORCID=
en-aut-name=TsumuraMunechika
en-aut-sei=Tsumura
en-aut-mei=Munechika
kn-aut-name=津村宗近
kn-aut-sei=津村
kn-aut-mei=宗近
aut-affil-num=8
ORCID=
en-aut-name=TakeuchiTetsuo
en-aut-sei=Takeuchi
en-aut-mei=Tetsuo
kn-aut-name=竹内哲男
kn-aut-sei=竹内
kn-aut-mei=哲男
aut-affil-num=9
ORCID=
en-aut-name=SugiyamaNarushi
en-aut-sei=Sugiyama
en-aut-mei=Narushi
kn-aut-name=杉山成史
kn-aut-sei=杉山
kn-aut-mei=成史
aut-affil-num=10
ORCID=
en-aut-name=KimataYoshihiro
en-aut-sei=Kimata
en-aut-mei=Yoshihiro
kn-aut-name=木股敬裕
kn-aut-sei=木股
kn-aut-mei=敬裕
aut-affil-num=11
ORCID=
affil-num=1
en-affil=Departments of Oral and Maxillofacial Reconstructive Surgery, Head and Neck Cancer Center, Okayama University Hospital
kn-affil=岡山大学病院 頭頸部がんセンター， 顎口腔再建外科
affil-num=2
en-affil=Departments of Otorhinolaryngology, Head and Neck Surgery, Head and Neck Cancer Center, Okayama University Hospital
kn-affil=岡山大学病院 頭頸部がんセンター，耳鼻咽喉・頭頸部外科
affil-num=3
en-affil=Departments of Plastic and Reconstructive Surgery, Head and Neck Cancer Center, Okayama University Hospital
kn-affil=岡山大学病院 頭頸部がんセンター，形成外科
affil-num=4
en-affil=Departments of Oral and Maxillofacial Reconstructive Surgery, Head and Neck Cancer Center, Okayama University Hospital
kn-affil=岡山大学病院 頭頸部がんセンター，顎口腔再建外科
affil-num=5
en-affil=Departments of Otorhinolaryngology, Head and Neck Surgery, Head and Neck Cancer Center, Okayama University Hospital
kn-affil=岡山大学病院 頭頸部がんセンター，耳鼻咽喉・頭頸部外科
affil-num=6
en-affil=Departments of Plastic and Reconstructive Surgery, Head and Neck Cancer Center, Okayama University Hospital
kn-affil=岡山大学病院 頭頸部がんセンター，形成外科
affil-num=7
en-affil=Departments of Oral and Maxillofacial Reconstructive Surgery, Head and Neck Cancer Center, Okayama University Hospital
kn-affil=岡山大学病院 頭頸部がんセンター，顎口腔再建外科
affil-num=8
en-affil=Departments of Otorhinolaryngology, Head and Neck Surgery, Head and Neck Cancer Center, Okayama University Hospital
kn-affil=岡山大学病院 頭頸部がんセンター，耳鼻咽喉・頭頸部外科
affil-num=9
en-affil=Departments of Dental Laboratory, Head and Neck Cancer Center, Okayama University Hospital
kn-affil=岡山大学病院 頭頸部がんセンター，歯科技工室
affil-num=10
en-affil=Departments of Plastic and Reconstructive Surgery, Head and Neck Cancer Center, Okayama University Hospital
kn-affil=岡山大学病院 頭頸部がんセンター，形成外科
affil-num=11
en-affil=Departments of Plastic and Reconstructive Surgery, Head and Neck Cancer Center, Okayama University Hospital
kn-affil=岡山大学病院 頭頸部がんセンター，形成外科
en-keyword=頭頸部がん（head and neck carcinoma）
kn-keyword=頭頸部がん（head and neck carcinoma）
en-keyword=口腔がん（oral carcinoma）
kn-keyword=口腔がん（oral carcinoma）
en-keyword=頭頸部がんセンター（Head and Neck Cancer Center）
kn-keyword=頭頸部がんセンター（Head and Neck Cancer Center）
en-keyword=医科歯科合同手術（collaborative medical and dental surgeries）
kn-keyword=医科歯科合同手術（collaborative medical and dental surgeries）
en-keyword=顎骨再建（reconstructive operations of the jaw）
kn-keyword=顎骨再建（reconstructive operations of the jaw）
END
start-ver=1.4
cd-journal=joma
no-vol=128
cd-vols=
no-issue=1
article-no=
start-page=21
end-page=25
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2016
dt-pub=20160401
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=A case of mucinous adenocarcinoma of the duodenum and literature review of 16 cases reported in Japan
kn-title=原発性十二指腸粘液癌の一例― 本邦報告16例の検討―
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract= Primary mucinous adenocarcinoma of the duodenum is rare. Here we report a case we recently encountered, and we review 16 cases reported in Japan. An 82-year-old Japanese woman was admitted to our hospital complaining of abdominal pain and heartburn. An endoscopic examination revealed a Type 2 tumor in the descending limb of the duodenum, and endoscopically obtained specimens revealed a poorly differentiated adenocarcinoma. We performed a curative pancreatoduodenectomy with lymph node resection, and the surgical specimen revealed that the duodenum was the primary site of the mucinous adenocarcinoma. The patient is currently alive ＞ 1 year after the operation without any evidence of recurrence. Of the 16 patients reviewed, all patients had advanced tumors those depth were T3-T4. 9 patients had lymph node metastasis and 4 patients had peritoneal dissemination at the time of surgery. Since mucinous adenocarcinoma of the duodenum is often progressive cancer at a diagnosis, which is tend to have a worse prognosis than other histological types.
en-copyright=
kn-copyright=
en-aut-name=HamanoIkumi
en-aut-sei=Hamano
en-aut-mei=Ikumi
kn-aut-name=浜野郁美
kn-aut-sei=浜野
kn-aut-mei=郁美
aut-affil-num=1
ORCID=
en-aut-name=MatsumotoYusuke
en-aut-sei=Matsumoto
en-aut-mei=Yusuke
kn-aut-name=松本祐介
kn-aut-sei=松本
kn-aut-mei=祐介
aut-affil-num=2
ORCID=
en-aut-name=EndoYoshikatsu
en-aut-sei=Endo
en-aut-mei=Yoshikatsu
kn-aut-name=遠藤芳克
kn-aut-sei=遠藤
kn-aut-mei=芳克
aut-affil-num=3
ORCID=
en-aut-name=WatanabeNaoki
en-aut-sei=Watanabe
en-aut-mei=Naoki
kn-aut-name=渡邊直樹
kn-aut-sei=渡邊
kn-aut-mei=直樹
aut-affil-num=4
ORCID=
en-aut-name=KaiKyouhei
en-aut-sei=Kai
en-aut-mei=Kyouhei
kn-aut-name=甲斐恭平
kn-aut-sei=甲斐
kn-aut-mei=恭平
aut-affil-num=5
ORCID=
en-aut-name=SatoShizou
en-aut-sei=Sato
en-aut-mei=Shizou
kn-aut-name=佐藤四三
kn-aut-sei=佐藤
kn-aut-mei=四三
aut-affil-num=6
ORCID=
en-aut-name=WaniYoji
en-aut-sei=Wani
en-aut-mei=Yoji
kn-aut-name=和仁洋治
kn-aut-sei=和仁
kn-aut-mei=洋治
aut-affil-num=7
ORCID=
affil-num=1
en-affil=
kn-affil=姫路赤十字病院 外科
affil-num=2
en-affil=
kn-affil=姫路赤十字病院 外科
affil-num=3
en-affil=
kn-affil=姫路赤十字病院 外科
affil-num=4
en-affil=
kn-affil=姫路赤十字病院 外科
affil-num=5
en-affil=
kn-affil=姫路赤十字病院 外科
affil-num=6
en-affil=
kn-affil=姫路赤十字病院 外科
affil-num=7
en-affil=
kn-affil=姫路赤十字病院 病理診断科
en-keyword=原発性十二指腸癌（primary duodenal cancer）
kn-keyword=原発性十二指腸癌（primary duodenal cancer）
en-keyword=粘液癌（mucinous carcinoma）
kn-keyword=粘液癌（mucinous carcinoma）
en-keyword=膵頭十二指腸切除（pancreatoduodenectomy）
kn-keyword=膵頭十二指腸切除（pancreatoduodenectomy）
END
start-ver=1.4
cd-journal=joma
no-vol=127
cd-vols=
no-issue=3
article-no=
start-page=213
end-page=218
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2015
dt-pub=20151201
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=A case report of giant ectopic pheochromocytoma conversion therapy with radioisotope therapy and chemotherapy followed by curative resection
kn-title=術前内照射および化学療法が著効し,根治切除し得た巨大異所性褐色細胞腫の1例
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A 46-year-old man was found to be positive for occult blood at a medical checkup and was revealed to have a 14-cm tumor on the right side of abdominal aorta by a subsequent abdominal CT scan. The endocrinology laboratory data showed elevations in the levels of serum noradrenaline, and ectopic pheochromocytoma was suspected.
The tumor was compressing the inferior vena cava and portal vein, the superior mesenteric artery and the pancreas. Since it would be difficult to cure by operation, neoadjuvant therapy was started using radioisotope therapy by I-131 metaiodobenzylguanidine (131I-MIBG) and chemotherapy (CVD therapy ; cyclophosphamide, vincristine, dacarbazine). He was treated with three courses of radioisotope therapy and 16 courses of chemotherapy, which significantly reduced the tumor size. This made radical resection possible ; we were able to avoid the merger excision of great vessels and other organs.
On pathological and immunopathological findings, the tumor was diagnosed as ectopic pheochromocytoma. Regarding the safety and curability of the treatment, neoadjuvant therapy may be useful in treating very large tumors that show invasion of other organs.
en-copyright=
kn-copyright=
en-aut-name=YasuiKazuya
en-aut-sei=Yasui
en-aut-mei=Kazuya
kn-aut-name=安井和也
kn-aut-sei=安井
kn-aut-mei=和也
aut-affil-num=1
ORCID=
en-aut-name=UmedaYuzo
en-aut-sei=Umeda
en-aut-mei=Yuzo
kn-aut-name=楳田祐三
kn-aut-sei=楳田
kn-aut-mei=祐三
aut-affil-num=2
ORCID=
en-aut-name=KumanoKenjiro
en-aut-sei=Kumano
en-aut-mei=Kenjiro
kn-aut-name=熊野健二郎
kn-aut-sei=熊野
kn-aut-mei=健二郎
aut-affil-num=3
ORCID=
en-aut-name=TabataMasahiro
en-aut-sei=Tabata
en-aut-mei=Masahiro
kn-aut-name=田端雅弘
kn-aut-sei=田端
kn-aut-mei=雅弘
aut-affil-num=4
ORCID=
en-aut-name=OtsukaFumio
en-aut-sei=Otsuka
en-aut-mei=Fumio
kn-aut-name=大塚文男
kn-aut-sei=大塚
kn-aut-mei=文男
aut-affil-num=5
ORCID=
en-aut-name=YagiTakahito
en-aut-sei=Yagi
en-aut-mei=Takahito
kn-aut-name=八木孝仁
kn-aut-sei=八木
kn-aut-mei=孝仁
aut-affil-num=6
ORCID=
en-aut-name=FujiwaraToshiyoshi
en-aut-sei=Fujiwara
en-aut-mei=Toshiyoshi
kn-aut-name=藤原俊義
kn-aut-sei=藤原
kn-aut-mei=俊義
aut-affil-num=7
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科
affil-num=2
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科
affil-num=3
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科
affil-num=4
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科
affil-num=5
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科
affil-num=6
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科
affil-num=7
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科
en-keyword=異所性褐色細胞腫（ectopic pheochromocytoma）
kn-keyword=異所性褐色細胞腫（ectopic pheochromocytoma）
en-keyword=化学療法（chemo therapy）
kn-keyword=化学療法（chemo therapy）
en-keyword=131I-MIBG
kn-keyword=131I-MIBG
END
start-ver=1.4
cd-journal=joma
no-vol=126
cd-vols=
no-issue=2
article-no=
start-page=99
end-page=102
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2014
dt-pub=20140801
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=The 2013 Incentive Award of the Okayama Medical Association in Neuroscience (2013 Niimi Prize)
kn-title=平成25年度岡山医学会賞 脳神経研究奨励賞（新見賞）
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=OshimaEtsuko
en-aut-sei=Oshima
en-aut-mei=Etsuko
kn-aut-name=大島悦子
kn-aut-sei=大島
kn-aut-mei=悦子
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学病院 精神科神経科
END
start-ver=1.4
cd-journal=joma
no-vol=38
cd-vols=
no-issue=4
article-no=
start-page=1
end-page=2
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1949
dt-pub=19491010
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Studies on the biological control of plant diseases by the utilization of antagonistic organisms on the pathogenes. (2)
kn-title=拮抗微生物による作物病害防除の研究 第2報 拮抗放射状菌No.1141によるトマト靑枯病防除試驗 [附]煩草立枯病防除試驗
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=NishikadoY.
en-aut-sei=Nishikado
en-aut-mei=Y.
kn-aut-name=西門義一
kn-aut-sei=西門
kn-aut-mei=義一
aut-affil-num=1
ORCID=
en-aut-name=OshimaT.
en-aut-sei=Oshima
en-aut-mei=T.
kn-aut-name=大島俊市
kn-aut-sei=大島
kn-aut-mei=俊市
aut-affil-num=2
ORCID=
en-aut-name=IshiiH.
en-aut-sei=Ishii
en-aut-mei=H.
kn-aut-name=石井博
kn-aut-sei=石井
kn-aut-mei=博
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=
affil-num=2
en-affil=
kn-affil=
affil-num=3
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=36
cd-vols=
no-issue=
article-no=
start-page=411
end-page=415
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1944
dt-pub=19440525
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=ハナズハウの角斑病及び褐紋病
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=西門義一
kn-aut-sei=西門
kn-aut-mei=義一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島俊市
kn-aut-sei=大島
kn-aut-mei=俊市
aut-affil-num=2
ORCID=
affil-num=1
en-affil=
kn-affil=
affil-num=2
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=36
cd-vols=
no-issue=
article-no=
start-page=381
end-page=396
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1944
dt-pub=19440525
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=棉の黑斑病に就いて 東亞に於ける棉花の病害防除に關する研究（第二報）
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=西門義一
kn-aut-sei=西門
kn-aut-mei=義一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島俊市
kn-aut-sei=大島
kn-aut-mei=俊市
aut-affil-num=2
ORCID=
affil-num=1
en-affil=
kn-affil=
affil-num=2
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=47
cd-vols=
no-issue=1-2
article-no=
start-page=51
end-page=57
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1959
dt-pub=195911
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Note on the parasitic fungus, Spicaria rubido-purpurea AOKI, on the potato tuber moth, Gnorimoschema opercullela (ZELL). (Preliminary report)
kn-title=Spicaria rubido-purpurea Aokiのジャガイモガに対する寄生性（予報）
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=OshimaS.
en-aut-sei=Oshima
en-aut-mei=S.
kn-aut-name=大島俊市
kn-aut-sei=大島
kn-aut-mei=俊市
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=41
cd-vols=
no-issue=1
article-no=
start-page=1
end-page=8
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1953
dt-pub=19530331
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=拮抗微生物による作物病害防除の硏究 第7報 Trichoderma菌の拮抗作用に関する硏究史
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=西門義一
kn-aut-sei=西門
kn-aut-mei=義一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島俊市
kn-aut-sei=大島
kn-aut-mei=俊市
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=野田二郎
kn-aut-sei=野田
kn-aut-mei=二郎
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=
affil-num=2
en-affil=
kn-affil=
affil-num=3
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=40
cd-vols=
no-issue=4
article-no=
start-page=195
end-page=204
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1953
dt-pub=19530228
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=拮抗微生物による作物病害防除の研究 第6報 放射狀菌の拮抗作用
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=西門義一
kn-aut-sei=西門
kn-aut-mei=義一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島俊市
kn-aut-sei=大島
kn-aut-mei=俊市
aut-affil-num=2
ORCID=
affil-num=1
en-affil=
kn-affil=
affil-num=2
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=40
cd-vols=
no-issue=1
article-no=
start-page=7
end-page=12
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1951
dt-pub=19511020
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=拮抗微生物による作物病害防除の硏究 第五報 抗菌力價に及ぼす溫度影響
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=西門義一
kn-aut-sei=西門
kn-aut-mei=義一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島俊市
kn-aut-sei=大島
kn-aut-mei=俊市
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=森田日出男
kn-aut-sei=森田
kn-aut-mei=日出男
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=
affil-num=2
en-affil=
kn-affil=
affil-num=3
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=39
cd-vols=
no-issue=4
article-no=
start-page=1
end-page=5
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1951
dt-pub=19510415
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=拮抗微生物による作物病害防除の硏究 第4報 拮抗放射狀菌堆肥培養について
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=西門義一
kn-aut-sei=西門
kn-aut-mei=義一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島俊市
kn-aut-sei=大島
kn-aut-mei=俊市
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=森田日出男
kn-aut-sei=森田
kn-aut-mei=日出男
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=
affil-num=2
en-affil=
kn-affil=
affil-num=3
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=39
cd-vols=
no-issue=1
article-no=
start-page=1
end-page=4
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1950
dt-pub=19500215
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=拮抗微生物による作物病害防除の硏究 第3報 拮抗放射狀菌の培養粉末に就て
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=西門義一
kn-aut-sei=西門
kn-aut-mei=義一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島俊市
kn-aut-sei=大島
kn-aut-mei=俊市
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=森田日出男
kn-aut-sei=森田
kn-aut-mei=日出男
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=
affil-num=2
en-affil=
kn-affil=
affil-num=3
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=38
cd-vols=
no-issue=2
article-no=
start-page=6
end-page=10
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1949
dt-pub=19490330
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=拮抗微生物利用による作物病害防除の硏究 第1報 トマト靑枯病菌Bact.solanacearumに對し拮抗作用を有する放射狀菌に就て
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=西門義一
kn-aut-sei=西門
kn-aut-mei=義一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島俊市
kn-aut-sei=大島
kn-aut-mei=俊市
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=石井博
kn-aut-sei=石井
kn-aut-mei=博
aut-affil-num=3
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=森田日出男
kn-aut-sei=森田
kn-aut-mei=日出男
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=
affil-num=2
en-affil=
kn-affil=
affil-num=3
en-affil=
kn-affil=
affil-num=4
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=38
cd-vols=
no-issue=1
article-no=
start-page=30
end-page=34
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1948
dt-pub=19481110
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=病害豫防用藥劑の効果の硏究 第4報 小麥苗に於ける白澁病對する効果の檢定
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=西門義一
kn-aut-sei=西門
kn-aut-mei=義一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=中山隆夫
kn-aut-sei=中山
kn-aut-mei=隆夫
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島俊市
kn-aut-sei=大島
kn-aut-mei=俊市
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=
affil-num=2
en-affil=
kn-affil=
affil-num=3
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=37
cd-vols=
no-issue=4
article-no=
start-page=17
end-page=21
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1948
dt-pub=19480910
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=病害予防用藥剤の効果の硏究 第3報 稻苗に於ける稻胡麻葉枯病に對する豫防効果の檢定
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=西門義一
kn-aut-sei=西門
kn-aut-mei=義一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=中山隆夫
kn-aut-sei=中山
kn-aut-mei=隆夫
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島俊市
kn-aut-sei=大島
kn-aut-mei=俊市
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=
affil-num=2
en-affil=
kn-affil=
affil-num=3
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2012
dt-pub=20120323
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=アルツハイマー病におけるFrontal assessment batteryと脳灌流画像
kn-title=Frontal assessment battery and brain perfusion imaging in Alzheimer's disease
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=OshimaEtsuko
en-aut-sei=Oshima
en-aut-mei=Etsuko
kn-aut-name=大島悦子
kn-aut-sei=大島
kn-aut-mei=悦子
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=123
cd-vols=
no-issue=2
article-no=
start-page=129
end-page=132
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2011
dt-pub=20110801
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Laparoscopic surgery for mesenteric Castleman's disease
kn-title=腹腔鏡下に摘出しえた上行結腸間膜発生のCastleman病の１例
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=We report herein a case of mesenteric Castleman's disease which was confirmed on pathology. A 60-year-old man was admitted to our hospital complaining of abdominal pain. On the physical examination, there was no palpable mass. Computed tomography findings and magnetic resonance imaging revealed a well circumscribed, lobulated round mass on the right side of the superior mesenteric vein. Laparoscopic surgery for the mesenteric tumor was carried out to obtain a definite diagnosis and treatment. In the operative field, the mass was located on the ascending colic mesentery and measured about 3 cm in size. It was solid and surrounded by a thin fibrous capsule. The histological diagnosis of the mesenteric tumor was hyaline vascular type Castleman's disease. The postoperative course of the patient was uneventful, and he was discharged on the 10th postoperative day.
en-copyright=
kn-copyright=
en-aut-name=NishieManabu
en-aut-sei=Nishie
en-aut-mei=Manabu
kn-aut-name=西江学
kn-aut-sei=西江
kn-aut-mei=学
aut-affil-num=1
ORCID=
en-aut-name=OtsukaShinya
en-aut-sei=Otsuka
en-aut-mei=Shinya
kn-aut-name=大塚真哉
kn-aut-sei=大塚
kn-aut-mei=真哉
aut-affil-num=2
ORCID=
en-aut-name=TomodaJun
en-aut-sei=Tomoda
en-aut-mei=Jun
kn-aut-name=友田純
kn-aut-sei=友田
kn-aut-mei=純
aut-affil-num=3
ORCID=
en-aut-name=FujiwaraKeishi
en-aut-sei=Fujiwara
en-aut-mei=Keishi
kn-aut-name=藤原敬士
kn-aut-sei=藤原
kn-aut-mei=敬士
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=国立病院機構福山医療センター 外科
affil-num=2
en-affil=
kn-affil=国立病院機構福山医療センター 外科
affil-num=3
en-affil=
kn-affil=国立病院機構福山医療センター 内科
affil-num=4
en-affil=
kn-affil=光生病院 内科
en-keyword=結腸間膜 (mesocolon)
kn-keyword=結腸間膜 (mesocolon)
en-keyword=Castleman病 (Castleman's disease)
kn-keyword=Castleman病 (Castleman's disease)
en-keyword=腹腔鏡手術 (laparoscopic surgery)
kn-keyword=腹腔鏡手術 (laparoscopic surgery)
END
start-ver=1.4
cd-journal=joma
no-vol=61
cd-vols=
no-issue=6-7
article-no=
start-page=131
end-page=134
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1949
dt-pub=19490831
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=温泉の效用
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大學放射能泉研究所
END
start-ver=1.4
cd-journal=joma
no-vol=12
cd-vols=
no-issue=
article-no=
start-page=15
end-page=20
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1953
dt-pub=195309
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=INDICE DE NUTRITION AND OXIDATIOM-REDUCTION POTENIAL OF MINERAL WATERS
kn-title=温泉水のIndice de nutritionと酸化還元電位
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Indice de nutrition (Pech), indice de nutrition simplifié (Rimattei), membrane potential difference of human skin, and oxidation-reduction potential of several mineral watem were measured. Their balneological significance was discussed.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学温泉研究所内科
END
start-ver=1.4
cd-journal=joma
no-vol=10
cd-vols=
no-issue=
article-no=
start-page=13
end-page=16
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1953
dt-pub=195303
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=EFFECT OF THE INTERNAL USE OF MISASA (RADON SPRING), HAMAMURA (SULFATED CALCIUM SPRING) AND TOTTORI (SULFATED MURIATED SPRING) SPRING WATERS UPON THE ALIMENTARY HYPERGLYCAEMIA IN RABBITS
kn-title=三朝温泉(放射能泉),浜村温泉(含石膏食塩泉)並に鳥取温泉(含食塩芒硝泉)の飲用が食餌性過血糖に及ぼす影響
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Five years ago Morinaga reported that the intemal use of the thermal waters of Misasa promoted the action of insuline, inhibited the adrenaline hyperglycaemia and suppressed the alimentary hyperglycaemia. But the highest radon content of the waters used at that time was about 1000×10(-10) Curie units per liter. Recently a more highly radioactive spring was found in Misasa, its radon content being 3000-4000×l0(-10) Curie units per liter, though very feebly mineralized (under 0.5 g per liter) and cold. Therefore the hypoglycaemic effect of this newly discovered water was, investigated in rabbits and compared with the effects of two other thermal waters in Tottori Prefecture and of plain water as a control. Twenty cc. of ten per cent glucofoe solution in thermal waters or in plain water per kilogram of bodyweight was administered to the rabitts by stomach tube and blood sugar level was determined before, 30, 60, 120, and 180 minutes after the administration. All of the three thermal waters decreased the glycaemia significantly as compared the results with plain water control.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学温泉研究所内科
END
start-ver=1.4
cd-journal=joma
no-vol=3
cd-vols=
no-issue=
article-no=
start-page=18
end-page=20
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1950
dt-pub=19500725
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Studies of the radio-active springs. XXV The effect of Thoron spring bath on Rotter's reaction
kn-title=放射能泉に關する研究（XXV） トロン泉入浴と皮膚の色素還元能力
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=In the preliminary papers the author reported that the Thoron in thermal water passes throngh the skin and stimulates the subcutaneous connective tissue cells. Sotozono proved that the reduced ascorbic acid content in the blood increases after the Radonspring bath. Before and after thermal bath the author measured the time necessary for the complete decoloration of intradermally injected dichlorphenol-indophenol solution. Compared with the plain water bath at a same temperature, the Thoron spring bath seems to have a tendency to reduce the time necessary for the decoloration.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=3
cd-vols=
no-issue=
article-no=
start-page=11
end-page=14
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1950
dt-pub=19500725
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Studies of the radio-active springs (XXII-XXIII)
kn-title=放射能泉に關する研究（XXII-XXIII）
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大學放射能泉研究所内科
END
start-ver=1.4
cd-journal=joma
no-vol=13
cd-vols=
no-issue=
article-no=
start-page=36
end-page=41
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1953
dt-pub=195312
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=MEDICAL STUDIES ON CHONDROITIN SULFATE (III)
kn-title=コンドロイチン硫酸の医学的研究（第3報）
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=2-5cc. of 1% Rodium chondroitin-sulfate solution subcutaneouRly or 2cc. of 5% solution intraveneously was administered to 37 cares of painful disorders such as headache, backache or arthralgia. A marked improvement was obtained in 12 cares and a moderate result was seen in 16 cases. No definite change was proved concerning blood pressure in the patients and detoxicating effect in animal experiment.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
en-aut-name=SotozonoMasazumi
en-aut-sei=Sotozono
en-aut-mei=Masazumi
kn-aut-name=外園正純
kn-aut-sei=外園
kn-aut-mei=正純
aut-affil-num=2
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学温泉研究所内科
affil-num=2
en-affil=
kn-affil=岡山大学温泉研究所内科
END
start-ver=1.4
cd-journal=joma
no-vol=13
cd-vols=
no-issue=
article-no=
start-page=15
end-page=17
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1953
dt-pub=195312
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=STUDIES ON VITRIOL SPRINGS (4) ON THE COPPER, ZINC, NICKEL, AND COBALT CONTENTS OF BLOOD AFTER THE INTERNAL USE OF A VITRIOL WATER
kn-title=緑ばん泉に関する研究（4） : 綠ばん泉飲用後血液内微量金属元素の動きについて
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Sotozono proved that the administration of daily 20cc of Fujino Mineral Water (an acid vitriol water containing copper, zinc, nickel and cobalt) has a remarkably beneficial effect on several kinds of hypochromic anemia. It contains 9.56gms of iron, 0.007gm of zinc, 0.005gm of copper 0.001gm of nickel, and 0.006gm of cobalt in one liter. 20 - 40cc of Fujino water was diluted 5 - 10 fold with plain water and administered to the fasting patients perorally. Blood samples were taken from cubital vein before, 1, 2, 4, 6, 24, 48, and 72 hours after the intake of the vitriol water. Copper, zinc, nickel and cobalt contents of the blood samples were measured by Ashizawa' s dithizone- chromatographic method. It was shown that copper, nickel, and cobalt contents of blood rose unexpectedly high temporarily, in a manner that did not correspond to their amount in the given mineral water. So that the mobilization of copper, nickel, and cobalt in the body after the intake of the mineral IVrter was susrected. Zinc
content of blood showed no constant tendency.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
en-aut-name=AshizawaTakashi
en-aut-sei=Ashizawa
en-aut-mei=Takashi
kn-aut-name=芦沢峻
kn-aut-sei=芦沢
kn-aut-mei=峻
aut-affil-num=2
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学温泉研究所
affil-num=2
en-affil=
kn-affil=岡山大学温泉研究所
END
start-ver=1.4
cd-journal=joma
no-vol=13
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1953
dt-pub=195312
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=岡山大学温泉研究所十周年記念に際して， 回顧と所感
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=14
cd-vols=
no-issue=
article-no=
start-page=1
end-page=14
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1954
dt-pub=195403
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=RADON CONTENT OF HOT SPRINGS IN TOTTORI PREFECTURE, JAPAN
kn-title=鳥取県下の温泉のラドン含有量に就て
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=1. Radon content of 166 thermal waters in IWAI, TOTTORI YOSHIOKA, HAMAMURA, TOGO, SEKIGANE, MISASA, and KAlKE Hot Springs was measured by I. M. Fontactoscope in the years 1950-1951. Of which 66 samples showed a radon content over 30×10(-10) curie units per liter. Namely, 50 springs in Misasa, 6 in Sekigane, 9 in Hamamura, and one in Togo belonged to the radioactive spring in the definition by Ministry of Social Welfare. The highest Radon content (1150×10(10) curie units per liter) was recorded in Hisuino-Yu in Misasa, where five springs had a radon content over 360×10(-10) curie units per liter. 2. No marked difference was proved between the results obtained this time and the data in the former reports concerning the radon content of these thermal springs. 3. Radon content proved higher in the springs which issue from granite than in
the springs of other districts. No definite relation was proved between the radon content and water temperature. The radon content was generally high in simple thermals or in weak sodium chloride springs, low in sulfated springs and in saline springs which had a comparatively
high sulfate content.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
en-aut-name=YamadaNaoharu
en-aut-sei=Yamada
en-aut-mei=Naoharu
kn-aut-name=山田尚春
kn-aut-sei=山田
kn-aut-mei=尚春
aut-affil-num=2
ORCID=
en-aut-name=MifuneMasaaki
en-aut-sei=Mifune
en-aut-mei=Masaaki
kn-aut-name=御船政明
kn-aut-sei=御船
kn-aut-mei=政明
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学温泉研究所
affil-num=2
en-affil=
kn-affil=岡山大学温泉研究所
affil-num=3
en-affil=
kn-affil=岡山大学温泉研究所
END
start-ver=1.4
cd-journal=joma
no-vol=16
cd-vols=
no-issue=
article-no=
start-page=1
end-page=18
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1956
dt-pub=195601
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=REPORT OF THE CHEMICAL ANALYSIS OF MISASA HOT SPRINGS, TOTTORI PREFECTURE
kn-title=鳥取県三朝温泉調査報告
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=The water samples of 55 springs of Misasa were analysed in the years 1950～1951. The temperatures of the waters ranged from 44° to 85° C. Radon content ranged from 34.1 to 2360×10(-10) curies per liter. pH 6.2～7.5. Evaporation residue: 534～1940 mg/kg. K(+) :10.4～47.3mg/kg. Na(+) : 140.4～574mg/kg. Ca(2+) : 7.56～49.06mg/kg. Mg(2+) : 0.11～15.3mg/kg.. Fe(2+) : 0.10～0.67mg/kg. Cl(-) : 138～854mg/kg. SO(4)(2-) : 29.2～187mg/kg. HCO(3)(-) : 74.8～370mg/kg. HBO(2)(-) : 1.80～19.6mg/kg. S(2)O(3)(2-) : o.62～3.69mg/kg. Radon sources seem to exist at shallow places under the ground and the radon in the thermal wacer is supposed to have been derive partly from the ground water which also contains considerable amount of radon. A close linear correlation (r=0.751) was proved between the sulfate and the chloride ion contents.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
en-aut-name=MifuneMasaaki
en-aut-sei=Mifune
en-aut-mei=Masaaki
kn-aut-name=御船政明
kn-aut-sei=御船
kn-aut-mei=政明
aut-affil-num=2
ORCID=
en-aut-name=YamadaNaoharu
en-aut-sei=Yamada
en-aut-mei=Naoharu
kn-aut-name=山田尚春
kn-aut-sei=山田
kn-aut-mei=尚春
aut-affil-num=3
ORCID=
en-aut-name=UeyamaAkiko
en-aut-sei=Ueyama
en-aut-mei=Akiko
kn-aut-name=上山昭子
kn-aut-sei=上山
kn-aut-mei=昭子
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学温泉研究所
affil-num=2
en-affil=
kn-affil=岡山大学温泉研究所
affil-num=3
en-affil=
kn-affil=鳥取県衛生部
affil-num=4
en-affil=
kn-affil=鳥取県衛生部
END
start-ver=1.4
cd-journal=joma
no-vol=68
cd-vols=
no-issue=3
article-no=
start-page=951
end-page=956
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2005
dt-pub=20050811
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Kinetic-spectrophotometric method for the determination of trace amounts of bromide in seawater
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A novel simple, sensitive and rapid kinetic-spectrophotornetric method is proposed for the determination of trace amounts of bromide. The method is based on its catalytic effect on the oxidation of methylene blue (MB) by hydrogen peroxide in strongly acidic solution. The oxidation reaction is activated by large amounts of chloride and can be monitored spectrophotometrically by measuring the decrease in the absorbance of MB at 746 run. The determination of bromide is performed by a fixed-time method at the first 100 s from the initiation of the reaction. Unlike other kinetic-spectrophotornetric methods for the determination of bromide, the proposed method does not require heating the solution. Bromide can be determined in the range from 80 to 960 mu g l(-1) with the detection limit of 35 mu g l(-1). The relative standard deviation of ten replicate determination of 480 mu g l(-1) bromide was 1.4%. The influence of potential interfering ions was studied. The proposed method was satisfactorily applied to the determination of bromide in seawater without interfering effect from chloride ion.
en-copyright=
kn-copyright=
en-aut-name=UraisinKanchana
en-aut-sei=Uraisin
en-aut-mei=Kanchana
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=NacaprichaDuangjai
en-aut-sei=Nacapricha
en-aut-mei=Duangjai
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=4
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=5
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Mahidol University
affil-num=5
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=Kinetic-spectrophotometry
kn-keyword=Kinetic-spectrophotometry
en-keyword=Methylene blue
kn-keyword=Methylene blue
en-keyword=Bromide
kn-keyword=Bromide
en-keyword=Seawater
kn-keyword=Seawater
END
start-ver=1.4
cd-journal=joma
no-vol=68
cd-vols=
no-issue=2
article-no=
start-page=388
end-page=393
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2005
dt-pub=20051013
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=On-line preconcentration using dual mini-columns for the speciation of chromium(III) and chromium(VI) and its application to water samples as studied by inductively coupled plasma-atomic emission spectrometry
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=On-line preconcentration system for the selective, sensitive and simultaneous determination of chromium species was investigated. Dual minicolumns containing chelating resin were utilized for the speciation and preconcentration of Cr(III) and Cr(VI) in water samples. In this system, Cr(III) was collected on first column packed with iminodiacetate resin. Cr(VI) in the effluent from the first column was reduced to Cr(III), which was collected on the second column packed with iminodiacetate resin. Hydroxyammonium chloride was examined as a potential reducing agent for Cr(VI) to Cr(III).
The effects of pH, sample flow rate, column length, and interfering ions on the recoveries of Cr(III) were carefully studied. Five millilitres of a sample solution was introduced into the system. The collected species were then sequentially washed by 1 M ammonium acetate, eluted by 2 M nitric acid and measured by ICP-AES. The detection limit for Cr(III) and Cr(VI) was 0.08 and 0.15 mu g l-1, respectively. The total analysis time was about 9.4 min.
The developed method was successfully applied to the speciation of chromium in river, tap water and wastewater samples with satisfied results.
en-copyright=
kn-copyright=
en-aut-name=SumidaTakashi
en-aut-sei=Sumida
en-aut-mei=Takashi
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=IkenoueTamami
en-aut-sei=Ikenoue
en-aut-mei=Tamami
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=HamadaKazuhide
en-aut-sei=Hamada
en-aut-mei=Kazuhide
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=4
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=5
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=6
ORCID=
affil-num=1
en-affil=
kn-affil=Industrial Technology Center of Kochi Prefecture
affil-num=2
en-affil=
kn-affil=Industrial Technology Center of Kochi Prefecture
affil-num=3
en-affil=
kn-affil=Industrial Technology Center of Kochi Prefecture
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=5
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=6
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=speciation
kn-keyword=speciation
en-keyword=chromium
kn-keyword=chromium
en-keyword=on-line preconcentration
kn-keyword=on-line preconcentration
en-keyword=ICP-AES
kn-keyword=ICP-AES
en-keyword=chelating resin
kn-keyword=chelating resin
END
start-ver=1.4
cd-journal=joma
no-vol=558
cd-vols=
no-issue=1-2
article-no=
start-page=246
end-page=253
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2006
dt-pub=20060203
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Synthesis of a chitosan-based chelating resin and its application to the selective concentration and ultratrace determination of silver in environmental water samples
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A novel chelating resin using chitosan as a base material, ethylenediamine-type chitosan, has been synthesized for the first time in the present study, and applied to the collection/concentration of ultratrace amounts of silver in environmental water samples. In the present study, ultratrace amounts of silver collected on the resin were eluted and determined by ICP-MS. The resin packed in a 1 mL mini column could adsorb silver selectively and quantitatively at a flow rate of 2 mL min(-1) in the wide pH range from 1 to 8, and silver adsorbed on the resin could be easily recovered by passing 1 M nitric acid as an eluent into the column. High adsorption capacity for silver at pH 5, 0.37 mmol mL(-1) of the resin, was achieved, and t(1/2) of the adsorption is less than 5 min. The effect of chloride on the collection of silver was examined by varying chloride concentrations from 10(-4) to 0.75 M; the results showed that the present resin can be used for the collection/concentration of ultratrace amounts of silver in natural waters, as well as seawater. To ensure the accuracy and the precision of the method, CASS-4 near shore seawater reference material from the NRCC has been analyzed. This is not a certified SRM for silver, but has been used for comparative silver analysis by several groups, who report very similar results to those that are reported here. The developed method using ethylenediamine-type chitosan resin gives 0.7 pg mL(-1) of the detection limit when 50-fold enrichment was used. The proposed method was successfully applied to the determination of silver in tap, river, and seawater samples.
en-copyright=
kn-copyright=
en-aut-name=KatarinaRosi Ketrin
en-aut-sei=Katarina
en-aut-mei=Rosi Ketrin
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=Chelating resin
kn-keyword=Chelating resin
en-keyword=Chitosan
kn-keyword=Chitosan
en-keyword=Determination of silver
kn-keyword=Determination of silver
en-keyword=Environmental water samples
kn-keyword=Environmental water samples
en-keyword=ICP-MS
kn-keyword=ICP-MS
END
start-ver=1.4
cd-journal=joma
no-vol=21
cd-vols=
no-issue=3
article-no=
start-page=263
end-page=268
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2005
dt-pub=200503
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Trace and ultratrace analysis of purified water samples and hydrogen peroxide solutions for phosphorus by flow-injection method
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A highly sensitive fluorescence-quenching method for the determination of phosphorus based on the formation of an ion associate between molybdophosphate and Rhodamine B (RB) was developed. A simple flow-injection system coupled with a fluorescence detector was used to measure the fluorescence intensity at 560 nm and 580 nm as an excitation and an emission wavelength, respectively. The calibration graph for phosphorus showed a good linearity in the range of (0-1) x 10(-7) M (1 M = 1 mol L-1), and a detection limit of I x 10(-9) M (SIN = 3). The proposed method was successfully applied to the determination of ultratrace amounts of phosphorus in ultrapurified and purified water samples, and to the determination of trace amounts of phosphorus in commercially-available hydrogen peroxide solutions with satisfactory results.
en-copyright=
kn-copyright=
en-aut-name=LiZenhai
en-aut-sei=Li
en-aut-mei=Zenhai
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
END
start-ver=1.4
cd-journal=joma
no-vol=60
cd-vols=
no-issue=6
article-no=
start-page=1277
end-page=1285
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2003
dt-pub=20030829
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Novel flow injection-fluorometric method for the determination of trace silicate and its application to ultrapurified water analysis
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
A highly sensitive fluorescence quenching method for the determination of silicate based on the formation of an ion associate between molybdosilicate and Rhodamine B (RB) in nitric acid medium was developed. A flow injection system coupled with a fluorescence detector was used for the measurement of fluorescence intensity at 560 and 580 nm as excitation and emission wavelengths, respectively. The calibration graph for Si showed a linear range of 0.1-5 ng cm(-3) with correlation coefficient of 0.9999, and the detection limit of 0.06 ng cm(-3). The proposed method was successfully applied to the determination of silicate in ultrapurified water with satisfactory results.
en-copyright=
kn-copyright=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=IshiiNaoe
en-aut-sei=Ishii
en-aut-mei=Naoe
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Laboratory Water Division, Nihon Millipore Ltd
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=ultrapurified water
kn-keyword=ultrapurified water
en-keyword=ion associate
kn-keyword=ion associate
en-keyword=molybdosilicate
kn-keyword=molybdosilicate
en-keyword=rhodamine B
kn-keyword=rhodamine B
en-keyword=flow injection
kn-keyword=flow injection
en-keyword=fluorescence quenching
kn-keyword=fluorescence quenching
END
start-ver=1.4
cd-journal=joma
no-vol=581
cd-vols=
no-issue=2
article-no=
start-page=214
end-page=220
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20070109
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Functionalization of chitosan with 3,4-dihydroxybenzoic acid for the adsorption/collection of uranium in water samples and its determination by inductively coupled plasma-mass spectrometry
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A chitosan resin derivatized with 3,4-dihydroxybenzoic acid moiety (CCTS-DHBA resin) was newly synthesized for the collection/concentration of trace uranium by using cross-linked chitosan (CCTS) as base material, and the adsorption behavior of uranium as well as 60 elements on the resin was examined by passing the sample solutions through a mini-column packed with the resin. After the elution of the collected elements on the resin with 1M HNO3, the eluates were measured by inductively coupled plasma-mass spectrometry (ICP-MS). The CCTS-DHBA resin can adsorb several metal cations and several oxoanionic elements at appropriate pH. Among these metal ions, uranium shows an excellent adsorption behavior on this resin. Uranium as UO22+ species can be adsorbed on the resin by chelating mechanism with adsorption capacity of 330 mg g(-1) resin. Through the column treatment, the complete removal of large amounts of alkali and alkaline earth matrices without any loss of adsorption efficiency over prolonged usage were achieved with this resin. The CCTS-DHBA resin was applied to the adsorption/collection of uranium in tap water, river water and seawater samples with satisfactory results. The validation of the proposed method was carried out by analyzing uranium in the standard reference materials of SLRS-4, CASS-4, and NASS-5 after passing through the CCTS-DHBA resin, and the results showed good agreement with the certified values.
en-copyright=
kn-copyright=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=
en-aut-name=HakimLukman
en-aut-sei=Hakim
en-aut-mei=Lukman
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=4
ORCID=
en-aut-name=OshitaKoji
en-aut-sei=Oshita
en-aut-mei=Koji
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=5
ORCID=
en-aut-name=GaoYun Hua
en-aut-sei=Gao
en-aut-mei=Yun Hua
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=6
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=7
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=5
en-affil=
kn-affil=Department of International Conservation Studies, Faculty of International and Industrial Studies, Kibi International University
affil-num=6
en-affil=
kn-affil=Technical Institute of Physics and Chemistry, Chinese Academy of Sciences
affil-num=7
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=Chitosan resin
kn-keyword=Chitosan resin
en-keyword=3,4-dihydroxybenzoic acid
kn-keyword=3,4-dihydroxybenzoic acid
en-keyword=Uranium
kn-keyword=Uranium
en-keyword=Adsorption
kn-keyword=Adsorption
en-keyword=Water
kn-keyword=Water
en-keyword=Inductively coupled plasma-mass spectrometry
kn-keyword=Inductively coupled plasma-mass spectrometry
END
start-ver=1.4
cd-journal=joma
no-vol=588
cd-vols=
no-issue=1
article-no=
start-page=73
end-page=81
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20070404
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Synthesis of novel chitosan resin derivatized with serine diacetic acid moiety and its application to on-line collection/concentration of trace elements and their determination using inductively coupled plasma-atomic emission spectrometry
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A novel chelating resin functionalized with serine diacetic acid moiety was synthesized by using chitosan as base material, and applied to the collection/concentration of trace elements in environmental water samples, followed by the determination using inductively coupled plasma-atomic emission spectrometer (ICP-AES). The synthesized resin, crosslinked chitosan serine diacetic acid (CCTS-SDA), showed good adsorption behavior toward trace amounts of Cd, Pb, Cu, Ni, V, Ga, Sc, In, and Th in a wide pH range. Additionally, rare earth elements also can be retained on the resin at neutral pH region. The adsorbed elements can be easily eluted with 1 mol L-1 of nitric acid, and their recoveries were found to be 90-100%. The CCTS-SDA was packed in a mini-column, which was then installed in a cornputer-controlled auto-pretreatment system (Auto-Pret System) for on-line trace elements collection and determination with ICP-AES. Experimental parameters which related to the improvement of sensitivity and reproducibility were optimized. The limits of detection (LOD) for 13 elements were found to be in sub-ppb level. The proposed method with CCTS-SDA resin was successfully applied to the determination of trace elements in river water samples. The method was validated by determining a certified reference material of river water, SLRS-4.
en-copyright=
kn-copyright=
en-aut-name=LukmanHakim
en-aut-sei=Lukman
en-aut-mei=Hakim
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=chelating resin
kn-keyword=chelating resin
en-keyword=chitosan
kn-keyword=chitosan
en-keyword=serine diacetic acid moiety
kn-keyword=serine diacetic acid moiety
en-keyword=trace elements
kn-keyword=trace elements
en-keyword=on-line pretreatment
kn-keyword=on-line pretreatment
en-keyword=computer control
kn-keyword=computer control
en-keyword=inductively coupled plasma-atomic emission spectrometry
kn-keyword=inductively coupled plasma-atomic emission spectrometry
en-keyword=SLRS-4
kn-keyword=SLRS-4
END
start-ver=1.4
cd-journal=joma
no-vol=532
cd-vols=
no-issue=1
article-no=
start-page=27
end-page=35
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2005
dt-pub=20050507
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Slope comparison method (SCM) for the determination of trace amounts of silicate in ultrapurified water
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A sensitive analytical method for the determination of trace amounts of silicate in ultrapurified water was developed. The method is based on the formation of an ion associate of molybdosilicate with malachite green (MG) and the collection of the ion associate on a tiny membrane filter (diameter: 5 mm, and effective filtering diameter: 1 mm). The ion associate formed on the membrane filter is dissolved together with the membrane filter in 1 ml of methyl cellosolve (MC) and the absorbance of MC solution is measured at 627 nm by a flow injection-spectrophotometric detection technique. In this method, silicate in the original sample (ultrapurified water) is concentrated as the ion associate into a small volume of MC to get high sensitivity. As sample concentration takes place, the small amounts of silicate contained in the reagents used also become concentrated as the ion associate into MC. The original sample volumes are varied and evaporated to an identical volume. Therefore, the reagent added is fixed to the same volume. The absorbance increase linearly with increase in the original sample volume will be due only to silicate in the original samples (ultrapurified water). The resulting slopes obtained by varying the sample volumes are compared with the slope of the calibration graph, and thus named the slope comparison method (SCM). The SCM facilitates a more sensitive and accurate evaluation of silicate concentration in the samples than either common calibration method (CCM) or standard addition method (SAM) because it compensates for the influence of trace amounts of silicate contained in chemicals, reagent solution and solvent used. The calibration graph was constructed from 0 to 0.25 ng ml(-1) of Si and the detection limit was 10 pg ml(-1) (ppt) when 30 ml of samples was used. The standard deviation and relative standard deviation from six measurements of the reagent blanks were 0.0012 and 3.5%, respectively.
en-copyright=
kn-copyright=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=slope comparison method
kn-keyword=slope comparison method
en-keyword=ultrapurified water
kn-keyword=ultrapurified water
en-keyword=ion associate
kn-keyword=ion associate
en-keyword=molybdosilicate
kn-keyword=molybdosilicate
en-keyword=malachite green
kn-keyword=malachite green
en-keyword=membrane filter
kn-keyword=membrane filter
END
start-ver=1.4
cd-journal=joma
no-vol=542
cd-vols=
no-issue=2
article-no=
start-page=207
end-page=215
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2005
dt-pub=20050629
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Synthesis of chitosan resin possessing 3,4-diamino benzoic acid moiety for the collection/concentration of arsenic and selenium in water samples and their measurement by inductively coupled plasma-mass spectrometry
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A chitosan resin functionalized with 3,4-diamino benzoic acid (CCTS-DBA resin) was newly synthesized by using a cross-linked chitosan (CCTS) as base material. The adsorption behavior of trace amounts of elements on the CCTS-DBA resin was examined by the pretreatment with a mini-column and measurement of the elements by inductively coupled plasma-Mass spectrometry (ICP-MS). Arsenic(V) could be retained on the CCTS-DBA resin at pH 3 as an oxoanion of H(2)ASO(4)(-). Selenium(VI) is strongly adsorbed at pH 2 and pH 3 as an oxoanion of SeO42-. while selenium(IV) as HSeO3- is adsorbed on the resin at pH 3. The sorption capacities are 82, 64, and 88 mg g(-1) resin for As(V), Se(IV), and Se(VI), respectively. The effect of common anions and cations on the adsorption of As(V), Se(IV), and Se(VI) were studied; there was no interference from such anionic matrices as chloride, sulfate, phosphate, and nitrate up to 20 ppm, as well as from such artificial river water matrices as Na, K, Mg, and Ca after passing samples through the mini-column containing the resin. The CCTS-DBA resin was applied to the collection of arsenic and selenium species in bottled drinking water, tap water, and river water.
en-copyright=
kn-copyright=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=OshitaKoji
en-aut-sei=Oshita
en-aut-mei=Koji
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=Cross-linked chitosan
kn-keyword=Cross-linked chitosan
en-keyword=3,4-diamino benzoic acid
kn-keyword=3,4-diamino benzoic acid
en-keyword=Arsenic
kn-keyword=Arsenic
en-keyword=Selenium
kn-keyword=Selenium
en-keyword=ICP-MS
kn-keyword=ICP-MS
END
start-ver=1.4
cd-journal=joma
no-vol=72
cd-vols=
no-issue=5
article-no=
start-page=1675
end-page=1680
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20070201
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Flow-Injection Spectrofluorometric Determination of Trace Amounts of Formaldehyde in Water after Derivatization with Acetoacetanilide
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A novel fluorophotometric method for formaldehyde determination in environmental waters was developed: the method does not require any enrichment procedures. A flow-injection analysis method for the spectrofluorometric determination of formaldehyde in waters, which is based on the reaction of formaldehyde with acetoacetanilide and ammonia, is proposed. The proposed method shows a good linearity from 0.50 to 40 x 10(-7) M, and the limit of detection (LOD) of 3 x 10(-9) M (0.09 ppb) is achievable. The sample throughput is 15 h(-1). One of the main advantages in the proposed method is that the reaction can be carried out at room temperature without any heating system. The effect of various interferences possibly present in the real water samples was investigated. Most cations and anions, as well as organic compounds, do not interfere with the determination of formaldehyde in environmental water samples. The proposed method is very simple, rapid, less expensive, and highly sensitive, and can be applied to the environmental water samples, such as rain, tap water and river water, at low concentration levels without any enrichment procedure.
en-copyright=
kn-copyright=
en-aut-name=LiQiong
en-aut-sei=Li
en-aut-mei=Qiong
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=Spectrofluorometric
kn-keyword=Spectrofluorometric
en-keyword=Water samples
kn-keyword=Water samples
en-keyword=Flow-injection
kn-keyword=Flow-injection
en-keyword=Formaldehyde determination
kn-keyword=Formaldehyde determination
en-keyword=Acetoacetanilide
kn-keyword=Acetoacetanilide
END
start-ver=1.4
cd-journal=joma
no-vol=76
cd-vols=
no-issue=5
article-no=
start-page=1256
end-page=1260
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2008
dt-pub=20080523
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Synthesis of chitosan-based resins modified with tris(2-aminoethyl)amine moiety and its application to collection/concentration and determination of trace mercury by inductively coupled plasma atomic emission spectrometry
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A novel chitosan-based chelating resin modified with tris(2-aminoethyl)amine moiety (CCTS-TAA) was synthesized. and its characteristics in the collection/concentration of mercury was examined. The synthesized resin showed good adsorption toward mercury in a wide pH range, and the adsorbed mercury can be easily eluted by using 2 M HNO3 without any addition of complexing agent. The resin was then packed in a mini-column and the mini-column was installed on a computer-controlled automated-pretreatment (Auto-Pret) system coupled with inductively coupled plasma-atomic emission spectroscopy (ICP-AES) for on-line mercury collection and determination at trace level.
en-copyright=
kn-copyright=
en-aut-name=HakimLukman
en-aut-sei=Hakim
en-aut-mei=Lukman
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshitaKoji
en-aut-sei=Oshita
en-aut-mei=Koji
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=4
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=5
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=5
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=resin
kn-keyword=resin
en-keyword=chitosan
kn-keyword=chitosan
en-keyword=tris(2-aminoethyl)amine moiety
kn-keyword=tris(2-aminoethyl)amine moiety
en-keyword=mercury
kn-keyword=mercury
en-keyword=on-line pretreatment
kn-keyword=on-line pretreatment
en-keyword=computer control
kn-keyword=computer control
en-keyword=inductively coupled plasma-atomic
kn-keyword=inductively coupled plasma-atomic
en-keyword=emission spectrometry
kn-keyword=emission spectrometry
END
start-ver=1.4
cd-journal=joma
no-vol=1069
cd-vols=
no-issue=2
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2005
dt-pub=20050502
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Capillary zone electrophoretic studies of ion association between inorganic anions and tetraalkylammonium ions in aqueous-dioxane media
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Ion association between inorganic anions and symmetrical tetraalkylammonium ions, R4N+ (R = Me, Et, Pr, n-Bu, n-Am, and 2-methyl butyl {isoamyl = iAm}) was investigated using ordinary silica capillary by capillary zone electrophoresis. An improved version of the Williams-Vigh method was used for the first time to measure the mobilities of the inorganic anions. Plots of log K-ass against log dielectric constant in various media, revealed a smaller change in K-ass compared to dielectric constant. These plots suggest that the Bjerrum's equation is inadequate in accounting for the associations of ions in a CZE setup.
en-copyright=
kn-copyright=
en-aut-name=MbunaJulius
en-aut-sei=Mbuna
en-aut-mei=Julius
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=aqueous-dioxane media
kn-keyword=aqueous-dioxane media
en-keyword=Williams-Vigh method
kn-keyword=Williams-Vigh method
en-keyword=ion association
kn-keyword=ion association
en-keyword=capillary zone electrophoresis
kn-keyword=capillary zone electrophoresis
END
start-ver=1.4
cd-journal=joma
no-vol=74
cd-vols=
no-issue=4
article-no=
start-page=977
end-page=985
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20070819
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Synthesis of cross-linked chitosan functionalized with threonine moiety and its application to on-line collection/concentration and determination of Mo, V and Cu
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A novel chitosan-based resin functionalized with threonine moiety was synthesized, and applied to the collection/concentration of Mo, V and Cu in environmental water samples, followed by their determination using inductively coupled plasma-atomic emission spectrometer (ICP-AES). The synthesized resin, cross-linked chitosan-threonine (CCTS-Thr), showed good adsorption behavior toward trace amounts of Mo, V and Cu in a wide pH range. The adsorbed elements can be easily eluted using 2 mol L-1 of nitric acid, and their recoveries were found to be 90-100%. The CCTS-Thr was packed in a mini-column, which was then installed in a computer-controlled auto-pretreatment system (Auto-Pret System) for on-line trace elements collection and determination by ICP-AES. Experimental parameters related to the improvement of sensitivity and reproducibility were optimized. The limits of detection (LODs) for target metals were found to be in sub-ppb level. The proposed method with CCTS-Thr resin was successfully applied to the determination of Mo, V and Cu in environmental water samples. The recovery test showed that common matrices which exist in environmental water samples did not interfere with the determination.
en-copyright=
kn-copyright=
en-aut-name=HakimLukman
en-aut-sei=Hakim
en-aut-mei=Lukman
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshitaKoji
en-aut-sei=Oshita
en-aut-mei=Koji
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=4
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=5
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=5
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=resin
kn-keyword=resin
en-keyword=chitosan
kn-keyword=chitosan
en-keyword=threonine moiety
kn-keyword=threonine moiety
en-keyword=molybdenum
kn-keyword=molybdenum
en-keyword=vanadium
kn-keyword=vanadium
en-keyword=copper
kn-keyword=copper
en-keyword=on-line pretreatment
kn-keyword=on-line pretreatment
en-keyword=computer control
kn-keyword=computer control
en-keyword=inductively coupled plasma-atomic emission spectrometry
kn-keyword=inductively coupled plasma-atomic emission spectrometry
END
start-ver=1.4
cd-journal=joma
no-vol=73
cd-vols=
no-issue=5
article-no=
start-page=831
end-page=837
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20070522
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Functionalization of chitosan with 3-nitro-4-amino benzoic acid moiety and its application to the collection/concentration of molybdenum in environmental water samples
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A chitosan resin functionalized with 3-nitro-4-amino benzoic acid moiety (CCTS-NABA resin) was newly synthesized for the collection/concentration of trace molybdenum by using cross-linked chitosan (CCTS) as base material. The carboxyl group of the moiety was chemically attached to amino group of cross-linked chitosan through amide bond formation. The adsorption behavior of molybdenum as well as other 60 elements on the resin was examined by passing the sample solutions through a mini-column packed with the resin. After the elution of the elements collected on the resin with 1 M HNO3, the eluates were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) and atomic emission spectrometry (ICP-AES).
The CCTS-NABA resin can adsorb several metal ions, such as vanadium, gallium, arsenic, selenium, silver, bismuth, thorium, tungsten, tin, tellurium, copper, and molybdenum at appropriate pHs. Among these metal ions, only molybdenum could be adsorbed almost completely on the resin at acidic regions. An excellent selectivity toward molybdenum could be obtained at pH 3-4. The adsorption capacity of CCTS-NABA resin for Mo(VI) was 380 mg g(-1) resin. Through the column pretreatment, alkali and alkaline earth metals in river water and seawater samples were successfully removed.
The CCTS-NABA resin was applied to the adsorption/collection of molybdenum in river water and seawater samples. The concentrations of molybdenum in river water samples were found in the range of 0.84 and 0.95 ppb (ng g(-1)), whereas molybdenum in seawater was about 9 ppb. The validation of the proposed method was carried out by determining molybdenum in the certified reference materials of SLRS-4, CASS-4, and NASS-5 after passing through the CCTS-NABA resin; the results showed good agreement with the certified-values.
en-copyright=
kn-copyright=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=NoguchiOsamu
en-aut-sei=Noguchi
en-aut-mei=Osamu
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Brawijaya University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=chitosan resin
kn-keyword=chitosan resin
en-keyword=3-nitro-4-amino benzoic acid
kn-keyword=3-nitro-4-amino benzoic acid
en-keyword=molybdenum
kn-keyword=molybdenum
en-keyword=adsorption behavior
kn-keyword=adsorption behavior
en-keyword=water and seawater
kn-keyword=water and seawater
en-keyword=ICP-MS
kn-keyword=ICP-MS
en-keyword=ICP-AES
kn-keyword=ICP-AES
en-keyword=certified reference materials
kn-keyword=certified reference materials
END
start-ver=1.4
cd-journal=joma
no-vol=64
cd-vols=
no-issue=5
article-no=
start-page=1259
end-page=1265
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2004
dt-pub=20041215
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Simple flow-injection system for the simultaneous determination of nitrite and nitrate in water samples
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A novel spectrophotometric reaction system was developed for the determination of nitrite as well as nitrate in water samples, and was applied to a flow-injection analysis (FIA). The spectrophotometric flow-injection system coupled with a copperised cadmium reductor column was proposed. The detection was based on the nitrosation reaction between nitrite ion and phloroglucinol (1,3,5-trihydroxybenzene), a commercially available phenolic compound. Sample injected into a carrier stream was split into two streams at the Y-shaped connector. One of the streams merged directly and reacted with the reagent stream: nitrite ion in the samples was detected. The other stream was passed through the copperised cadmium reductor column, where the reduction of nitrate to nitrite occurred, and the sample zone was then mixed with the reagent stream and passed through the detector: the sum of nitrate and nitrite was detected. The optimised conditions allow a linear calibration range of 0.03-0.30 mug NO2--N ml(-1) and 0.10-1.00 mug NO3--N ml(-1). The detection limits for nitrite and nitrate, defined as three times the standard deviation of measured blanks are 2.9 ng NO2--N ml(-1) and 2.3 ng NO3--N ml(-1), respectively. Up to 20 samples can be analyzed per hour with a relative standard deviation of less than 1.5%. The proposed method could be applied successfully to the simultaneous determination of nitrite and nitrate in water samples.
en-copyright=
kn-copyright=
en-aut-name=BurakhamRodjana
en-aut-sei=Burakham
en-aut-mei=Rodjana
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=GrudpanKate
en-aut-sei=Grudpan
en-aut-mei=Kate
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Chiang Mai University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Chiang Mai University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=Flow-injection analysis
kn-keyword=Flow-injection analysis
en-keyword=Phloroglucinol
kn-keyword=Phloroglucinol
en-keyword=Nitrite
kn-keyword=Nitrite
en-keyword=Nitrate
kn-keyword=Nitrate
en-keyword=Simultaneous determination
kn-keyword=Simultaneous determination
END
start-ver=1.4
cd-journal=joma
no-vol=72
cd-vols=
no-issue=5
article-no=
start-page=1609
end-page=1617
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20070118
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Sequential-injection on-line preconcentration using chitosan resin functionalized with 2-amino-5-hydroxy benzoic acid for the determination of trace elements in environmental water samples by inductively coupled plasma-atomic emission spectrometry
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A new chelating resin using chitosan as a base material was synthesized. Functional moiety of 2-amino-5-hydroxy benzoic acid (AHBA) was chemically bonded to the amino group of cross-linked chitosan (CCTS) through the arm of chloromethyloxirane (CCTS-AHBA resin). Several elements, such as Ag, Be, Cd, Co, Cu, Ni, Ph, U, V, and rare earth elements (REEs), could be adsorbed on the resin. To use the resin for on-line pretreatment, the resin was packed in a mini-column and installed into a sequential-injection/automated pretreatment system (Auto-Pret System) coupled with inductively coupled plasma-atomic emission spectrometry (ICP-AES). The sequential-injection/automated pretreatment system was a laboratory-assembled, and the program was written using Visual Basic software. This system can provide easy operation procedures, less reagent consumption, as well as less waste production.
Experimental variables considered as effective factors in the improvement sensitivity, such as an eluent concentration, a sample and an eluent flow rate, pH of samples, and air-sandwiched eluent were carefully optimized. The proposed system provides excellent on-line collection efficiency, as well as high concentration factors of analytes in water samples, which results in highly sensitive detection of ultra-trace and trace analysis. Under the optimal conditions, the detection limits of 24 elements examined are in the range from ppt to sub-ppb levels. The proposed method was validated by using the standard reference material of a river water, SLRS-4, and the applicability was further demonstrated to the on-line collection/concentration of trace elements, such as Ag, Be, Cd, Co, Cu, Ni, Ph, U, V, and REEs in water samples.
en-copyright=
kn-copyright=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=LenghorNarong
en-aut-sei=Lenghor
en-aut-mei=Narong
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=HakimLukman
en-aut-sei=Hakim
en-aut-mei=Lukman
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=4
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=5
ORCID=
en-aut-name=GaoYun-Hua
en-aut-sei=Gao
en-aut-mei=Yun-Hua
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=6
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=7
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=5
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=6
en-affil=
kn-affil=Technical Institute of Physics and Chemistry, Chinese Academy of Sciences (CAS)
affil-num=7
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=sequential-injection
kn-keyword=sequential-injection
en-keyword=on-line preconcentration
kn-keyword=on-line preconcentration
en-keyword=trace elements
kn-keyword=trace elements
en-keyword=ICP-AES
kn-keyword=ICP-AES
en-keyword=chitosan resin
kn-keyword=chitosan resin
END
start-ver=1.4
cd-journal=joma
no-vol=23
cd-vols=
no-issue=12
article-no=
start-page=1431
end-page=1434
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20071211
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Adsorption behavior of cationic and anionic species on chitosan resins possessing amino acid moieties
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Chitosan resins modified with amino acids, such as glycine, valine, leucine, and serine, were synthesized for investigating the adsorption behavior of cationic and anionic species, and showed good abilities for the adsorption of trace elements in aquatic media as follows: glycine for lanthanoids at pH 7, leucine for molybdenum at pH 1 - 5, serine for uranium at pH 2 - 7, and amino acids for bismuth at pH 1 - 7. Cationic and anionic species could be adsorbed by a chelating mechanism and an anion-exchange mechanism.
en-copyright=
kn-copyright=
en-aut-name=OshitaKoji
en-aut-sei=Oshita
en-aut-mei=Koji
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Department of International Conservation Studies for Cultural Properties, Faculty of Cultural Properties, Kibi International University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=CHEMICALLY-MODIFIED CHITOSAN
kn-keyword=CHEMICALLY-MODIFIED CHITOSAN
en-keyword=SELECTIVE ADSORPTION
kn-keyword=SELECTIVE ADSORPTION
en-keyword=ICP-MS
kn-keyword=ICP-MS
en-keyword=COLUMN COLLECTION/CONCENTRATION
kn-keyword=COLUMN COLLECTION/CONCENTRATION
en-keyword=COMPLEXANE TYPES
kn-keyword=COMPLEXANE TYPES
en-keyword=PRECIOUS METALS
kn-keyword=PRECIOUS METALS
en-keyword=DERIVATIVES
kn-keyword=DERIVATIVES
en-keyword=ION
kn-keyword=ION
en-keyword=COPRECIPITATION
kn-keyword=COPRECIPITATION
en-keyword=COPPER(II)
kn-keyword=COPPER(II)
END
start-ver=1.4
cd-journal=joma
no-vol=23
cd-vols=
no-issue=10
article-no=
start-page=1203
end-page=1208
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20071010
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Synthesis of cross-linked chitosan modified with the glycine moiety for the collection/concentration of bismuth in aquatic samples for ICP-MS determination
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A chelating resin, cross-linked chitosan modified with the glycine moiety (glycine-type chitosan resin), was developed for the collection and concentration of bismuth in aquatic samples for ICP-MS measurements. The adsorption behavior of bismuth and 55 elements on glycine-type chitosan resin was systematically examined by passing a sample solution containing 56 elements through a mini-column packed with the resin (wet volume; I ml). After eluting the elements adsorbed on the resin with nitric acid, the eluates were measured by ICP-MS. The glycine-type chitosan resin could adsorb several cations by a chelating mechanism and several oxoanions by an anion-exchange mechanism. Especially, the resin could adsorb almost 100% Bi(III) over a wide pH region from pH 2 to 6. Bismuth could be strongly adsorbed at pH 3, and eluted quantitatively with 10 ml of 3 M nitric acid. A column pretreatment method with the glycine-type chitosan resin was used prior to removal of high concentrations of matrices in a seawater sample and the preconcentration of trace bismuth in river water samples for ICP-MS measurements. The column pretreatment method was also applied to the determination of bismuth in real samples by ICP-MS. The LOD of bismuth was 0.1 pg ml(-1) by 10-fold column preconcentration for ICP-MS measurements. The analytical results for bismuth in sea and river water samples by ICP-MS were 22.9 +/- 0.5 pg ml(-1) (RSD, 2.2%) and 2.08 +/- 0.05 pg ml(-1) (RSD, 2.4%), respectively.
en-copyright=
kn-copyright=
en-aut-name=OshitaKoji
en-aut-sei=Oshita
en-aut-mei=Koji
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=NoguchiOsamu
en-aut-sei=Noguchi
en-aut-mei=Osamu
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Department of International Conservation Studies for Cultural Properties, Faculty of Cultural Properties, Kibi International University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
END
start-ver=1.4
cd-journal=joma
no-vol=66
cd-vols=
no-issue=1
article-no=
start-page=136
end-page=144
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2004
dt-pub=20041208
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Synthesis of cross-linked chitosan possessing N-methyl-D-glucamine moiety (CCTS-NMDG) for adsorption/concentration of boron in water samples and its accurate measurement by ICP-MS and ICP-AES
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A chitosan resin derivatized with N-methyl-(D)-glucamine (CCTS-NMDG) was synthesized by using a cross-linked chitosan (CCTS) as base material. The N-methyl-D-glucamine (NMDG) moiety was attached to the amino group of CCTS through the arm of chloromethyloxirane. The adsorption behavior of 59 elements on the synthesized resin was systematically examined by using the resin packed in a mini-column, passing water samples through it and measuring the adsorbed elements in eluates by ICP-MS. The CCTS-NMDG resin shows high ability in boron sorption with the capacity of 0.61 mmol ml(-1) (= 2.1 mmol g(-1)). The sorption kinetics of this resin was faster than that of the commercially available resins. Other advantages of the synthesized resin are: (1) quantitative collection of boron at neutral pH regions; (2) complete removal of large amounts of matrices; (3) no loss of efficiency over prolonged usage; (4) effective collection of boron in wide range concentration using a mini column containing 1 ml resin; (5) complete elution of boron with 1 mol 1(-1) nitric acid. The resin was applied to the collection/concentration of boron in water samples. Boron in tap water and river water was found to be in the range of 6-8 mu g 1(-1). The limit of detection (LOD) of boron after pretreatment with CCTS-NMDG resin and measurement by ICP-MS was 0.07 mu g 1(-1) and the limit of quantification (LOQ) was 0. 14 mu g 1(-1) when the volume of each sample and eluent was 10 ml.
en-copyright=
kn-copyright=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=OshitaKoji
en-aut-sei=Oshita
en-aut-mei=Koji
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=chitosan resin
kn-keyword=chitosan resin
en-keyword=N-methyl-D-glucamine
kn-keyword=N-methyl-D-glucamine
en-keyword=boron
kn-keyword=boron
en-keyword=adsorption
kn-keyword=adsorption
en-keyword=ICP-MS/AES
kn-keyword=ICP-MS/AES
END
start-ver=1.4
cd-journal=joma
no-vol=612
cd-vols=
no-issue=2
article-no=
start-page=165
end-page=172
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2008
dt-pub=200804
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Development of novel detection reagent for simple and sensitive determination of trace amounts of formaldehyde and its application to flow injection spectrophotometric analysis
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=In this paper, a novel detection reagent for formaldehyde determination is proposed, and is applied to a simple and highly sensitive flow injection method for the spectrophotometric determination of formaldehyde. The method is based on the reaction of formaldehyde with methyl acetoacetate in the presence of ammonia. The increase in the absorbance of the reaction product was measured at 375 nm. An inexpensive light emitting diode (LED)based UV detector (375 nm) was, for the first time, used. Under the optimized experimental conditions, formaldehyde in an aqueous solution was determined over the concentration range from 0.25 to 20.0 x 10(-6) M with a liner calibration graph; the limit of detection (LOD) of 5 x 10(-8) M (1.5 mu g L-1) was possible. The relative standard deviation of 12 replicate measurements of 5 X 10(-6) M formaldehyde was 1.2%. Maximum sampling throughput was about 21 samples/h. The effect of potential interferences such as metals, organic compounds and other aldehyde was also examined. The analytical performance for formaldehyde determination was compared with those obtained by the conventional acetylacetone method, which uses visible absorption spectrophotometry. Finally, the proposed method was successfully applied to the determination of formaldehyde in natural water samples.
en-copyright=
kn-copyright=
en-aut-name=LiQiong
en-aut-sei=Li
en-aut-mei=Qiong
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=SritharathikhumPiyanete
en-aut-sei=Sritharathikhum
en-aut-mei=Piyanete
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=Flow injection
kn-keyword=Flow injection
en-keyword=Formaldehyde determination
kn-keyword=Formaldehyde determination
en-keyword=Spectrophotometry
kn-keyword=Spectrophotometry
en-keyword=Methyl acetoacetate
kn-keyword=Methyl acetoacetate
en-keyword=UV-light emitting diode (LED)
kn-keyword=UV-light emitting diode (LED)
END
start-ver=1.4
cd-journal=joma
no-vol=64
cd-vols=
no-issue=5
article-no=
start-page=1147
end-page=1150
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2004
dt-pub=20040611
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Flow injection spectrophotometry coupled with a crushed barium sulfate reactor column for the determination of sulfate ion in water samples
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A new type of a reactor column, a crushed BaSO4 reactor column used for the flow injection spectrophotometric determination of sulfate ion using the exchange reaction of sulfate ion and barium-dimethylsulfonazo III is proposed. The column is very simple and economical. It can be continuously used for 8 h before washing with water for repeated usage of at least 1 month. The procedure is sensitive. Application to various water samples was demonstrated.
en-copyright=
kn-copyright=
en-aut-name=BurakhamRodjana
en-aut-sei=Burakham
en-aut-mei=Rodjana
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=HiguchiKeiro
en-aut-sei=Higuchi
en-aut-mei=Keiro
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=GrudpanKate
en-aut-sei=Grudpan
en-aut-mei=Kate
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=4
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=5
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Chiang Mai University
affil-num=2
en-affil=
kn-affil=FIA Instruments Co., Ltd.
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Chiang Mai University
affil-num=5
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=Sulfate
kn-keyword=Sulfate
en-keyword=Dimethylsulfonazo III
kn-keyword=Dimethylsulfonazo III
en-keyword=On-line reactor column
kn-keyword=On-line reactor column
en-keyword=Flow injection analysis
kn-keyword=Flow injection analysis
en-keyword=Spectrophotometry
kn-keyword=Spectrophotometry
END
start-ver=1.4
cd-journal=joma
no-vol=24
cd-vols=
no-issue=5
article-no=
start-page=665
end-page=668
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2008
dt-pub=20080510
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Adsorption Properties of Ionic Species on Cross-linked Chitosans Modified with Catechol and Salicylic Acid Moieties
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Catechol-type chitosan resin and salicylic acid-type chitosan resin were easily synthesized for use in estimating the adsorption behavior of 34 elements at pH 1 - 7 in aquatic media. The catechol-type chitosan resin could adsorb Cu(II) at pH 3 - 7, In(III) at pH 4 - 6, Pb(II) and lanthanoids at pH 5 - 7, and U(VI) at pH 4 - 7 more effectively than the salicylic acid-type chitosan resin and the cross-linked chitosan resin (base material). Adsorption ability was in the order: catechol-type chitosan resin > salicylic acid-type chitosan resin > cross-linked chitosan resin.
en-copyright=
kn-copyright=
en-aut-name=OshitaKoji
en-aut-sei=Oshita
en-aut-mei=Koji
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Department of International Conservation Studies for Cultural Properties, Faculty of Cultural Properties, Kibi International University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=CHEMICALLY-MODIFIED CHITOSAN
kn-keyword=CHEMICALLY-MODIFIED CHITOSAN
en-keyword=SELECTIVE ADSORPTION; ICP-MS
kn-keyword=SELECTIVE ADSORPTION; ICP-MS
en-keyword=COLUMN COLLECTION/CONCENTRATION
kn-keyword=COLUMN COLLECTION/CONCENTRATION
en-keyword=COMPLEXANE TYPES
kn-keyword=COMPLEXANE TYPES
en-keyword=PRECIOUS METALS
kn-keyword=PRECIOUS METALS
en-keyword=DERIVATIVES
kn-keyword=DERIVATIVES
en-keyword=COPRECIPITATION
kn-keyword=COPRECIPITATION
en-keyword=COPPER(II)
kn-keyword=COPPER(II)
en-keyword=BEHAVIOR
kn-keyword=BEHAVIOR
END
start-ver=1.4
cd-journal=joma
no-vol=481
cd-vols=
no-issue=2
article-no=
start-page=311
end-page=319
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2003
dt-pub=20030403
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Ultratrace determination of phosphorus in ultrapurified water by a slope comparison method
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=The analytical method for the determination of phosphorus in ultrapurified water was developed. Ultrapurified water was evaporated to concentrate phosphorus and the final sample volume for analysis was 10 ml. In 0.55 mol 1(-1) HCl, orthophosphate forms molybdophosphate, and then the molybdophosphate forms ion associate with Malachite Green (MG), which can be collected on a tiny membrane filter (diameter: 5 mm, and effective filtering diameter: 2 mm). After the ion associate on the membrane filter is dissolved together with the membrane filter in I ml of methyl cellosolve (MC), the absorbance of MC solution is measured at 627 nm by a flow injection-spectrophotometric detection technique. When 10 ml of the sample solution was used for the procedures and absorbance measurement, the calibration graph is linear up to about 500 ng 1(-1) of phosphorus and the detection limit was 8 ng 1(-1) (S/N = 3). For the determination of phosphorus in an ultrapurified water, 10-40 ml of sample solutions were transferred into poly(tetrafluoroethylene) (PTFE) beaker and evaporated to 5 ml or to dryness. To them, 0.003 mol 1(-1) HCl was added to get 10 ml of final solution, which was used as sample. Phosphate is determined by comparing the slope of the varied sample volume after evaporation/concentration with a slope of the standard calibration graph (a slope comparison method: SCM). The SCM enables to evaluate the concentration of phosphate in ultrapurified waters more sensitively and accurately.
en-copyright=
kn-copyright=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=ultrapurified water
kn-keyword=ultrapurified water
en-keyword=evaporation/concentration
kn-keyword=evaporation/concentration
en-keyword=ion associate
kn-keyword=ion associate
en-keyword=molybdophosphate
kn-keyword=molybdophosphate
en-keyword=malachite green
kn-keyword=malachite green
en-keyword=slope comparison method
kn-keyword=slope comparison method
END
start-ver=1.4
cd-journal=joma
no-vol=22
cd-vols=
no-issue=1
article-no=
start-page=161
end-page=164
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2006
dt-pub=20060224
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Speciation of chromium in seawater by ICP-AES with dual mini-columns containing chelating resin
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A method for the preconcentration and speciation of chromium in seawater was developed. On-line preconcentration and determination were carried out by using inductively coupled plasma atomic emission spectrometry (ICP-AES) with dual mini-columns containing a chelating resin. In this system, Cr(III) was collected on the first column. The effluent containing residual chromium from the first column was collected on the second column after passing through a reduction-switching unit, in which the reducing agent was introduced, or not, for the reduction of Cr(VI) to Cr(Ill). Cr(VI) was determined as the difference between the concentration of pre-reduced Cr(VI) and Cr(III) in the effluent from the first column. The detection limits for Cr(III) and Cr(VI) were 0.04 and 0.09 mu g l(-1), respectively.
en-copyright=
kn-copyright=
en-aut-name=SumidaTakashi
en-aut-sei=Sumida
en-aut-mei=Takashi
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=Kochi Prefectual Industrial Technology Center
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=ONLINE PRECONCENTRATION
kn-keyword=ONLINE PRECONCENTRATION
en-keyword=SPECTROMETRY
kn-keyword=SPECTROMETRY
END
start-ver=1.4
cd-journal=joma
no-vol=159
cd-vols=
no-issue=3-4
article-no=
start-page=341
end-page=348
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20070426
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Application of chitosan functionalized with 3,4-dihydroxy benzoic acid moiety for on-line preconcentration and determination of trace elements in water samples
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Chitosan resin functionalized with 3,4-dihydroxy benzoic acid (CCTS-DHBA resin) was used as a packing material for flow injection (FI) on-line mini-column preconcentration in combination with inductively coupled plasma-atomic emission spectrometry (ICP-AES) for the determination of trace elements such as silver, bismuth, copper, gallium, indium, molybdenum, nickel, uranium, and vanadium in environmental waters. A 5-mL aliquot of sample (pH 5.5) was introduced to the minicolumn for the adsorption/preconcentration of the metal ions, and the collected analytes on the mini-column were eluted with 2 M HNO3, and the eluates was subsequently transported via direct injection to the nebulizer of ICP-AES for quantification. The parameters affecting on the sensitivity, such as sample pH, sample flow rate, eluent concentration, and eluent flow rate, were carefully examined. Alkali and alkaline earth metal ions commonly existing in river water and seawater did not affect the analysis of metals. Under the optimum conditions, the method allowed the determination of metal ions with detection limits of 0.08 ng mL(-1) (Ag), 0.9 ng mL(-1) (Bi), 0.07 ng mL(-1) (Cu), 0.9 ng mL(-1) (Ga), 0.9 ng mL(-1) (In), 0.08 ng mL(-1) (Mo), 0.09 ng mL(-1) (Ni), 0.9 ng mL(-1) (U), and 0.08 ng mL(-1) (V). By using 5 mL of sample solution, the enrichment factor and collection efficiency were 8-12 fold and 96-102%, respectively, whereas the sample throughput was 7 samples/hour. The method was validated by determining metal ions in certified reference material of river water (SLRS-4) and nearshore seawater (CASS-4), and its applicability was further demonstrated to river water and seawater samples.
en-copyright=
kn-copyright=
en-aut-name=SabarudinAkhmad
en-aut-sei=Sabarudin
en-aut-mei=Akhmad
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=NoguchiOsamu
en-aut-sei=Noguchi
en-aut-mei=Osamu
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=HiguchiKeiro
en-aut-sei=Higuchi
en-aut-mei=Keiro
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=4
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=5
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=2
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=3
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
affil-num=4
en-affil=
kn-affil=FIA Instruments Division, Ogawa and Co.
affil-num=5
en-affil=
kn-affil=Department of Chemistry, Faculty of Science, Okayama University
en-keyword=flow injection
kn-keyword=flow injection
en-keyword=chitosan resin
kn-keyword=chitosan resin
en-keyword=on-line preconcentration
kn-keyword=on-line preconcentration
en-keyword=3
kn-keyword=3
en-keyword=4-dihydroxy benzoic acid
kn-keyword=4-dihydroxy benzoic acid
en-keyword=ICP-AES
kn-keyword=ICP-AES
END
start-ver=1.4
cd-journal=joma
no-vol=17
cd-vols=
no-issue=
article-no=
start-page=49
end-page=55
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1995
dt-pub=19951220
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Determination of Inorganic Anions in Environmental Samples by Capillary Electrophoresis
kn-title=キャピラリー電気泳動法による環境試料中の無機陰イオンの定量
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Several inorganic anions in environmental water samples, such as river, rain, tap, and waste waters, were determined by capillary electrophoresis with indirect photometric UV detection. In this study, the use of a polymer coated silica capillary and an anionic organic photometric reagent realized a stable baseline and short analytical time. Nine kinds of anions, Cl(-), Br(-), NO(3)(-), SO(4)(2-), C(2)O(4)(2-), ClO(4)(-), F(-), HPO(4)(2-), and HCO(3)(-), were well separated and detected within 12 minutes. Calibration graphs for the anions showed a good linearity in the range of 0 to 4x10(-4) mol dm(-3). Detection limits of the anions were 2x10(-6) mol dm(-3) (HPO(4)(2-)) to 4x10(-5) mol dm(-3) (NO(2)(-)). Anions in river water (Zasu river) and waste water (Okayama University, North district) were measured over 5 days. The waste water contained various kinds of anions, at high concentrations with its large variation, when compared with the river water. The proposed method offers a simple, rapid, and accurate analysis of anions in water samples.
en-copyright=
kn-copyright=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=高柳俊夫
kn-aut-sei=高柳
kn-aut-mei=俊夫
aut-affil-num=1
ORCID=
en-aut-name=WadaEiko
en-aut-sei=Wada
en-aut-mei=Eiko
kn-aut-name=和田栄子
kn-aut-sei=和田
kn-aut-mei=栄子
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=2
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=3
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=4
en-affil=
kn-affil=岡山大学理学部化学科
END
start-ver=1.4
cd-journal=joma
no-vol=21
cd-vols=
no-issue=
article-no=
start-page=4
end-page=10
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1999
dt-pub=199908
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Determination of trace metals in environmental water samples by inductively coupled plasma - mass spectrometry (ICP-MS)
kn-title=誘導結合プラズマ―質量分析法による環境水中の微量金属の定量
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Trace metals in water samples, such as tap water, river water, and sea water, were determined by inductively coupled plasma-mass spectrometry (ICP-MS). ICP-MS has sufficient sensitivity to detect even below the concentrations of ppt level, and therefore the samples were not pretreated with a concentration column. Practical samples were diluted by lo-fold with ultrapure water and measured directly by ICP-MS. The measuring time of one sample was 2.5 min, and the data for 30 elements were obtained simultaneously. The concentrations of heavy metals, such as Cr, Mn, Co, Ni, Cu, Zn, As, Cd, Sb, and Pb, in the water samples were in the ranges of 0.05~82ng/ml. Zasu river and Sibukawa (sea water) contained various kinds of metals, and the concentration ranges were spread in a wide range; for example, Mg was 25700 ppb and In was 2 ppt. ICP-MS is found to be a useful and a powerful instrument for trace amounts of elements, and can be applied satisfactorily to the environmental water analysis.
en-copyright=
kn-copyright=
en-aut-name=LeeKyue-Hyung
en-aut-sei=Lee
en-aut-mei=Kyue-Hyung
kn-aut-name=李啓熒
kn-aut-sei=李
kn-aut-mei=啓熒
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=高柳俊夫
kn-aut-sei=高柳
kn-aut-mei=俊夫
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=2
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=3
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=4
en-affil=
kn-affil=岡山大学理学部化学科
END
start-ver=1.4
cd-journal=joma
no-vol=25
cd-vols=
no-issue=
article-no=
start-page=37
end-page=42
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2003
dt-pub=200308
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=岡山大学周辺の割川水の長期定量データの解析
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=HamasakiKayoko
en-aut-sei=Hamasaki
en-aut-mei=Kayoko
kn-aut-name=濵崎佳代子
kn-aut-sei=濵崎
kn-aut-mei=佳代子
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学理学部
affil-num=2
en-affil=
kn-affil=岡山大学理学部
END
start-ver=1.4
cd-journal=joma
no-vol=3
cd-vols=
no-issue=3
article-no=
start-page=265
end-page=269
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1987
dt-pub=19870610
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Spectrophotometric Determination of Anionic Surfactants in River Water with Cationic AZO Dye by Solvent Extraction- Flow Injection Analysis
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Anionic surfactants in water were determined by a spectrophotometric flow injection technique coupled with solvent extraction. The ion associate which formed between an anionic surfactant and an cationic azo dye was extracted into an organic solvent and the absorbance was measured. The carrier was distilled water, and the reagent solution contained an cationic azo dye and sodium sulfate, the pH of which being adjusted to 5 with acetate buffer. A phase separator with a poly(tetrafluoroethylene) porous membrane (0.8μm pore size) was used to separate the organic phase. Six derivatives of cationic azo dyes and several extracting solvents were examined; a pair of 1-methyl-4-(4-diethylaminophenylazo)- pyridinium cation and chloroform turned out best. The sampling rate was 30 samples per hour. Calibration graphs were linear up to 2×10(-6)M or 3×10(-5)M of anionic surfactant when injection volume was 300 or 100μl, respectively. The relative standard deviation(n=10) was 1.5% for 300μl of 1×10(-6)M sodium dodecylsulfate. The detection limit was as little as 1×10(-8)M of anionic surfactant. Anionic surfactants in river water were determined satisfactorily.
en-copyright=
kn-copyright=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=1
ORCID=
en-aut-name=HazakiYoshito
en-aut-sei=Hazaki
en-aut-mei=Yoshito
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=ToeiKyoji
en-aut-sei=Toei
en-aut-mei=Kyoji
kn-aut-name=桐栄恭二
kn-aut-sei=桐栄
kn-aut-mei=恭二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
affil-num=4
en-affil=
kn-affil=岡山大学
en-keyword=Anionic surfactant determination
kn-keyword=Anionic surfactant determination
en-keyword=cationic azo dye
kn-keyword=cationic azo dye
en-keyword=ion associate extraction
kn-keyword=ion associate extraction
en-keyword=spectrophotometry
kn-keyword=spectrophotometry
en-keyword=flow injection analysis
kn-keyword=flow injection analysis
END
start-ver=1.4
cd-journal=joma
no-vol=5
cd-vols=
no-issue=6
article-no=
start-page=767
end-page=769
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1989
dt-pub=19891210
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Flotation/Extraction and Spectrophotometric Determination of Silicate with Molybdate and Cationic Dyes
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=IkegamiTomoko
en-aut-sei=Ikegami
en-aut-mei=Tomoko
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
en-keyword=Silicate determination
kn-keyword=Silicate determination
en-keyword=ion association complex
kn-keyword=ion association complex
en-keyword=heteropolyacid
kn-keyword=heteropolyacid
en-keyword=cationic dyes
kn-keyword=cationic dyes
en-keyword=flotation
kn-keyword=flotation
en-keyword=extraction
kn-keyword=extraction
END
start-ver=1.4
cd-journal=joma
no-vol=5
cd-vols=
no-issue=1
article-no=
start-page=85
end-page=88
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1989
dt-pub=19890210
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Spectrophotometric Determination of Silicate in Water with Molybdate and Malachite Green
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=On the basis of the coloration formed with molybdosilicate and Malachite Green in aqueous solution, trace amounts of silicate were determined. In an acidic medium, silicate reacted with molybdate to form molybdosilicate, which reacted with Malachite Green to form a colored ion association complex. The color was stabilized by adding poly(vinyl alcohol). The molar absorptivity was 1.0×10(5)mol(-1)cm(-1) at 595nm, and the absorbance of the reagent blank was 0.089. The recommended concentration range of silicon was 0.1-5μg and the limit of detection was 0.01μg of silicon. Silicate in river and tap waters was determined.
en-copyright=
kn-copyright=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=OjimaYuka
en-aut-sei=Ojima
en-aut-mei=Yuka
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
en-keyword=Spectrophotometry
kn-keyword=Spectrophotometry
en-keyword=silicate determination
kn-keyword=silicate determination
en-keyword=molybdate
kn-keyword=molybdate
en-keyword=Malachite Green
kn-keyword=Malachite Green
en-keyword=ion association complex
kn-keyword=ion association complex
END
start-ver=1.4
cd-journal=joma
no-vol=6
cd-vols=
no-issue=4
article-no=
start-page=627
end-page=628
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1990
dt-pub=19900810
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Fluorometric Determination of Boric Acid by High Performance Liquid Chromatography after Derivatization with Chromotropic Acid
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=1
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=2
ORCID=
en-aut-name=JinZou
en-aut-sei=Jin
en-aut-mei=Zou
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=6
cd-vols=
no-issue=2
article-no=
start-page=215
end-page=220
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1990
dt-pub=19900410
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Spectrophotometric Determination of Calcium with Dicyclohexano- 24-crown-8 and Propyl Orange by Solvent Extraction/Flow Injection Method
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Calcium in water was determined by a spectrophotometric method involving flow injection coupled with solvent extraction. An ion association complex which formed between a calcium-crown complex ion and a dye anion was extracted into an organic solvent and the absorbance of the organic phase was measured after phase separation. Six derivatives of alkylaminophenylazobenzene sulfonic acid and tetrabromophenolphthalein ethylester were examined as counter anions with dicyclohexano-24-crown-8, and a mixture of benzene and chlorobenzene was examined as an extraction solvent. A suitable method for calcium determination in water was one with Propyl Orange and a (1+1 v/v) mixture of benzene and chlorobenzene. The carrier stream was distilled water, while the reagent stream was comprised of a dye anion and lithium hydroxide. The sampling rate was 20-30 per hour. The calibration graph was linear at concentrations up to 10(-4)M using samples of 100μl. The detection limit corresponding to a signal-to-noise ratio of 3 was 2×10(-7)M; the relative standard deviation was 0.99% for 10 injections of 5×10(-5)M calcium solution. Calcium in river water was determined satisfactorily by the proposed method.
en-copyright=
kn-copyright=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=YonedaNaomi
en-aut-sei=Yoneda
en-aut-mei=Naomi
kn-aut-name=米田直生
kn-aut-sei=米田
kn-aut-mei=直生
aut-affil-num=3
ORCID=
en-aut-name=IwashidoTadashi
en-aut-sei=Iwashido
en-aut-mei=Tadashi
kn-aut-name=岩知道正
kn-aut-sei=岩知道
kn-aut-mei=正
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
affil-num=4
en-affil=
kn-affil=岡山大学
en-keyword=Calcium, Propyl Orange
kn-keyword=Calcium, Propyl Orange
en-keyword=dicyclohexano-24-crown-8
kn-keyword=dicyclohexano-24-crown-8
en-keyword=spectrophotometry
kn-keyword=spectrophotometry
en-keyword=solvent extraction
kn-keyword=solvent extraction
en-keyword=flow-injection method
kn-keyword=flow-injection method
END
start-ver=1.4
cd-journal=joma
no-vol=8
cd-vols=
no-issue=5
article-no=
start-page=619
end-page=625
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1992
dt-pub=19921010
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Separation and Determination of Alkaline-Earth Metal Ions as UV- Absorbing Chelates with EDTA by Capillary Electrophoresis. Determination of Calcium and Magnesium in Water and Serum Samples
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Capillary electrophoresis of alkaline-earth metal ions was examined with a UV-absorbing chelating agent. The metal1 chelates separated in a capillary were measured by on-column UV-absorptive detection. When ethylenediamine-tetraacetic acid (EDTA) was used as an chelating agent in a carrier solution (pH 9.2), the order of the migration time (t(m)) of metal ions was as follows: Ba(2+)3位>2位置換体の順に小さくなる.2位置換体は隣接のN-置換基との重なり効果の結果,3,4位置換体よりも小さくなる.基本骨格(C(5)H(5)N(+)-)の抽出性の尺度(C:>N(+)<を基準C=0とする)は約2.2となり,メチレン基の数から単純計算した値(0.59×5=2.95)よりも0.75小さい.これはベンゼン環(-C(6)H(5))の単純計算値と実測値との差(0.64)とほぼ一致しており,閉環効果による抽出性(疎水性)の減少分と見なされる.
en-copyright=
kn-copyright=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=YanHu
en-aut-sei=Yan
en-aut-mei=Hu
kn-aut-name=胡焔
kn-aut-sei=胡
kn-aut-mei=焔
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
en-keyword=alkyl-N-alkylpyridinium derivatives
kn-keyword=alkyl-N-alkylpyridinium derivatives
en-keyword=dichloro derivatives of Ethyl Orange
kn-keyword=dichloro derivatives of Ethyl Orange
en-keyword=extractability of ion associates
kn-keyword=extractability of ion associates
en-keyword=contribution of substituents to extractability
kn-keyword=contribution of substituents to extractability
END
start-ver=1.4
cd-journal=joma
no-vol=42
cd-vols=
no-issue=9
article-no=
start-page=T123
end-page=T128
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1993
dt-pub=19930905
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Assembly of a new gas-diffusion unit and its application to the determination of total carbonate and ammoniacal nitrogen by FIA.
kn-title=新規ガス透過装置の試作とそれを用いるフローインジェクション分析法による天然水中の総炭酸及びアンモニア態窒素の吸光光度定量
en-subtitle=
kn-subtitle=
en-abstract=A new gas-diffusion unit was constructed and applied to determine total carbonate or ammoniacal nitrogen in water by spectrophotometric FIA. The gas diffusion unit, which was constructed without any glue, could be assembled easily by fastening the screws to tee connectors with ferrules. The new gas-diffusion unit was improved to decrease the dead volume. The unit gave sharper peaks than the previous one, and peaks higher by 10% in the case of CO(2) determination. The gas-diffusion part consisted of an inner microporous polytetrafluoroethylene (PTFE) tube (GORE-TEX®, 1.0 mm i.d., 1.8 mm o.d., pore size 2.0 μm, porosity 50%) and an outer PTFE tube (2.0 mm i.d., 3.0 mm o.d.). Sample solution was injected into the carrier solution (CS), in which the analyte was converted to a gaseous substance which passed through the microporous PTFE membrane to be mixed with the reagent solution (RS) flowing in the space between the outer and the inner tubings. The resulting pH shift caused the color of the indicator in RS to change. The conditions for the determination of total carbonate are as folows; CS was 1.8X×10(-3) mol dm(-3) H(2)SO(4), RS contained Cresol Red (at pH 9.0) and the detection wavelength was 410 nm. The detection limit was 0.96 mg dm(-3) CO(2) (S/N=3), the response was linear up to 172 mg dm(-3), and the sampling rate was 20 h(-1). For ammoniacal nitrogen, CS was 10(-2) mol dm(-3) NaOH, RS contained Cresol Red (pH 7.0) and absorbance was measured at 550 nm. The detection limit was 30μg dm(-3)NH(4)(+)-N (S/N=3), the response was linear up to 3.5 mg dm(-3), and the sampling rate was 30 h(-1). Total carbonate and ammoniacal nitrogen in river and seawater samples were determined satisfactorily.
kn-abstract=今回新たに多孔質PTFE(polytetrafluoroethylene)チューブを分離膜とするガス透過装置を試作し,その性能について総炭酸定量用FIA装置を用いて検討した.新しいガス透過装置は組み立てが簡単で,前回製作のものに比べ,約10%の感度向上が達成され,更にピークのテイリングも減少した.本装置を組み込んだFIAにより環境水中の総炭酸,アンモニア態窒素の定量が可能である.いずれの場合もpH変化に伴うクレゾールレッドの呈色変化を測定に利用した.本法によれば多孔質ガス透過チューブ長8cmのとき,172mg dm(-3)(4×10(-3)mol dm(-3))以下の総炭酸を1時間当たり20試料,3.6mg dm(-3)(2.6×10(-4)mol dm(-3))以下のアンモニア態窒素を1時間当たり30試料の速さで測定できた.この際の検出限界(S/N=3に相当)は総炭酸の場合,0.96mg dm(-3)(2×10(-5)mol dm(-3)),アンモニア態窒素の場合は30μg dm(-3)(2×10(-6)mol dm(-3))であった.
en-copyright=
kn-copyright=
en-aut-name=SanadaMasahiro
en-aut-sei=Sanada
en-aut-mei=Masahiro
kn-aut-name=真田昌宏
kn-aut-sei=真田
kn-aut-mei=昌宏
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
en-keyword=FIA with gas-diffusion unit
kn-keyword=FIA with gas-diffusion unit
en-keyword=tubular microporous polytetrafluoroethylene
kn-keyword=tubular microporous polytetrafluoroethylene
en-keyword=determination of total carbonate and ammoniacal nitrogen
kn-keyword=determination of total carbonate and ammoniacal nitrogen
END
start-ver=1.4
cd-journal=joma
no-vol=42
cd-vols=
no-issue=3
article-no=
start-page=151
end-page=157
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1993
dt-pub=19930305
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Determination of phosphate and arsenate by a flotation-pairing ion exchange/extraction method
kn-title=フローテーション/対イオン交換抽出法による極微量リン酸及びヒ酸の吸光光度定量
en-subtitle=
kn-subtitle=
en-abstract=Flotation-pairing ion exchange-extraction and spectrophotometric determination of trace amounts of phosphate and arsenate were examined. Ion association complexes of heteropoly acids and a bulky cationic dye floated on the interface between an aqueous and a less polor organic solvent phase. After the flotation, the heteropoly acids were exchanged for an anionic dye, which have a high molar absorptivity and the similar maximum absorption wavelength to the cationic dye. The sum of the absorbances of the cationic and the anionic dyes was measured. In this work, malachite green (MG(+)) and 4'-hydroxy-3,5,3',5',2",6"-hexachlorofuchsone (Cl(6)BZ), a hexachloro derivative of benzaurin, were used as a cationic and an anionic dye. The recommended procedure for phosphate determination is as follows. To a 50-cm(3) separatory funnel, take sample solution (up to 10 cm(3)); if arsenate coexists, add 0.1 cm3 of 2×10(-2) M Na(2)S(2)O(3) to reduce arsenate to arsenite. Then, add 1 cm(3) of 10 M hydrochloric acid, 1 cm(3) of 0.4 M (as Mo) molybdate, 0.5 cm(3) of 5×10(-4) M Malachite Green, and 2 cm(3) of flotation solvent (Isobutyl methyl ketone + cyclohexane= 1 +8 v/v). After shaking for 5 min, discard the aqueous phase, and wash the organic phase 2 times with 5 cm(3) of water. After 1 cm(3) of 2×10(-4) M anionic dye solution, 8 cm(3) of 1, 2-dichloroethane and 5 cm(3) of borax buffer (pH 9) are added, shake 10 times by hands. After the phase separation, measure the absorbance of the organic phase at 620 nm. As arsenate reacts under the same conditions as phosphate, arsenate can be determined by subtracting the amounts of phosphate from the total amounts of phosphate and arsenate which were obtained in the absence of Na(2)S(2)O(3). The apparent molar absorptivity of phosphate or arsenate was 5.7×10(5) dm(3) mol(-1) cm(-1), and the absorbance of the reagent blank was 0.005. Six times concentration was achieved when 30 cm(3) of aqueous phase and 5 cm(3) of extraction solvent were used. Bulky anionic ions, such as iodide, perchlorate and lauryl sulfate, did not interfere with the determination of phosphate and arsenate. This method was applied to the determination of phosphate in seawater and iron and steel samples.
kn-abstract=フローテーション/対イオン交換抽出法を用いる極微量リン酸,及びヒ酸の吸光光度定量法を確立した.オルトリン酸とモリブデン酸との反応により生成したモリブドリン酸にマラカイトグリーン(MG(+))をイオン会合させ,この会合体を水相と有機相(シクロヘキサン+イソブチルメチルケトン=8+1v/v)の界面にフローテーションさせる.この後,MG(+)と近い極大吸収波長をもつ染料陰イオン(A(-)と略記)とモリブドリン酸を交換し,(MG(+)・A(-))イオン会合体を有機相(フローテーション溶媒+1,2-ジクロロエタン)に抽出する.ヒ酸も類似のイオン会合体を形成するため,同様にして定量することができる.A-としては新規合成酸性染料の4'-ヒドロキシ-3,5,3',5',2",6"-ヘキサクロロフクソン(以後,Cl(6)BZと略記)を用いた.リンを基準とした見掛けのモル吸光係数は620nmで5.7×10(5)dm(3)mol(-1)cm(-1)であった.この方法によるRSDは1×10(-6)Mのリン酸で0.29%(n=10)であった.本法は試薬から試験値が0.005と低く,6倍の濃縮も可能であり,これによりsub-ppb(10(-10)gml(-1))レベルのリンの定量が可能となった.又ヨウ化物イオン,過塩素酸イオン,ラウリル硫酸イオンなどのイオン会合抽出されやすい疎水性イオンの影響は,溶媒抽出法に比べはるかに小さいことが分かった.本法を海水,鉄鋼試料中のリン,ヒ素の定量に応用した.
en-copyright=
kn-copyright=
en-aut-name=GotoNobutake
en-aut-sei=Goto
en-aut-mei=Nobutake
kn-aut-name=後藤伸武
kn-aut-sei=後藤
kn-aut-mei=伸武
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
en-keyword=flotation-pairing ion-exchange-extraction
kn-keyword=flotation-pairing ion-exchange-extraction
en-keyword=heteropoly acid
kn-keyword=heteropoly acid
en-keyword=determination of phosphate and arsenate
kn-keyword=determination of phosphate and arsenate
en-keyword=Malachite Green and 4'-hydroxy-3,5,3',5',2
kn-keyword=Malachite Green and 4'-hydroxy-3,5,3',5',2
en-keyword=spectrophotometry
kn-keyword=spectrophotometry
END
start-ver=1.4
cd-journal=joma
no-vol=43
cd-vols=
no-issue=8
article-no=
start-page=621
end-page=628
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1994
dt-pub=19940805
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Separation and determination of metal ions with 2-nitroso-1-naphthol-4-sulfonic acid by high-performance capillary electrophoresiscapillary electrophoresis
kn-title=キャピラリー電気泳動法による2-ニトロソ-1-ナフトール4-スルホン酸を用いる金属イオンの分離・定量
en-subtitle=
kn-subtitle=
en-abstract=Capillary electrophoresis study was carried out by using 2-nitroso-1-naphthol-4-sulfonic acid (nitroso-NW acid) as a chelating and chromogenic agent. Nitroso-NW acid (H2R) reacts with Co(2+) to form the chelate anion, CoR(3)(3-) and also reacts with Fe(2+), Ni(2+), Cu(2+) and Pd(2+). However, except for Ni(2+) and Cu(2+), sharp peaks could not be obtained with a conventional carrier containing HR-and buffer components. This is probably because the metal chelates were highly charged: the chelates of Ni(2+), Cu(2+), Fe(2+), Co(2+) and Pd(2+) are expected to be CuR(2)(2-), Fe(II)R(3)(4-) Co(III)R(3)(3-), NiR(3)(4-) and Pd(OH)(2)(2) R(-), from their electrophoretic mobilities. The peaks of Fe(2+), Co(2+) and Pd(2+) were sharpend by adding a quaternary ammonium ion to the carrier. The quaternary ammonium ion in the carrier acts as a pairing cation of metal chelate anions. Of these, tetrabutylammonium ion(TBA(+)) was the best pairing ion for the metal chelates. By using a carrier containing HR(-), TBA(+) ·Br(-) and buffer components (pH 7), good separation and highly sensitive detection of the five metal ions (Fe(2+), Co(2+), Ni(2+), Cu2+and Pd2+) could be achieved within 7 min. The proposed method was applied to the determination of cobalt in nickel salts.
kn-abstract=2-ニトロソ-1-ナフトール-4-スルホン酸(ニトロソ-NW酸)の金属キレート(Fe(2+),Co(2+),Ni(2+),Cu(2+)及びPd(2+))をキャピラリー電気泳動により分離した.通常の泳動液(ニトロソ-NW酸と緩衝剤の混合液)では,Ni(2+),Cu(2+)のみが鋭いピークを与えた.泳動液中に第四級アンモニウムイオンを加えると,ブロードなピークであったFe(2+),Co(2+),Pd(2+)も鋭いピークとなった.泳動液中に添加する第四級アンモニウムイオンの種類と濃度の影響を調べたところ,疎水性のイオンほど,又高濃度ほどキレートの移動度(絶対値)は小さくなることが分かった.これは,第四級アンモニウムイオンがキレート陰イオンと一部イオン会合体を形成し,実質的電荷を下げていることによると考えられる.泳動液組成の最適化を検討した結果,テトラブチルアンモニウムイオンを用いることにより,上述の5種の金属イオンの良好な分離と同時定量が可能となった.本法により,市販ニッケル塩中の微量コバルトの定量を行った.
en-copyright=
kn-copyright=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=1
ORCID=
en-aut-name=KuwabaraMasayosi
en-aut-sei=Kuwabara
en-aut-mei=Masayosi
kn-aut-name=桑原正良
kn-aut-sei=桑原
kn-aut-mei=正良
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
en-keyword=high-performance capillary electrophoresis
kn-keyword=high-performance capillary electrophoresis
en-keyword=metal ions
kn-keyword=metal ions
en-keyword=2-nitroso-1-naphthol-4-sulfonic acid
kn-keyword=2-nitroso-1-naphthol-4-sulfonic acid
en-keyword=ion-association
kn-keyword=ion-association
END
start-ver=1.4
cd-journal=joma
no-vol=47
cd-vols=
no-issue=8
article-no=
start-page=513
end-page=517
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1998
dt-pub=19980805
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Highly sensitive graphite-furnace AAS of lead using a miniaturemembrane concentration/dissolution method
kn-title=微小膜濃縮/黒鉛炉原子吸光法による鉛の高感度定量
en-subtitle=
kn-subtitle=
en-abstract=極微量の鉛イオンを定量するための濃縮法として,膜濾過捕集系を改良し,微小膜捕集濃縮/溶解法を用い,黒鉛炉AASにより測定する鉛の高感度定量法を開発した.試料溶液に3.5×10(-5)Mゼフィラミンを加えた後,鉛イオンをピロリジンジチオカルバミン酸イオンと錯形成させ,微小メンブランフィルター(MF)を用いて濾過し,膜捕集濃縮する.用いたMFは膜直径5mm,濾過有効径2mm,孔径0.2μmのニトロセルロース製であり,鉛キレートを捕集後,MFをポンチで3mmにカットして用いた.これにより,膜溶解溶媒であるメチルセロソルブの量を100μlまで減少させることができ,高倍率濃縮を達成することができた.試料量10mlの濾過時間は15分であった.試料10mlを用い,メチルセロソルブ200μlに溶解したときの鉛の定量下限は,10 pptであり,鉛40pptを含む試料を用いたときの相対標準偏差は4.51%(n=4)であった.本法により,水道水,河川水中の鉛を定量した.
kn-abstract=Ultra-trace amounts of lead were determined by graphite-furnace AAS (GF-AAS) after miniature-membrane filter (MF) concentration/dissolution. Lead was concentrated as a pyrrolidinedithiocarbamate (APDC) chelate on a miniature MF, which was 5mm in diameter, 2mm in effective filtering diameter and 0.2 μm in pore size. After collection of the lead chelate on MF, the MF was cut so as to be 3mm in diameter using a punch. This tiny MF was dissolved in 100 μl of a dissolution solvent (methyl cellosolve), which resulted in a high concentration efficiency. When 10 ml of a sample was used, the concentration ratio was 100. The addition of 5 × 10(-5) M Zephiramine to the sample solution before chelation was effective for collecting lead; the recovery was almost 100%. The filtering time was 15 min for a 10 ml sample solution. The detection limit was 10 ppt when a 10 ml of sample solution was concentrated in 200 μl of methyl cellosolve. Measurements by GF-AAS were carried out using 40 μl of a methyl cellosolve solution. The relative standard deviation for 40 ppt of lead was 4.51% (n= 4). This method was applied to both river- and tap-water samples.
en-copyright=
kn-copyright=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=1
ORCID=
en-aut-name=OhsakiTakashi
en-aut-sei=Ohsaki
en-aut-mei=Takashi
kn-aut-name=大崎隆史
kn-aut-sei=大崎
kn-aut-mei=隆史
aut-affil-num=2
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
en-keyword=lead
kn-keyword=lead
en-keyword=miniature membrane filter concentration/dissolution
kn-keyword=miniature membrane filter concentration/dissolution
en-keyword=ammonium pyrrolidinedithiocarbamate
kn-keyword=ammonium pyrrolidinedithiocarbamate
en-keyword=graphite furnace AAS
kn-keyword=graphite furnace AAS
END
start-ver=1.4
cd-journal=joma
no-vol=47
cd-vols=
no-issue=6
article-no=
start-page=375
end-page=380
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1998
dt-pub=19980605
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Simultaneous determination of nitrate and nitrite ion by micro-flow injection analysis
kn-title=マイクロフローインジェクション分析法による硝酸,亜硝酸イオンの同時定量
en-subtitle=
kn-subtitle=
en-abstract=試薬,試料量の低減化とオンサイト分析を目的として,マイクロフロー方式FIA(μFIA)による硝酸イオン,亜硝酸イオンの定量について検討した.流路は二流路とし,ダブルプランジャー型マイクロポンプを用い,吐出量は2.5μl stroke-1,流量は50μl min-1とした.吸光検出反応には,スルファニルアミドと2-ナフチルエチレンジアミンを用いるジアゾ化-カップリング反応を用い,538nmで測定した.試料注入量20μlで,内径0.25mm,長さ75 cmの反応コイルを用いれば,通常の河川水程度の硝酸,亜硝酸イオンの定量が可能である.μFIA用のCd/Cu還元ミニカラムは,カドミウムパウダー(60～80メッシュ)を銅コーティングし,内径0.53mmのシリカチューブ(長さ5cm)に詰めて作製した.本ミニカラムによる硝酸イオンの亜硝酸イオンへの還元効率は99%以上であった.スプリット方式により,硝酸亜硝酸イオンの同時定量用流路を構築した.実際試料のオンサイト分析装置には,発光ダイオード(LED)を川いて,消費電力の低減化を計った.硝酸,亜硝酸イオンを単独に定量する場合の検出限界はそれぞれ約2×10(-8)Mであり,同時定量の場合には約10(-7)Mであった.河川水中の硝酸,亜硝酸イオンの同時定量にも応用できることが分かった.
kn-abstract=To minimize the sample size, reagent consumption and waste, a micro-flow injection analysis (μFIA) was investigated and applied to the simultaneous determination of nitrate and nitrite ion in water samples. A double-plunger micropump was used to propel a carrier and a chromogenic solution; each flow rate was 50 μl min(-1), and the delivery volume was 2.5 μl per stroke. Nitrate was reduced to nitrite on line by passing through a mini column (0.53 mm i.d.×5 cm) packed with powdered Cd/Cu (6080 mesh). The reduction efficiency was 99% using this reduction column. Detection was carried out at 538 nm with a light-emitting diode used as an azo dye. The carrier solution contained EDTA and NaCl (pH 8.18.4) and the reagent solution contained sulfanilamide, N-(1-naphthyl)ethylenediamine and HCl. For a simultaneous determination, the sample injected into the carrier stream was split into two streams: one passed through the mini Cd/Cu column ; the other passed through a bypass column packed with glass beads. The sample zone passing through the bypass column gave a first peak derived from nitrite; the other sample zone passing through the reduction column gave the second peak derived from nitrate and nitrite. The detection limits of nitrate and nitrite were about 1×10(-7) M using the proposed simultaneous determination system.
en-copyright=
kn-copyright=
en-aut-name=MaLan
en-aut-sei=Ma
en-aut-mei=Lan
kn-aut-name=馬蘭
kn-aut-sei=馬
kn-aut-mei=蘭
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=3
ORCID=
en-aut-name=HattoriTakayasu
en-aut-sei=Hattori
en-aut-mei=Takayasu
kn-aut-name=服部隆康
kn-aut-sei=服部
kn-aut-mei=隆康
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
affil-num=4
en-affil=
kn-affil=旭テクネイオン(株)
en-keyword=micro-flow injection analysis
kn-keyword=micro-flow injection analysis
en-keyword=river water, nitrate and nitrite
kn-keyword=river water, nitrate and nitrite
en-keyword=simultaneous determination
kn-keyword=simultaneous determination
en-keyword=mini Cd/Cu reduction column
kn-keyword=mini Cd/Cu reduction column
END
start-ver=1.4
cd-journal=joma
no-vol=51
cd-vols=
no-issue=9
article-no=
start-page=785
end-page=789
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2002
dt-pub=20020905
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Highly sensitive determination of copper ion with newly synthesized water-soluble fluorescent reagents having a 1,8-diaminonaphthalene-3,6-disulfonic acid skeleton
kn-title=1,8-ジアミノナフタレン-3,6-ジスルホン酸骨格を持つ新規水溶性蛍光試薬の合成と銅イオンの高感度定量への応用
en-subtitle=
kn-subtitle=
en-abstract=水溶性蛍光試薬として1,8-ジヒドロキシナフタレン-3,6-ジスルホン酸 (クロモトロープ酸) に類似した1,8-ジアミノナフタレン-3,6-ジスルホン酸骨格を持つ1,8-ジ-(トルエン-4-スルホニルアミノ)-ナフタレン-3,6-ジスルホン酸 (BTND) 及び1,8-ジ-(トリフルオロメタンスルホニルアミノ)-ナフタレン-3,6-ジスルホン酸 (BTFND) を合成し, 金属イオンとの反応性を検討した. BTFNDは検討した8種類の金属イオンと反応し消蛍光を示した. またBTNDは銅 (II) イオンと選択的に反応することが分かった. BTNDは水溶液中pH7で銅 (II) イオンと定量的に反応し, 消蛍光を示したので, 検量線を作成したところ, 銅濃度0～10(-6)Mの範囲で直線関係を示した (λ(ex)=360nm, λ(em)=405nm). 本法の銅 (II) イオンの検出下限は2.0×10(-7)Mであった. BTNDは水溶液中で反応し, 定量操作が簡便で, 銅 (II) イオンに対する高感度・高選択的な蛍光試薬であることが分かった.
kn-abstract=Water-soluble fluorescent reagents, 1,8-di-(toluene-4-sulfonylamino)-naphthalene-3,6-disulfonic acid (BTND) and 1,8-di-(trifluoromethanesulfonylamino)-naphthalene-3,6-disulfonic acid (BTFND), were newly synthesized. The reactivities of these fluorescent reagents to Cu(2+), Ni(2+), Co(2+), Cd(2+), Pb(2+), V(V), Ag(+), Fe(3+), and Mg(2+) were examined. BTFND was reacted with 8 metal ions, except for Pb(2+), to show fluorescence quenching. BTND was selective to Cu(2+), and the fluorescence was quenched quantitatively at pH 7 in an aqueous solution (λ(ex)=360 nm and λ(em)=405 nm). The calibration graph for Cu(2+) with BTND was rectilinear over the concentration range from 0 to 10(-5) M and the detection limit was 2.0×10(-7) M. BTND has many advantages, such as selectivity for Cu(2+), high sensitivity, and a simple procedure.
en-copyright=
kn-copyright=
en-aut-name=NomuraKazuhiro
en-aut-sei=Nomura
en-aut-mei=Kazuhiro
kn-aut-name=野村一央
kn-aut-sei=野村
kn-aut-mei=一央
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=高柳俊夫
kn-aut-sei=高柳
kn-aut-mei=俊夫
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
affil-num=4
en-affil=
kn-affil=岡山大学
en-keyword=determination of copper ion
kn-keyword=determination of copper ion
en-keyword=1,8-di-(toluene-4-sulfonylamino)-naphthalene-3,6-disulfonic acid
kn-keyword=1,8-di-(toluene-4-sulfonylamino)-naphthalene-3,6-disulfonic acid
en-keyword=1,8-di-(trifluoromethane-4-sulfonylamino)-naphthalene-3,6-disulfonic acid
kn-keyword=1,8-di-(trifluoromethane-4-sulfonylamino)-naphthalene-3,6-disulfonic acid
en-keyword=fluorescence detection
kn-keyword=fluorescence detection
END
start-ver=1.4
cd-journal=joma
no-vol=51
cd-vols=
no-issue=9
article-no=
start-page=791
end-page=795
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2002
dt-pub=20020905
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Determination of trace metal impurities in nickel and iron salts using 2-(5-Nitro-2-pyridylazo)-5-(N-propyl-N-sulfopropyl-amino)phenol by capillary zone electrophoresis
kn-title=2-(5-ニトロ-2-ピリジルアゾ)-5-(N-プロピル-N-スルホプロピルアミノ)フェノールを用いるキャピラリー電気泳動法によるニッケル, 鉄塩中の極微量不純物の定量
en-subtitle=
kn-subtitle=
en-abstract=市販金属塩中の極微量金属不純物の定量法として, 2-(5-ニトロ-2-ピリジルアゾ)-5-(N-プロピル-N-スルホプロピルアミノ)フェノール (Nitro-PAPS) とのキレートを分離, 検出するキャピラリー電気泳動法について検討した. 各種金属イオンと定量的に反応するpH7の条件では, 高感度検出が可能であるが, 多くの金属錯体の分離は十分でない. そこで, 電気浸透流やキレートの電気泳動移動度を変化させる効果のある第四級アンモニウム塩等の添加を検討し, 種々な相互作用試薬を用いて分離の改善を図った. その結果, 臭化セチルトリメチルアンモニウムの添加で電気浸透流が抑制され, 硫酸ナトリウムの添加によるスタッキング効果の活用によりシグナルが鋭敏化され, 尿素の添加でニトロ基周りの水和を抑制したところ, 金属キレートの分離性能が向上した. 本法により10(-7)MレベルのFe, Co, Ni, Cuの分離定量が可能になり, 市販特級金属塩中の極微量金属の分析に適用したところ, ppm (=10(-6)g/g) レベルの金属不純物を定量することができた.
kn-abstract=2-(5-Nitro-2-pyridylazo)-5-(N-propyl-N-sulfopropylamino)phenol (Nitro-PAPS) was used for a quantitative determination of ultratrace-level metal ions in commercially available metal salts by capillary zone electrophoresis. At pH 7, Nitro-PAPS reacts with various metal ions to form chelate compounds having large molar absorptivities. Although chelate formation is useful for the highly sensitive detection of metal ions, the resolution of the metal complexes is poor at pH 7. Cetyltrimethylammonium bromide was added to suppress any electroosmotic flow. The hydration of nitro groups of a chelating agent and chelates was controlled by the addition of urea. Sodium sulfate was also utilized to sharpen the signals of metal chelates by a field-enhanced stacking effect. As a result, the resolution was improved and the determination of 10-7 M level metal ions was possible. The proposed method was applied to the analysis of metal impurity at ultratrace levels in commercially available nickel and iron salts.
en-copyright=
kn-copyright=
en-aut-name=KagawaTakuji
en-aut-sei=Kagawa
en-aut-mei=Takuji
kn-aut-name=香川拓司
kn-aut-sei=香川
kn-aut-mei=拓司
aut-affil-num=1
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=高柳俊夫
kn-aut-sei=高柳
kn-aut-mei=俊夫
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
affil-num=4
en-affil=
kn-affil=岡山大学
en-keyword=capillary zone electrophoresis
kn-keyword=capillary zone electrophoresis
en-keyword=metal ions
kn-keyword=metal ions
en-keyword=2-(5-nitro-2-pyridylazo)-5-(N-propyl-N-sulfopropylamino)phenol
kn-keyword=2-(5-nitro-2-pyridylazo)-5-(N-propyl-N-sulfopropylamino)phenol
en-keyword=nickel and iron salt
kn-keyword=nickel and iron salt
en-keyword=impurity analysis
kn-keyword=impurity analysis
END
start-ver=1.4
cd-journal=joma
no-vol=7
cd-vols=
no-issue=
article-no=
start-page=20
end-page=25
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1952
dt-pub=195208
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=MEDICAL STUDIES ON CHONDROITIN SULFATE (2nd Report)
kn-title=コンドロイチン硫酸の医学的研究-2-
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=After the internal use of daily 3 grams of crude chondroitin sulfate cholinesterase activity of serum decreased and elimination of glycuronic acid in urine increased, but no definite change in serum mucoprotein level was observed. Mucoprotein in serum showed a positive linear correlation to erythrocyte sedimentation rate, and chondroitin sulfate promoted the e.s.r. in vitro and in vivo. Chondroitin sulfate showed no marked influence on phagocytosis of human leucocytes in vitro, but it promoted the production of agglutinin in rabbits by subcutaneous injection．
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
en-aut-name=YokotaTakeo
en-aut-sei=Yokota
en-aut-mei=Takeo
kn-aut-name=横田剛男
kn-aut-sei=横田
kn-aut-mei=剛男
aut-affil-num=2
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学温泉研究所内科
affil-num=2
en-affil=
kn-affil=岡山大学温泉研究所内科
END
start-ver=1.4
cd-journal=joma
no-vol=31
cd-vols=
no-issue=2
article-no=
start-page=29
end-page=37
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1997
dt-pub=19970328
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Estimation of Loosening of Knee Joint Prosthesis
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Knee replacement arthroplasty is indicated for the patient with advanced knee pain, knee deformation, and knee functional disorder. The aim of this study was to estimate loosening after a knee replacement arthroplasty. Loosening is measured by a frequency response function, and mobility by random vibration. The modal parameters for the knee joint are obtained by applying a modal analysis to the frequency response function. The values decrease as the knee joint prosthesis loosened. These parameters serve as an index for the condition between a thighbone and the prosthesis. The various indexes will greatly clarify the stage of advance in the loosening of knee-joint prostheses.
en-copyright=
kn-copyright=
en-aut-name=OkaHisao
en-aut-sei=Oka
en-aut-mei=Hisao
kn-aut-name=岡久雄
kn-aut-sei=岡
kn-aut-mei=久雄
aut-affil-num=1
ORCID=
en-aut-name=OhshimaMasakazu
en-aut-sei=Ohshima
en-aut-mei=Masakazu
kn-aut-name=大島正和
kn-aut-sei=大島
kn-aut-mei=正和
aut-affil-num=2
ORCID=
affil-num=1
en-affil=
kn-affil=Department of Electrical & Electronic Engineering
affil-num=2
en-affil=
kn-affil=Department of Electrical & Electronic Engineering
END
start-ver=1.4
cd-journal=joma
no-vol=7
cd-vols=
no-issue=
article-no=
start-page=1
end-page=5
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1952
dt-pub=195208
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=BALNEOLOGICAL STUDIES USING RADIO-ACTIVE ISOTOPES (1) ON THE MECHANISM OF THE ACTION OF SODIUM SULFATE SPRING BATH．
kn-title=人工放射性同位元素による温泉作用の研究(1)芒硝泉入浴による硫酸イオンの体内進入について
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Using Na(2)SO(4) labelled with S(35) transition of sulfate ion into the body across the skin was investigated soon after the bath in sodium sulfate solution at varying conditions. Mice were used as test animal. Percutaneous absorption of sulfate ion proved to be promoted at high bath temperature (45℃) than at indifferent temperature(37℃). stronger by the bath of longer duration (30min.) than by the bath of shorter duration (10min.), increased after repeated baths than after a single bath. It was accelerated by making a burn to the skin of the bathed animals. Layton and Dziewiatkowski proved that the parenterally administered sulfate ion was partly fixed in the connective tissue as chondroitin sulfate. The author had proved that chondroitin sulfate relieves pain, increases peripheral circulation and when administered parenterally promotes production of immune bodies. In Japan natural and artificial Glauber's salt spring bath are known to have a beneficial effect on wound healing, but no satisfactory explanation was given till today. Lith reported that a hypertonic solution of sodium sulfate promoten wound cure by external application and Seki showed that subcutaneous connective tissue of mice was stimulated by the bath in sodium sulfate spring. And so the abovementioned author's data seem to throw some light on solving the problem.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
en-aut-name=YokotaTakeo
en-aut-sei=Yokota
en-aut-mei=Takeo
kn-aut-name=横田剛男
kn-aut-sei=横田
kn-aut-mei=剛男
aut-affil-num=2
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学温泉研究所内科
affil-num=2
en-affil=
kn-affil=岡山大学温泉研究所内科
END
start-ver=1.4
cd-journal=joma
no-vol=77
cd-vols=
no-issue=4
article-no=
start-page=717
end-page=724
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1965
dt-pub=19650430
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Report of Field Survey on Acatalasemia and Hypocatalasemia in 1964
kn-title=昭和39年度ACATALASEMIA,HYPOCATALASEMIA調査集計
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=The authors reported the results of the field survey and family follow-up of acatalasemia and hypocatalasemia during the year of 1964. Among 2,964 individuals submitted to the screening test for the purpose of detecting acatalasemic gene carriers in various parts of Japan, two proved to be hypocatalasemia. On examination of the remaining 34 members of two acatalasemic families, there were one case of acatalasemia and 11 of hypocatalasemia in addition to the formerly known cases. Consequently, the total of reported acatalasemic cases amounted to 80 cases of 37 families by the end of 1964.
en-copyright=
kn-copyright=
en-aut-name=TakaharaShigeo
en-aut-sei=Takahara
en-aut-mei=Shigeo
kn-aut-name=高原滋夫
kn-aut-sei=高原
kn-aut-mei=滋夫
aut-affil-num=1
ORCID=
en-aut-name=OguraYoshio
en-aut-sei=Ogura
en-aut-mei=Yoshio
kn-aut-name=小倉義郎
kn-aut-sei=小倉
kn-aut-mei=義郎
aut-affil-num=2
ORCID=
en-aut-name=OkazakiHideo
en-aut-sei=Okazaki
en-aut-mei=Hideo
kn-aut-name=岡崎英生
kn-aut-sei=岡崎
kn-aut-mei=英生
aut-affil-num=3
ORCID=
en-aut-name=YasuharaKozo
en-aut-sei=Yasuhara
en-aut-mei=Kozo
kn-aut-name=安原晧三
kn-aut-sei=安原
kn-aut-mei=晧三
aut-affil-num=4
ORCID=
en-aut-name=SadamotoMasanori
en-aut-sei=Sadamoto
en-aut-mei=Masanori
kn-aut-name=貞本昌規
kn-aut-sei=貞本
kn-aut-mei=昌規
aut-affil-num=5
ORCID=
en-aut-name=OhshimaAkio
en-aut-sei=Ohshima
en-aut-mei=Akio
kn-aut-name=大島昭夫
kn-aut-sei=大島
kn-aut-mei=昭夫
aut-affil-num=6
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=2
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=3
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=4
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=5
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=6
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
END
start-ver=1.4
cd-journal=joma
no-vol=80
cd-vols=
no-issue=1-2
article-no=
start-page=65
end-page=75
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1968
dt-pub=19680228
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Studies on Lactic Dehydrogenase Activity and Isozyme in Malignant Disease Part 2 Effects of Chemotherapy on Serum Lactic Dehydrogenase Activity and Isozyme of Tumor-Bearing Mice
kn-title=悪性腫瘍における乳酸脱水素酵素とそのIsozymeに関する研究 第二編 担腫瘍マウス血清乳酸脱水素酵素活性及びそのIsozyme patternに及ぼす抗癌剤の影響について
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Alterations of serum lactic dehydrogenase (S-LDH) activity and isozyme during therapy in tumor-bearing mice were assayed. 1. Normal Strong A mice receiving Mitomycin C (MMC), Chromomycin A(3) (TM), and Chloroquine phosphate (CQ) respectively were evaluated for S-LDH activity. S-LDH activities of the mice receiving MMC and TM were about twice as high as mormal, this seems to be the side effects of chemotherapeutic agents. The strong A mice receiving CQ showed no changes in S-LDH activity. 2. The strong A mice bearing Bashford carcinoma and the Swiss mice bearing fibrosarcoma were evaluated at weekly intervals for SLDH activity and isozymes. S-LDH activities gradually elevated for 4 weeks. In the Strong A mice bearing Bashford carcinoma LD(3) in creased and LD(1) decreased gradually. In the Swiss mice bearing fibrosarcoma LD(3) was higher than normal at every week. 3. S LDH activities in tumor-bearing mice undergoring therapy with MMC and TM, especially MMC, markedly decreased correlating with tumor regression. As to the S-LDH isozyme, LD(3) in mice receiving TM decreased correlating with decrease of S-LDH activity. In mice receiving others no characteristics were observed. 4. In couclusion, the assay of S-LDH activity and isozymes during therapy directing at tumors are useful in determining wheather or not a chemotherapentic agent affects the tumors.
en-copyright=
kn-copyright=
en-aut-name=OshimaYukiko
en-aut-sei=Oshima
en-aut-mei=Yukiko
kn-aut-name=大島由紀子
kn-aut-sei=大島
kn-aut-mei=由紀子
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部平木内科教室
END
start-ver=1.4
cd-journal=joma
no-vol=79
cd-vols=
no-issue=5-6
article-no=
start-page=453
end-page=463
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1967
dt-pub=19670630
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Studies on Lactic Dehydrogenase Activity and Isozyme in Malignant Disease Part I. Relationship Between the Serum Lactic Dehydrogenase and the Clinical course of Leukemia
kn-title=悪性腫瘍における乳酸脱水素酵素とそのIsozymeに関する研究 第一編 白血病の化学療法と血清乳酸脱水素酵素及びそのIsozymeの関係について
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=1. Serum lactic dehydrogenase (S-LDH) activity and isozyme were measured in 29 patients with leukemia. The elevated S-LDH levels were demonstrated in all cases of acute leukemias and chronic myelocytic leukemias and in a half of cases of chronic lymphocytic leukemias. The S-LDH isozyme can be identified five fractions by means of agar gel electrophoresis. The changes of pattern of S-LDH isozyme were observed in all types of leukemia. It was the increased third (LD(3)), second (LD(2)) and first (LD(1)) fractions of LDH isozyme and the decreased fifth fraction (LD(5)). The most significant fraction in leukemia was LD(3), and the increased LD(3) and decreased LD(5) were observed in 25 of 29 cases (86 % ). 2. The degree of S-LDH elevation appeared to be the greatest in the acute lymphatic and the smallest in the chronic lymphatic leukemia. The degree of increase of LD(3) was independent on the type of leukemia. 3. As to the correlation of S-LDH with clinical findings, the level of S-LDH and LD(3) well correlated with the percentage of circulating immature leukocytes, but not with the absolute number of leukocyte. 4. The serial S-LDH levels and LD(3) closely paralleled with the clinical courses in 10 cases of 29 patients with leukemia and relatively well paralleled in 13 cases. 5. In regard to possible mechanisms of S-LDH elevation in leukemia, acceleration of biosynthesis of LDH in the leukemic cells and liberation of the enzyme from the cells might be suggested.
en-copyright=
kn-copyright=
en-aut-name=OshimaYukiko
en-aut-sei=Oshima
en-aut-mei=Yukiko
kn-aut-name=大島由紀子
kn-aut-sei=大島
kn-aut-mei=由紀子
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部平木内科教室
END
start-ver=1.4
cd-journal=joma
no-vol=83
cd-vols=
no-issue=7-8
article-no=
start-page=259
end-page=265
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1971
dt-pub=19710830
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=昭和43年度および44年度Acatalasemia, Hypocatalasemia調査集計
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=高原滋夫
kn-aut-sei=高原
kn-aut-mei=滋夫
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=小倉義郎
kn-aut-sei=小倉
kn-aut-mei=義郎
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=小野田元男
kn-aut-sei=小野田
kn-aut-mei=元男
aut-affil-num=3
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島昭夫
kn-aut-sei=大島
kn-aut-mei=昭夫
aut-affil-num=4
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=住田昭三
kn-aut-sei=住田
kn-aut-mei=昭三
aut-affil-num=5
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=滝口峻
kn-aut-sei=滝口
kn-aut-mei=峻
aut-affil-num=6
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=尾関安英
kn-aut-sei=尾関
kn-aut-mei=安英
aut-affil-num=7
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=笠井英夫
kn-aut-sei=笠井
kn-aut-mei=英夫
aut-affil-num=8
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=黒田泰生
kn-aut-sei=黒田
kn-aut-mei=泰生
aut-affil-num=9
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大倉興司
kn-aut-sei=大倉
kn-aut-mei=興司
aut-affil-num=10
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=2
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=3
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=4
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=5
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=6
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=7
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=8
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=9
en-affil=
kn-affil=岡山大学医学部耳鼻咽喉科学教室
affil-num=10
en-affil=
kn-affil=東京医科歯科大学人類遺伝研究室
END
start-ver=1.4
cd-journal=joma
no-vol=93
cd-vols=
no-issue=7-8
article-no=
start-page=701
end-page=708
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1981
dt-pub=19810830
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Multiple polypoid filling defects of the duodenal bulb
kn-title=十二指腸球部多発陰影欠損について
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Multiple polypoid filling defects of the duodenal bulb are infrequently encountered. Two cases of multiple filling defects of the duodenal bulb are reported in this paper. Case 1. A 42 year old female complained of abdominal fullness and epigastralgia. On examination, generalized peripheral lymphadenopathy and marked hepatosplenomegaly were noted. Cervical lymphnode biopsy revealed a diffuse, poorly-differanciated lymphocytic lymphoma. X-ray examination of the gastrointestinal tract showed multiple filling defects localized at the duodenal bulb. Endoscopy disclosed multiple well-defined protrusions with small mucosal ulceration over the the whole circumference of the duodenal wall. Case 2. A 36 year old female had no subjective symptoms. At gastric mass screening, numerous polypoid elevations of the duodenal bulb were pointed out. Detailed gastrointestinal x-ray examination showed numerous, tiny, round polypoid nodules localized at the duodenal bulb. These nodules were 2-3mm in size with no mucosal ulceration. The endoscopic biopsy specimen revealed lymphoid hyperplasia of the duodenal bulb.
en-copyright=
kn-copyright=
en-aut-name=MorinoYasuo
en-aut-sei=Morino
en-aut-mei=Yasuo
kn-aut-name=森野靖雄
kn-aut-sei=森野
kn-aut-mei=靖雄
aut-affil-num=1
ORCID=
en-aut-name=TakedaYoshihiro
en-aut-sei=Takeda
en-aut-mei=Yoshihiro
kn-aut-name=竹田芳弘
kn-aut-sei=竹田
kn-aut-mei=芳弘
aut-affil-num=2
ORCID=
en-aut-name=MorimotoSetsuo
en-aut-sei=Morimoto
en-aut-mei=Setsuo
kn-aut-name=森本節夫
kn-aut-sei=森本
kn-aut-mei=節夫
aut-affil-num=3
ORCID=
en-aut-name=MiyakeMasayoshi
en-aut-sei=Miyake
en-aut-mei=Masayoshi
kn-aut-name=三宅正淑
kn-aut-sei=三宅
kn-aut-mei=正淑
aut-affil-num=4
ORCID=
en-aut-name=HayashiHidehiro
en-aut-sei=Hayashi
en-aut-mei=Hidehiro
kn-aut-name=林英博
kn-aut-sei=林
kn-aut-mei=英博
aut-affil-num=5
ORCID=
en-aut-name=EzoeHiroshi
en-aut-sei=Ezoe
en-aut-mei=Hiroshi
kn-aut-name=江添弘
kn-aut-sei=江添
kn-aut-mei=弘
aut-affil-num=6
ORCID=
en-aut-name=KimotoShin
en-aut-sei=Kimoto
en-aut-mei=Shin
kn-aut-name=木本真
kn-aut-sei=木本
kn-aut-mei=真
aut-affil-num=7
ORCID=
en-aut-name=JojaIkuo
en-aut-sei=Joja
en-aut-mei=Ikuo
kn-aut-name=上者郁夫
kn-aut-sei=上者
kn-aut-mei=郁夫
aut-affil-num=8
ORCID=
en-aut-name=HashimotoKeiji
en-aut-sei=Hashimoto
en-aut-mei=Keiji
kn-aut-name=橋本啓二
kn-aut-sei=橋本
kn-aut-mei=啓二
aut-affil-num=9
ORCID=
en-aut-name=AonoKaname
en-aut-sei=Aono
en-aut-mei=Kaname
kn-aut-name=青野要
kn-aut-sei=青野
kn-aut-mei=要
aut-affil-num=10
ORCID=
en-aut-name=HayashiKyoichi
en-aut-sei=Hayashi
en-aut-mei=Kyoichi
kn-aut-name=林恭一
kn-aut-sei=林
kn-aut-mei=恭一
aut-affil-num=11
ORCID=
en-aut-name=TakaokaKazuko
en-aut-sei=Takaoka
en-aut-mei=Kazuko
kn-aut-name=高岡和子
kn-aut-sei=高岡
kn-aut-mei=和子
aut-affil-num=12
ORCID=
en-aut-name=OshimaYukiko
en-aut-sei=Oshima
en-aut-mei=Yukiko
kn-aut-name=大島由起子
kn-aut-sei=大島
kn-aut-mei=由起子
aut-affil-num=13
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部放射線医学教室
affil-num=2
en-affil=
kn-affil=岡山大学医学部放射線医学教室
affil-num=3
en-affil=
kn-affil=岡山大学医学部放射線医学教室
affil-num=4
en-affil=
kn-affil=岡山大学医学部放射線医学教室
affil-num=5
en-affil=
kn-affil=岡山大学医学部放射線医学教室
affil-num=6
en-affil=
kn-affil=岡山大学医学部放射線医学教室
affil-num=7
en-affil=
kn-affil=岡山大学医学部放射線医学教室
affil-num=8
en-affil=
kn-affil=岡山大学医学部放射線医学教室
affil-num=9
en-affil=
kn-affil=岡山大学医学部放射線医学教室
affil-num=10
en-affil=
kn-affil=岡山大学医学部放射線医学教室
affil-num=11
en-affil=
kn-affil=岡山大学医学部第II内科学教室
affil-num=12
en-affil=
kn-affil=岡山大学医学部第II内科学教室
affil-num=13
en-affil=
kn-affil=三菱水島病院内科
en-keyword=Duodenal bulb
kn-keyword=Duodenal bulb
en-keyword=multiple polypoid nodules
kn-keyword=multiple polypoid nodules
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2009
dt-pub=20090325
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=bFGF局所投与による下顎骨骨質改善効果の検討 ‐神経提由来骨髄細胞と中胚葉由来骨髄細胞の骨芽細胞分化ならびに破骨細胞分化の相違とbFGFへの反応性‐
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=OshimaMasamitsu
en-aut-sei=Oshima
en-aut-mei=Masamitsu
kn-aut-name=大島正充
kn-aut-sei=大島
kn-aut-mei=正充
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=8
cd-vols=
no-issue=
article-no=
start-page=1
end-page=7
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1952
dt-pub=195211
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=STUDIES ON SERUM MUCOPROTEIN (1) SERUM MUCOPROTEIN LEVEL IN NORMAL AND PATHOLOGICAL STATES OF JAPANESE.
kn-title=血清Mucoprotein含有量(1)正常人並に各種疾患患者に於ける血清Mucoprotein含有量
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Serum mucoprotein level in 16 normnls and 3CO cases of diseased was investignted by Winzler' s method. Using biuret rengent normal range of serum mucoprotein proved to be 94-120mg per cent. Higher mucoprotein content was often recognized in rheumatoid arthritis, cancer, pneumonia, and hepatitis. High mucoprotein level in cancer or ulcer patients was decrensed after their resection. A positive linear correlation wns shown between erythrocytes sedimentation rate and mucoprotein level in serum. But no close relation was observed between serum mucoprotein and Takata reaction, Wassermann reaction or total protein content in serum.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
en-aut-name=UedaYoshio
en-aut-sei=Ueda
en-aut-mei=Yoshio
kn-aut-name=上田良雄
kn-aut-sei=上田
kn-aut-mei=良雄
aut-affil-num=2
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学温泉研究所内科
affil-num=2
en-affil=
kn-affil=岡山大学温泉研究所内科
END
start-ver=1.4
cd-journal=joma
no-vol=6
cd-vols=
no-issue=
article-no=
start-page=52
end-page=61
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1952
dt-pub=195203
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=MEDICAL STUDIES ON CHONDROITIN SULFATE (1)
kn-title=コンドロイチン硫酸の医学的研究（第1報）
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Chondroitin sulfate (daily 3g. per os) was administered to fifty cases of painful disorders, such as hemicrania, neuralgia, chronic rheumatoid arthritis, perialthritis, etc. And amelioration was observed in 34 cases (68%).
Chondroitin Sulfate promotes the blood clotting time by intravenous injection, but has no influence on blood viscosity. It inhibits the action of cholin esterase slightly in vitro and shows a tendency to increase peripheral circulation by Laewen-Trendelenburgs method. It showed no definite effect on blood pressure in the above-mentioned patients. By Magnus method it was shown that chondroitin sulfate accelerates the motility of the isolated rabbit intestine and suppresses the action of adrenalin. Chondroitin sulfate increases the permeability of tissue, but it shows a slight inhibitory action on testicular byaluronidase. Peroral administration of chondroitin sulfate promotes diuresis, increases the elimination of total sulfate and diminishes the neutral sulfur in the urine.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学温泉研究所内科
END
start-ver=1.4
cd-journal=joma
no-vol=6
cd-vols=
no-issue=
article-no=
start-page=49
end-page=51
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1952
dt-pub=195203
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=SENSITIVITY TO HISTAMINE DURING A SERIES OF THERMAL BATHS.
kn-title=温泉浴による変調の研究, ヒスタミン感受性の変化
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Sensitivity of mice to histamine was estimated with the death-rate by its subcutaneous injection. In control group without bath ten mg. of histamine per ten g. of body weight
proved to be tolerable, but twenty mg. of histamine per ten g. of body weight was lethal in August. To 24 mice were given everyday a plain water bath at 37℃ for ten minutes. To another 24 mice were given everyday a thermal bath of Misasa at 37℃for ten minutes. On the 4th, 7th, 14th and 21st day to each six mice of both groups was given a subcutaneous injection of histamine, namely to three mice was given ten mg. of histamine per ten g. of bodyweight and to another three mice was given twenty mg. of histamine per ten g. of body weight. In plain water bath group no change in death rate was shown during the series of bath days. But in the thermal bath group a 100% 1ethality was recognized on the 4th day, 67% lethality was proved on the 7th day and only 17% lethality was shown on the 14th day. Histamine or histaminelike substance is known to be a chemical agent liberated in
the skin by any skin irritants. And the above-mentioned change in the sensitivity to histamine during a series of
thermal baths suggests an explanation to the mechanism of thermal crisis that has a tendency to occur in the first week of thermal bath cure.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
en-aut-name=YokotaTakeo
en-aut-sei=Yokota
en-aut-mei=Takeo
kn-aut-name=横田剛男
kn-aut-sei=横田
kn-aut-mei=剛男
aut-affil-num=2
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学温泉研究所内科
affil-num=2
en-affil=
kn-affil=岡山大学温泉研究所内科
END
start-ver=1.4
cd-journal=joma
no-vol=6
cd-vols=
no-issue=
article-no=
start-page=46
end-page=48
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1952
dt-pub=195203
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=SEASONAL DIFFERENCE IN THE EFFECT OF THERMAL BATH ON BLOOD CATALASE.
kn-title=温泉浴作用の季節による差違： 血液カタラーゼ数にみられた変化
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Blood catalase level in healthy rabbits was measured before and after thermal bath of Misasa in January, May, July and September. And the differences in the effect of thermal bath between the four seasons were investigated.
Blood catalase level in rabbits proved to be highest in winter and lowest in September. A slight fall in blood catalase level was recognized an hour after the thermal bath at 42℃ for five minutes. And in September the degree of fall seemed to be slightest and the recovery soonest.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学温泉研究所内科
END
start-ver=1.4
cd-journal=joma
no-vol=5
cd-vols=
no-issue=
article-no=
start-page=57
end-page=58
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1951
dt-pub=195108
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=STUDIES ON VITRIOL SPRINGS,(8) BLOOD CATALASE LEVEL AFTER THE INTERNAL USE oF VITRIOL WATERS.
kn-title=綠礬泉に関する研究（8） 酸性綠礬泉の飲用と血液カタラーゼ
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=After the internal use of 20-40 cc of Fujino or Yanahara mineral waters a rise in the iron, copper, nickel and cobalt content in blood and a slight fall in the bloodcatalase level were observed. No significant difference was proved between the effects of two vitriol waters.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学温泉研究所内科
END
start-ver=1.4
cd-journal=joma
no-vol=5
cd-vols=
no-issue=
article-no=
start-page=55
end-page=56
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1951
dt-pub=195108
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=STUDIES ON VITRIOL SPRINGS,(7) IN-VITRO EFFECT OF VIIRIOl WATERS ON OXIDOREDUCTASE.
kn-title=綠礬泉に関する研究(7) 酸化還元酵素作用に及ぼす影響
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Fujino and Yanahara spring waters were used. The latter, is the strongest copper spring in Japan. Iron ion in Fujino mineral water is mainly ferric and in Yanahara mineral water mainly ferrous. Yanahara spring water promotes the action of oxidoreductase in milk and liver extract. It also promotes the action of succinic dehydrase in albino rat muscle. And this promoting action of spring water is inhibited by cyanide. Fujino is less active than Yanahara and Mitsuishi proved to be almost inactive.
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学溫泉研究所内科
END
start-ver=1.4
cd-journal=joma
no-vol=4
cd-vols=
no-issue=
article-no=
start-page=49
end-page=53
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1951
dt-pub=195103
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=THE MEMBRANE POTENTlAL OF THE LIVING HUMAN SKIN AND THE MINERALWATERS
kn-title=溫泉水と人體皮膚膜電位差
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=The membrane potential difference with the living human skin between the physiological saline and the mineral waters was measured. The hypotonic mineral waters, that have a pH higher than the isoelectric point of human epidermis, showed a positive potential against the physiological saline. The membrane potential difference of these mineral waters against the physiological saline at the same temperature tends to increase by raising the water temperature. The acid waters showed either a positive or a negative potential against the physiological saline. The membrane potential difference between the mineral wates at room temperature and at the temperature raised above it is increased according to their temperature difference,
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大學放射能泉研究所
END
start-ver=1.4
cd-journal=joma
no-vol=4
cd-vols=
no-issue=
article-no=
start-page=13
end-page=23
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1951
dt-pub=195103
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=STUDIES OF THE RADIO-ACTIVE SPRINGS (XXV-XXVII)
kn-title=放射能泉に關する研究(XXV-XXVII)
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=OshimaYoshio
en-aut-sei=Oshima
en-aut-mei=Yoshio
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大學放射能泉研究所
END
start-ver=1.4
cd-journal=joma
no-vol=2
cd-vols=
no-issue=
article-no=
start-page=1
end-page=19
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1949
dt-pub=194912
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=放射能泉に関する研究-9〜19-
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島良雄
kn-aut-sei=大島
kn-aut-mei=良雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=
END
start-ver=1.4
cd-journal=joma
no-vol=49
cd-vols=
no-issue=7
article-no=
start-page=529
end-page=536
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2000
dt-pub=2000
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Determination of trace elements in natural water samples by air-segmented flow-injection/ICP-MS after preconcentration with a chitosan-based chelating resin
kn-title=キトサンキレート樹脂前処理法を用いる空気分節試料導入/誘導結合プラズマ質量分析法による天然水中の多元素同時定量
en-subtitle=
kn-subtitle=
en-abstract=Ultratrace elements in natural water samples were determined simultaneously by air-segmented flow-injection/inductively coupled plasma-mass spectrometry(SFI/ICP-MS).A small volume of the sample solutions(80μl) was introduced into a nebulizer by an air-segmented flow-injection(SFI) system, and a maximum of fifteen elements were measured during each run.A chitosan-based chelating resin containing functional groups of iminodiacetate was used to separate and enrich analyte metal ions.A 50-fold preconcentration using 50ml of sample solutions was achieved by the proposed method, where 1ml of 0.1M nitric acid was added to residues after drying the chelating column effluent.At pH6, several heavy metals(Fe, Ni, Co, Cu, Zn, Ag, Cd, Pb and U) and rare earth elements(REEs) were quantitatively retained on the chelating resin column, whereas alkali and alkaline earth metals were eluted from the column by rinsing with 5ml of a 0.2M ammonium acetate solution.Metals adsorbed on the chelating resin column were recovered by elution with 10ml of 1M nitric acid.The proposed method was applied to the determination of trace elements in several natural water samples, such as river water and mineral drinking water.
kn-abstract=本法では,各種天然水中の極微量金属成分を同時定量する目的で空気分節試料導入/ICP-MSシステムを用いて,微少量試料(数十μl)を前処理せずにネブライザーに送り込み,多数の金属成分の定量が可能であった。共存主成分による質量干渉を受ける一部遷移金属や直接試料導入では感度の足りない元素については,イミノ二酢酸型キトサンキレート樹脂充填カラムによる分離·濃縮操作の併用によって更に信頼性の高いデータが得られることが分かった。前処理においては,体積1mlのミニカラムを用いて50mlの溶液試料から50倍濃縮を行い,試料·試薬·廃液すべてを少量化することができた。本ICP-MSシステムでは試料導入量は80μlで十分であり,1mlでも数回繰り返し測定が可能で,しかも多元素同時分析ができた。確立した分析法を用いて河川水や市販のミネラルウォーターに応用し,希土類を含め45種の微量元素の定量が可能となった。
en-copyright=
kn-copyright=
en-aut-name=NinomiyaTakahiko
en-aut-sei=Ninomiya
en-aut-mei=Takahiko
kn-aut-name=二宮崇彦
kn-aut-sei=二宮
kn-aut-mei=崇彦
aut-affil-num=1
ORCID=
en-aut-name=LeeKyue-Hyung
en-aut-sei=Lee
en-aut-mei=Kyue-Hyung
kn-aut-name=李啓熒
kn-aut-sei=李
kn-aut-mei=啓熒
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=2
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=3
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=4
en-affil=
kn-affil=岡山大学理学部化学科
en-keyword=ICP-MS
kn-keyword=ICP-MS
en-keyword=segmented-flow injection
kn-keyword=segmented-flow injection
en-keyword=chelating resin
kn-keyword=chelating resin
en-keyword=chitosan
kn-keyword=chitosan
en-keyword=iminodiacetic functional group
kn-keyword=iminodiacetic functional group
en-keyword=natural waters
kn-keyword=natural waters
en-keyword=preconcentration
kn-keyword=preconcentration
END
start-ver=1.4
cd-journal=joma
no-vol=52
cd-vols=
no-issue=9
article-no=
start-page=811
end-page=877
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2004
dt-pub=2004
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Synthesis of dithiocarbamate-chitosan resin and its adsorption behavior for trace metals
kn-title=ジチオカルバミン酸型キトサン樹脂の合成と金属の捕集挙動
en-subtitle=
kn-subtitle=
en-abstract=A chitosan-based resin possessing the dithiocarbamate moiety (DTC-chitosan resin) was synthesized using cross-linked chitosan as a base material. The adsorption behavior of trace metal ions on the DTC-chitosan resin was systematically examined by packing it in a mini-column (1 ml of the resin) and measuring the recovery by ICP-MS. The resin could adsorb almost 100% of 7 kinds of metals(Cu, Mo, Ag, Te, W, Hg and Bi) at pH ranges from acidic to neutral. However, elution of these metals from the resin was difficult. In this study, we improved the recovery efficiency by a pretreatment of the resin: the resin was added to 100 ml of a 0.1 M copper sulfate solution, stirred for 24 h and washed sufficiently with 1 M nitric acid and water. With this pretreatment, metals adsorbed on 1 ml of the resin were readily eluted with 1 M nitric acid (10 ml). This method was applied to the determination of metals in river-water samples; the RSDs (10-fold preconcentration) were within 5%.
kn-abstract=キレート官能基としてジチオカルバミン酸を架橋キトサンに導入した樹脂を合成した．ジチオカルバミン酸型キトサン樹脂への金属捕集挙動はカラム法を用いて誘導結合プラズマ質量分析法（ICP-MS）により評価した．銅，モリブデン，銀，テルル，タングステン，水銀，ビスマスは幅広いpH範囲で樹脂に捕集された．これらのうち，水溶液中に陽イオンとして存在する銅，銀，テルル，水銀，ビスマスは，キレート生成により樹脂に捕集され，モリブデン，タングステンのように酸素酸として存在する金属は，キレート生成とイオン交換により吸着していると考えられる．この樹脂は通常の溶離酸濃度では金属の溶離が困難であったので，試料処理前に樹脂をあらかじめ0.1 Mの銅イオン溶液とかくはんし，樹脂内部の強い吸着サイトに銅を吸着させておくことで，金属の溶離を改善することに成功した．この前処理をした樹脂1 mlを用いて捕集した金属は，1 M硝酸10 mlでほぼ100％回収可能であった．本法を河川水中の微量金属の定量に応用したところ，相対標準偏差5％ 以内で定量可能であった．
en-copyright=
kn-copyright=
en-aut-name=NinomiyaTakahiko
en-aut-sei=Ninomiya
en-aut-mei=Takahiko
kn-aut-name=二宮崇彦
kn-aut-sei=二宮
kn-aut-mei=崇彦
aut-affil-num=1
ORCID=
en-aut-name=OshitaKoji
en-aut-sei=Oshita
en-aut-mei=Koji
kn-aut-name=大下浩司
kn-aut-sei=大下
kn-aut-mei=浩司
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=2
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=3
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=4
en-affil=
kn-affil=岡山大学理学部化学科
en-keyword=chitosan resin
kn-keyword=chitosan resin
en-keyword=dithiocarbamate
kn-keyword=dithiocarbamate
en-keyword=heavy metals
kn-keyword=heavy metals
en-keyword=elution method
kn-keyword=elution method
en-keyword=preconcentartion
kn-keyword=preconcentartion
END
start-ver=1.4
cd-journal=joma
no-vol=53
cd-vols=
no-issue=4
article-no=
start-page=345
end-page=351
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2004
dt-pub=2004
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Highly sensitive determination of boron with 1,8-dihydroxynaphthalene-3,6-disulfonic acid in ultrapurified water by fluorescence detection/flow-injection analysis
kn-title=クロモトロープ酸を用いる高感度蛍光検出/フローインジェクション分析法による超純水中の極微量ホウ素の定量
en-subtitle=
kn-subtitle=
en-abstract=Boron as boric acid was determined as a complex with chromotropic acid at pH 6.0 in an aqueous medium by fluorescence detection/flow-injection analysis. The complex was detected by measuring the fluorescence intensities (λ(ex) = 313 nm, λ(em) = 360 nm). EDTA was used as a buffer component with the role of a masking agent to metal ions. The background fluorescence of chromotropic acid could be decreased by mixing with 0.1 M ammonia water after complex formation, resulting in a stable baseline. The calibration graph was rectilinear over 10(−9)∼10(−6) mol dm(−3) (M), and the detection limit was 5×10(−10) M (S/N = 3). The reproducibility was 3.61% (n = 10, with the peak height) at 6×10(−9) M of boron and sample throughput was 40 h(−1). Applications to river water, ion-exchanged water and distilled water could be achived without any pretreatments. For the analysis of ultrapurified water, an evaporation/preconcentration procedure was carried out, because the concentration was under the LOD and no reference water which could be used for the carrier solution or preparation of the reagent solutions.
kn-abstract=超純水中の極微量ホウ素を定量するために，クロモトロープ酸を用いるホウ素の蛍光検出/フローインジェクション（FIA）法の諸条件を再検討し，検出限界を10分の1の5×10(－10) Mに下げることに成功し，大幅な感度向上を達成した．クロモトロープ酸とホウ酸との反応生成物の蛍光を利用するホウ素のFIA法における残存クロモトロープ酸の蛍光強度を低下させるために，アンモニア水を加え，アルカリ性にした．緩衝液としてエチレンジアミン四酢酸を含む酢酸緩衝液を用い，金属のマスキングを兼ねたpH調整を行うことにより，非常に安定なベースラインを得ることに成功した．流量，反応コイル長，試料注入量，試薬濃度等のFIAパラメーターについて感度向上の観点から最適化を行い，ホウ素錯体の蛍光測定（励起波長λ(ex)＝313 nm，蛍光波長λ(em)＝360 nm）により，前処理なしでホウ素10(－9) Mの定量が可能となった．S/N＝3での検出限界は5×10(－10) M（5 ppt）で，現在最も高感度な定量法である．ホウ素6×10(－9) Mの10回繰り返し実験の相対標準偏差（RSD）は3.6％（n＝10）であり，1時間に40試料の分析が可能であった．河川水，蒸留水，イオン交換水などに存在する程度の金属イオン及び陰イオンは定量を妨害しない．本法により，イオン交換水，蒸留水中に存在するホウ素は直接定量できた．超純水中に存在する微量のホウ素（10(－10) Mレベル）は，加熱濃縮操作法を併用することにより，定量可能となった．
en-copyright=
kn-copyright=
en-aut-name=LiZhen Hai
en-aut-sei=Li
en-aut-mei=Zhen Hai
kn-aut-name=李貞海
kn-aut-sei=李
kn-aut-mei=貞海
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学理学部
affil-num=2
en-affil=
kn-affil=岡山大学理学部
affil-num=3
en-affil=
kn-affil=岡山大学理学部
en-keyword=boron
kn-keyword=boron
en-keyword=chromotropic acid
kn-keyword=chromotropic acid
en-keyword=ultrapurified water
kn-keyword=ultrapurified water
en-keyword=fluorescence/flow injection analysis
kn-keyword=fluorescence/flow injection analysis
END
start-ver=1.4
cd-journal=joma
no-vol=53
cd-vols=
no-issue=1
article-no=
start-page=1
end-page=6
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2004
dt-pub=2004
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Development of a micro-flow titration method and application to acid-base titration
kn-title=微量フロー滴定分析法の開発と酸塩基滴定への応用
en-subtitle=
kn-subtitle=
en-abstract=A flow titration analysis method based on flow ratiometry was developed in this study from the viewpoint of simplicity, rapidity, automation, and cost efficiency. Sample and titrant solutions react while the solutions are continuously propelled by individual pumps at different flow rates. The flow rates are accurately controlled and changed independently, and the color change of an indicator gives an equivalent point. The concentration of analyte was determined by using the ratio of the flow rate and the equivalent point. The fundamental properties of the flow titration method were evaluated through acid-base titration, and compared with the conventional manual titration. When Phenolphthalein or Cresol Red was used as an indicator added in either the sample solution or the titrant solution, linear calibration graphs were obtained for all titrations examined, including strong and weak acids. The proposed method was applied to the titration of carbonate salt using Bromocresol Green and Phenolphthalein. Two isolated end-points were obtained in one sequential measurement corresponding to carbonate and bicarbonate ions. The proposed titration method was applied to the analysis of commercial vinegar samples. The results agreed well with the ones obtained by the conventional titration method; the relative standard deviations for the end point were within 0.3%. The volume of wastewater per one measurement can be reduced down to about 100 μl by the proposed method, while a practical method requires about 50 ml.
kn-abstract=容量分析法の簡便化，迅速化，自動化及び省力化を含む高機能化を目的として，送液ポンプの流量比に基づくフロー滴定システムの構築と応用について検討した．フロー滴定分析法は，連続して流れる試料液，滴定剤溶液の正確な流量制御を基本原理としている．2台の送液ポンプを用いてそれらの流量を変化させながら試料液（被滴定液）と滴定剤（滴定液）を送液し，流れ内において混合・反応させ，指示薬の変色を用いて試料液中の分析対象物質濃度を流量比から定量する容量分析法である．各種酸塩基滴定を通して本法の性能評価を行い，従来法との比較を行った．酸塩基指示薬としてフェノールフタレイン，あるいはクレゾールレッドを試料液又は滴定剤へ添加したところ，強酸，弱酸を問わず検討したすべての系において直線性の高い検量線が得られた．また，終点検出の相対標準偏差は0.3％未満であった．更に，滴定剤に2種類の指示薬を用いる多塩基酸・多酸塩基の連続滴定法について検討した．炭酸塩の分析ではブロモクレゾールグリーンとフェノールフタレインを指示薬として用い，炭酸イオン，重炭酸イオンに由来する二つの当量点を一試料測定で検出できた．
本法を市販されている食酢の分析に適用したところ，従来法により決定した酢酸濃度と良好な一致を得た．1試料測定当たりの廃液量は50 ml程度から100 μl程度まで大幅に低減化することができ，フロー滴定分析法により全操作の自動化，試料・廃液量の大幅な低減化，滴定時間の短縮等の高機能化を達成した．
en-copyright=
kn-copyright=
en-aut-name=KonishiHironobu
en-aut-sei=Konishi
en-aut-mei=Hironobu
kn-aut-name=小西明伸
kn-aut-sei=小西
kn-aut-mei=明伸
aut-affil-num=1
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=高柳俊夫
kn-aut-sei=高柳
kn-aut-mei=俊夫
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=2
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=3
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=4
en-affil=
kn-affil=岡山大学理学部化学科
en-keyword=flow titration analysis
kn-keyword=flow titration analysis
en-keyword=flow ratiometry
kn-keyword=flow ratiometry
en-keyword=acid-base titration
kn-keyword=acid-base titration
END
start-ver=1.4
cd-journal=joma
no-vol=103
cd-vols=
no-issue=4
article-no=
start-page=387
end-page=397
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1991
dt-pub=1991
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Studies on the lymphocyte function bronchial asthma Part 1. Examination of lymphocyte responsiveness with inhalation antigens of bronchial asthma
kn-title=気管支喘息におけるリンパ球機能に関する研究 第1編 気管支喘息におけるBAL 液中並びに末梢血中リンパ球の吸入抗原に対する幼若化反応の検討
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Various antigens such as mite and fungi have been known to provoke bronchoconstriction in patients with bronchial asthma. The allergic mechanisms of asthmatic attack induced by these antigens were analyzed to clarify the role of cellular immunity in the pathogenesis of bronchial asthma. Mite and Candida antigens were applied to lymphocyte blastogenesis in asthmatic patients. Both lymphocytes in bronchoalveolar lavage fluid (BALF) and in peripheral blood of asthmatic patients responded significantly to mite and Candida antiten. Furthermore, BALF lymphocytes of patients with non-atopic and intractable asthma showed higher responses against Candida antigen than those of patients with atopic and non-intractable asthma, while peripheral blood lymphocytes showed a higher response against mite antigen in patients with atopic and non-intractable asthma. These findings indicate that lymphocytes in lugns sensitized with Candida antigen might play an important role in the pathogenesis of non-atopic and intractable asthma.
en-copyright=
kn-copyright=
en-aut-name=TakadaSho
en-aut-sei=Takada
en-aut-mei=Sho
kn-aut-name=武田昌
kn-aut-sei=武田
kn-aut-mei=昌
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部第二内科学教室
en-keyword=気管支喘息
kn-keyword=気管支喘息
en-keyword=リンパ球幼若化反応
kn-keyword=リンパ球幼若化反応
en-keyword=bronchoalveolar lavage
kn-keyword=bronchoalveolar lavage
en-keyword=Candida
kn-keyword=Candida
en-keyword=mite
kn-keyword=mite
END
start-ver=1.4
cd-journal=joma
no-vol=104
cd-vols=
no-issue=9-10
article-no=
start-page=915
end-page=922
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1992
dt-pub=199210
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Development of double cancer in small cell lung cancer patients treated with intensive chemotherapy
kn-title=肺小細胞癌化学療法実施例における重複癌の発生に関する研究
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Development of double cancer was evaluated in 337 small cell lung cancer patients who had received intensive chemotherapy with or without radiotherapy. Of them, 14 patients (4.2%) developed a second malignancy: non-small cell lung cancer in six, stomach cancer in four, acute myelogenous leukemia in two, liver cancer in one, and esophagus cancer in one. The relative risk for the development of double cancer calculated by person-year method utilizing age and sex adjusted cancer incidence in Japan was 2.75-fold (P<0.01). The risk of non-small cell lung cancer (8.75-fold) and acute myelogenous leukemia (37.82-fold) was particularly high. The cumulative risk for the development of double cancer was 2.0% at 1 year, 4.1% at 2 years, 14.3% at 3 years, and 100% at 8.1 years. Of 27 patients who survived disease-free for more than 2 years, 10 patients died; five patients (50%) died of double cancer, two died of infectious disease, and only three patients died from recurrent small cell lung cancer. These findings indicate that a cautious follow-up program for the detection of double cancer is indicated in patients with small cell lung cancer.
en-copyright=
kn-copyright=
en-aut-name=MiyakeKenichi
en-aut-sei=Miyake
en-aut-mei=Kenichi
kn-aut-name=三宅賢一
kn-aut-sei=三宅
kn-aut-mei=賢一
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部第二内科学教室
en-keyword=肺小細胞癌
kn-keyword=肺小細胞癌
en-keyword=化学療法
kn-keyword=化学療法
en-keyword=重複癌
kn-keyword=重複癌
END
start-ver=1.4
cd-journal=joma
no-vol=104
cd-vols=
no-issue=1-2
article-no=
start-page=83
end-page=95
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1992
dt-pub=1992
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Studies on laser photocoagulation for retinopathy of prematurity
kn-title=レーザー光凝固による未熟児網膜症の治療に関する研究
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Forty eyes in twenty-two cases in the active phase of retinopathy of prematurity were treated with laser photocagulation. Thiry (93.7%) of the 32 eyes in type I and intermediate type were found in the cicartrical phase grade 1. In type Ⅱ in which cryocautery was used as combination therapy, only 2 eyes (25.0%) were found in grade 1, 2 eyes (25.0%) in grade 2, 1 eye (12.5%) in grade 4 and 3 eyes (37.5%) in grade 5. All 21 eyes in which photocoagulation was performed up to the middle of stage 3 were found in grade 1 (100%). However, among 11 eyes in which photocoagulation were performed in late stage 3, 9 eys (81.8%) were found in grade 1, and 2 eyes (18.2%) in grade 2. In conclusion, if adequate laser photocoagulation is performed in avascular ares at the middle of stage 3 of type Ⅰ and intermediate type, treatment in cicartrical phase grade 1 is possible. Laser photocoagulation is clearly more effective than the xenon are photocoagula-tion or cryocautery. However, in type Ⅱ it is difficult to control the condition by photocagulation alone, and early diagnosis followed by combination therapy using cryocautery is reqired.
en-copyright=
kn-copyright=
en-aut-name=OhtakiChiaki
en-aut-sei=Ohtaki
en-aut-mei=Chiaki
kn-aut-name=大滝千秋
kn-aut-sei=大滝
kn-aut-mei=千秋
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部眼科学教室
en-keyword=未熟児網膜症
kn-keyword=未熟児網膜症
en-keyword=レーザー光凝固
kn-keyword=レーザー光凝固
END
start-ver=1.4
cd-journal=joma
no-vol=104
cd-vols=
no-issue=9-10
article-no=
start-page=885
end-page=895
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1992
dt-pub=199210
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=The effect of nutritional intake on energy metabolism in postoperative patients after gastrointestinal surgery
kn-title=間接熱量測定による消化器手術後のエネルギー代謝の検討―投与量･投与経路の比較―
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Many studies have shown that enteral nutrition (EN) has nutritional effects comparable to total parenteral nutrition (TPN). However, the energy metabolism of the two different nutritioanl methods remains undefined. The two nutritional methods were compared by measuring the resting energy expenditure (REE) and nutritional assessment in postoperative patients after gastrointestinal surgery. The effects of different amounts of EN were also evaluated. Patients were diveded into three groups : Patients who were fed by EN of 30 Cal/kg/day (Group I, EN 30 : n=8), patients who were fed by EN of 40 Cal/kg/day (Group II, EN 40 : n=8), and patients who were fed by TPN of 30 Cal/kg/day (Group III, TPN : n=8). REE was measured by the Datex indirect calorimetry and nutritional assessment included the measurements of triceps skinfold thickness (TSF), arm muscle circumference (AMC), albumin and rapid turnover proteins. ％REE/BEE of EN30, EN40 and TPN was 122.5±14.3%, 138.2±16.8% and 107.6±10.5% respectively. The RQ for the three groups was about 1.0, which means the energy source of all regimens is carbohydrate. The TPN group showed a significantly higher RQ than the EN groups, but there was no difference in albumin or transferrin. There was no difference in nutritional effect between EN 30 and EN 40. No difference was found in anthropometric effects among the three groups. These findings suggest that 30 Cal/kg/day would be preferable to 40 Cal/kg/day in energy supply of enteral nutrition and that the energy expenditure of EN is higher than that of TPN under 30 Cal/kg/day nutrition. There is no difference among the three mehtods in terms of nutritional effects.
en-copyright=
kn-copyright=
en-aut-name=YoshizaneKen
en-aut-sei=Yoshizane
en-aut-mei=Ken
kn-aut-name=吉實憲
kn-aut-sei=吉實
kn-aut-mei=憲
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部第二外科学教室
en-keyword=間接熱量計
kn-keyword=間接熱量計
en-keyword=経腸栄養
kn-keyword=経腸栄養
en-keyword=経静脈栄養
kn-keyword=経静脈栄養
en-keyword=代謝熱量
kn-keyword=代謝熱量
END
start-ver=1.4
cd-journal=joma
no-vol=106
cd-vols=
no-issue=5-6
article-no=
start-page=663
end-page=668
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1994
dt-pub=1994
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Senile diabetes mellitus complicated with celiac arterial obliteration and heaptocellular carinoma : A case report
kn-title=腹腔動脈完全閉塞をきたした肝細胞癌合併高齢者糖尿病の興味ある一例
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=We report a 75-year-old female with diabetes mellitus complicated with celiac arterial obliteration and hepatocellular cercinoma (HCC). She had been treated with diet therapy by her family doctor for essential hypertension and diabetes mellitus and was referred to our hospital because a space occupying lesion (SOL) was detected in the liver by abdominal CT examination. The SOL was confirmed as hepatocellular carcinoma by ultrasonography and magnetic resoance imaging. Celiac angiography revealed complete obliteration of the celiac artery probably due to diabetic macroangiopathy. Sine the deterioration of the liver function was not conspicuous, it was suggested that the development of HCC was affected by diabetes mellitus.
en-copyright=
kn-copyright=
en-aut-name=OkaTakahiko
en-aut-sei=Oka
en-aut-mei=Takahiko
kn-aut-name=岡隆彦
kn-aut-sei=岡
kn-aut-mei=隆彦
aut-affil-num=1
ORCID=
en-aut-name=TomodaJun
en-aut-sei=Tomoda
en-aut-mei=Jun
kn-aut-name=友田純
kn-aut-sei=友田
kn-aut-mei=純
aut-affil-num=2
ORCID=
en-aut-name=KobashiHaruhiko
en-aut-sei=Kobashi
en-aut-mei=Haruhiko
kn-aut-name=小橋春彦
kn-aut-sei=小橋
kn-aut-mei=春彦
aut-affil-num=3
ORCID=
en-aut-name=SakaiNobuyuki
en-aut-sei=Sakai
en-aut-mei=Nobuyuki
kn-aut-name=坂井宣行
kn-aut-sei=坂井
kn-aut-mei=宣行
aut-affil-num=4
ORCID=
en-aut-name=SakaguchiKohsaku
en-aut-sei=Sakaguchi
en-aut-mei=Kohsaku
kn-aut-name=坂口孝作
kn-aut-sei=坂口
kn-aut-mei=孝作
aut-affil-num=5
ORCID=
en-aut-name=YamamotoKazuhide
en-aut-sei=Yamamoto
en-aut-mei=Kazuhide
kn-aut-name=山本和秀
kn-aut-sei=山本
kn-aut-mei=和秀
aut-affil-num=6
ORCID=
en-aut-name=HigashiToshihiro
en-aut-sei=Higashi
en-aut-mei=Toshihiro
kn-aut-name=東俊宏
kn-aut-sei=東
kn-aut-mei=俊宏
aut-affil-num=7
ORCID=
en-aut-name=ItoToshio
en-aut-sei=Ito
en-aut-mei=Toshio
kn-aut-name=伊藤俊雄
kn-aut-sei=伊藤
kn-aut-mei=俊雄
aut-affil-num=8
ORCID=
en-aut-name=YamadaGotaro
en-aut-sei=Yamada
en-aut-mei=Gotaro
kn-aut-name=山田剛太郎
kn-aut-sei=山田
kn-aut-mei=剛太郎
aut-affil-num=9
ORCID=
en-aut-name=TsujiTakao
en-aut-sei=Tsuji
en-aut-mei=Takao
kn-aut-name=辻孝夫
kn-aut-sei=辻
kn-aut-mei=孝夫
aut-affil-num=10
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部第一内科学教室
affil-num=2
en-affil=
kn-affil=岡山大学医学部第一内科学教室
affil-num=3
en-affil=
kn-affil=岡山大学医学部第一内科学教室
affil-num=4
en-affil=
kn-affil=岡山大学医学部第一内科学教室
affil-num=5
en-affil=
kn-affil=岡山大学医学部第一内科学教室
affil-num=6
en-affil=
kn-affil=岡山大学医学部第一内科学教室
affil-num=7
en-affil=
kn-affil=岡山大学医学部第一内科学教室
affil-num=8
en-affil=
kn-affil=岡山大学医学部第一内科学教室
affil-num=9
en-affil=
kn-affil=岡山大学医学部第一内科学教室
affil-num=10
en-affil=
kn-affil=岡山大学医学部第一内科学教室
en-keyword=糖尿病
kn-keyword=糖尿病
en-keyword=腹腔動脈閉塞
kn-keyword=腹腔動脈閉塞
en-keyword=肝細胞癌
kn-keyword=肝細胞癌
en-keyword=動脈硬化
kn-keyword=動脈硬化
END
start-ver=1.4
cd-journal=joma
no-vol=104
cd-vols=
no-issue=7-8
article-no=
start-page=789
end-page=795
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1992
dt-pub=199208
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=The relationships between physique and throwing ability in high school baseball players
kn-title=高校野球選手における形態と投能力の関係
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=There is little information on anthropometric measures (i. e., length, breadth and girth of body's parts) related to throwing ability. To clarify the influence of the physique on the throwing ability, the relationships between physique and throwing distance, as well as ball speed were investigated. The subjects were fourty-nine high school baseball players, and thirty-eight high school volleyball players, football players and canoeists served as a control group. The throwing distance was significantly related to lean body mass (r=.290), chest girth (r=.416), upper arm girth (r=.307), abdominal girth (r=.288), thigh girth (r=.327) and lower leg girth (r=.285) in baseball players group (p<0.05-0.01). A significant relationship between the throwing distance and foot length in control group (r=.329, p<0.05) was demonstrated. Significant relationships between ball speed and standing height in the baseball players group (r=.354, p<0.01) and that between ball speed and Impedance in the control group (r=-.288, p<0.05) were ovserved. These findings indicate that the throwing distance is influenced by quantity of body muscle in baseball players. There was no relation between physique and throwing ability in unskilled players.
en-copyright=
kn-copyright=
en-aut-name=UchidaHayato
en-aut-sei=Uchida
en-aut-mei=Hayato
kn-aut-name=内田勇人
kn-aut-sei=内田
kn-aut-mei=勇人
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部衛生学教室
en-keyword=野球選手
kn-keyword=野球選手
en-keyword=形態
kn-keyword=形態
en-keyword=遠投距離
kn-keyword=遠投距離
en-keyword=ボールスピード
kn-keyword=ボールスピード
en-keyword=Impedance
kn-keyword=Impedance
END
start-ver=1.4
cd-journal=joma
no-vol=104
cd-vols=
no-issue=7-8
article-no=
start-page=763
end-page=775
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1992
dt-pub=199208
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Studies on the role of neutrophils in intractable asthma Part 1. Leukotriene and superoxide production of neutrophils
kn-title=難治性喘息における好中球の役割に関する研究 第1編 好中球からの Leukotrienes 産生能及び superoxide 産生能に関する検討
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=The role of neutrophils migrated in the sputum and bronchoalveolar lavage fluid of intractable asthmatics is not difficult to understand. The production of leukotrienes (LTs) and superoxide stimulated by the calcium ionophores (CaI) from neutrophil-rich fraction of 29 intractable, 70 non-intractable asthmatics and 18 healthy subjects was examined by high performance liquid chromatography and a cytochrome C reduction method. Significantly larger amounts of LTC(4) and LTB(4) were produced by CaI in the neutrophil-rich fraction from asthematics, than in that from the healthy subjects (p<0.01). Moreover, a significantly larger amounts of LTC(4) was producted in the fraction obtained from the intractable asthmatics than in that from the non-intractable asthmatics (p<0.05). However, there was no significant difference in LTB(4) production between the two groups of asthmatics. The production of superoxide by concanavalin A was significantly increased in the neutrophil-rich fraction from prednisolone-within-10mg-dependent asthmatics than in those from prednisolone-over-10mg-dependent patients (p<0.01). There were correlations between the LTC(4) and LTB(4) production, and also between LTB(4) and superoxide production. LTs and superoxide released from inflammatory cells, especially neutrophils, may play an important role in the pathgenesis of intractable asthma.
en-copyright=
kn-copyright=
en-aut-name=ShimizuIkki
en-aut-sei=Shimizu
en-aut-mei=Ikki
kn-aut-name=清水一紀
kn-aut-sei=清水
kn-aut-mei=一紀
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部第二内科学教室
en-keyword=難治性喘息
kn-keyword=難治性喘息
en-keyword=好中球
kn-keyword=好中球
en-keyword=ロイコトリエン
kn-keyword=ロイコトリエン
en-keyword=スーパーオキサイド
kn-keyword=スーパーオキサイド
END
start-ver=1.4
cd-journal=joma
no-vol=53
cd-vols=
no-issue=7
article-no=
start-page=723
end-page=728
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2004
dt-pub=20041022
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Separation and determination of n-alkylamines by reversed-phase high-performance liquid chromatography coupled with merging zone derivatization to water-soluble Schiff bases
kn-title=水溶性シッフ塩基へのマージングゾーン誘導体化/逆相分配高速液体クロマトグラフィーによるn-アルキルアミン類の分離定量
en-subtitle=
kn-subtitle=
en-abstract=n-アルキルアミン類の分離定量法として，陰イオン性アルデヒドを誘導体化試薬として用いる吸光検出-逆相分配高速液体クロマトグラフィーを検討した．誘導体化試薬としては，サリチルアルデヒド-5-スルホン酸イオン（SAS）と4-（4-スルホフェニルアゾ）-1-ヒドロキシ-2-ナフトアルデヒド（SPAHNA）を用いた．n-アルキルアミンを含む試料溶液と試薬溶液はそれぞれの流路に同時に注入され，マージングゾーン法によりオンラインで混合され，5 m，70℃ の反応コイル中で水溶性シッフ塩基へと誘導体化された．生成した水溶性シッフ塩基は逆相カラムにより分離され，吸光検出された．オンライン誘導体化とカラム分離/検出を含む分析時間は，SASを用いた場合25分，SPAHNAを用いた場合は18分であった．アルキルアミン類に対する検量線は0～50 μMの範囲で良好な直線性が得られ，検出限界は，SASを用いた場合0.5～1.0 μM，SPAHNAを用いた場合は0.08～0.20 μMであった．
kn-abstract=Separation and determination of n-alkylamines were investigated with anionic aldehydes to form water-soluble Schiff bases by using reversed-phase high-performance liquid chromatography (RP-HPLC). Two labeling reagents of salicylaldehyde-5-sulfonate (SAS) and 4-(4-sulfophenylazo)-1-hydroxy-2-naphthaldehyde (SPAHNA) were investigated. Sample solution containing the analytes and reagent solution were simultaneously injected and merged in the flow line, and water-soluble Schiff bases were formed in the reaction tube with its length of 5 m and at 70°C. The Schiff bases were resolved with water-methanol eluent on a reversed-phase column and photometrically detected. The entire analysis time including on-line derivatization, column separation and detection was accomplished within 25 min with SAS and 18 min with SPAHNA. The determination range for the n-alkylamines are 0∼50 μM with the limit of detections at 0.5∼1.0 μM for SAS and 0.08∼0.20 μM for SPAHNA.
en-copyright=
kn-copyright=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=高柳俊夫
kn-aut-sei=高柳
kn-aut-mei=俊夫
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=DriouichRim
kn-aut-sei=Driouich
kn-aut-mei=Rim
aut-affil-num=2
ORCID=
en-aut-name=SawaiKuniko
en-aut-sei=Sawai
en-aut-mei=Kuniko
kn-aut-name=澤井邦子
kn-aut-sei=澤井
kn-aut-mei=邦子
aut-affil-num=3
ORCID=
en-aut-name=LiQiong
en-aut-sei=Li
en-aut-mei=Qiong
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=4
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=5
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=6
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=2
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=3
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=4
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=5
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=6
en-affil=
kn-affil=岡山大学理学部化学科
en-keyword=n-alkylamines
kn-keyword=n-alkylamines
en-keyword=salicylaldehyde-5-sulfonate
kn-keyword=salicylaldehyde-5-sulfonate
en-keyword=4-(4-sulfophenylazo)-1-hydroxy-2-naphthaldehyde
kn-keyword=4-(4-sulfophenylazo)-1-hydroxy-2-naphthaldehyde
en-keyword=merging zone
kn-keyword=merging zone
en-keyword=reversed-phase HPLC
kn-keyword=reversed-phase HPLC
END
start-ver=1.4
cd-journal=joma
no-vol=53
cd-vols=
no-issue=4
article-no=
start-page=309
end-page=314
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2004
dt-pub=20040914
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Rapid and simple determination of chemical oxygen demand (COD) with potassium permanganate as an oxidizing agent by a flow-injection technique using a platinum-tube reactor
kn-title=白金チューブを反応管として用いる過マンガン酸カリウム酸化/フローインジェクション分析法による化学的酸素要求量の迅速定量
en-subtitle=
kn-subtitle=
en-abstract=化学的酸素要求量（COD）の迅速定量についてフローインジェクション/吸光光度定量の検討を行った．過マンガン酸カリウムを酸化剤として用い，この酸化反応の反応時間を促進させ，短縮するため触媒を用いる方法について検討した．その結果，白金チューブを反応コイルとして用いることにより，酸化反応が促進され測定時間を大幅に短縮できることが分かった．白金チューブ反応コイルのフローインジェクション分析（FIA）法への適用について詳細な検討を行った結果，D-グルコースを標準物質としたとき，検量線は0～100 ppmの範囲で良好な直線性を示した．S/N＝3に相当する検出限界は0.01 ppmであり，5，10，20，50，100 ppmのD-グルコースに対する相対標準偏差は，それぞれ0.9，0.8，0.8，0.5，1.4％であった．本FIA法は，排水のCOD迅速定量に適用可能であり，またCODモニターとして利用できる．
kn-abstract=A rapid and simple spectrophotometric determination method for chemical oxygen demand in water samples was developed using a flow-injection method. The detection method is based on the permanganate oxidation reaction accelerated by a catalyst. A platinum tube reactor was installed after the merging point of a carrier and a reagent stream as a catalyst and a reactor coil, and was heated at 95°C by an aluminum heating block. By using the platinum tube reactor (0.5 mm i.d.×3 m), a standard sample, D-glucose, was measured within a few minutes, and the calibration graph was linear from 0 to 100 ppm of COD(D-glucose); the detection limit corresponding to S/N = 3 was 0.01 ppm. The relative standard deviations for 5, 10, 50 and 100 ppm of COD(D-glucose) were 0.9, 0.8, 0.8, 0.5 and 1.4%, respectively. The proposed FIA system can be applied to waste water or can be used as a monitor of COD.
en-copyright=
kn-copyright=
en-aut-name=TsuboiTomonori
en-aut-sei=Tsuboi
en-aut-mei=Tomonori
kn-aut-name=坪井知則
kn-aut-sei=坪井
kn-aut-mei=知則
aut-affil-num=1
ORCID=
en-aut-name=HiranoYoshio
en-aut-sei=Hirano
en-aut-mei=Yoshio
kn-aut-name=平野義男
kn-aut-sei=平野
kn-aut-mei=義男
aut-affil-num=2
ORCID=
en-aut-name=KinoshitaKazuyoshi
en-aut-sei=Kinoshita
en-aut-mei=Kazuyoshi
kn-aut-name=木下一次
kn-aut-sei=木下
kn-aut-mei=一次
aut-affil-num=3
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=4
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=5
ORCID=
affil-num=1
en-affil=
kn-affil=中国電力株式会社技術研究センター
affil-num=2
en-affil=
kn-affil=中国電力株式会社技術研究センター
affil-num=3
en-affil=
kn-affil=岡山大学理学部
affil-num=4
en-affil=
kn-affil=岡山大学理学部
affil-num=5
en-affil=
kn-affil=岡山大学理学部
en-keyword=chemical oxygen demand
kn-keyword=chemical oxygen demand
en-keyword=FIA
kn-keyword=FIA
en-keyword=spectrophotometry
kn-keyword=spectrophotometry
en-keyword=platinum catalyst
kn-keyword=platinum catalyst
en-keyword=potassium permanganate
kn-keyword=potassium permanganate
en-keyword=waste water
kn-keyword=waste water
END
start-ver=1.4
cd-journal=joma
no-vol=53
cd-vols=
no-issue=9
article-no=
start-page=919
end-page=923
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2004
dt-pub=20041224
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Determination of anionic surfactants using newly synthesized n-dialkyl-2,2'-thiacyanine dyes
kn-title=シアニン系新規合成試薬を用いる陰イオン界面活性剤の定量
en-subtitle=
kn-subtitle=
en-abstract=水溶液一相系でイオン会合反応を利用する陰イオン界面活性剤直接定量のための陽イオン性染料を新規に合成した．基本骨格はシアニンとし，二つのNに炭素数の異なるn -アルキル鎖を導入した四級塩染料を合成した．アルキル鎖の炭素数4と6のものは新規合成化合物であり，(p)K(a)を求めた．炭素数2と3の市販品と合成した陽イオン試薬を用い，吸光光度法により陰イオン界面活性剤（DBS）との最適反応条件を検討した．3,3'-ジヘキシル-2,2'-チアシアニン（DHT，C6の試薬）を用いて，10(－6) MオーダーのDBSを定量することができ，検出下限は4×10(－7) Mであった．また，疎水性相互作用により，非イオン性界面活性剤，陽イオン界面活性剤とも反応することが分かり，DHTとのイオン会合定数を求めた．
kn-abstract=For the spectrophotometric determination of anionic surfactants in aqueous media, cationic dyes with a 2,2'-thiacyanine skeleton were newly synthesized. Carbon numbers of 4 and 6 in the n-dialkyl chain combined at the N position of 2,2'-thiacyanine are new compounds. Fundamental information, such as the (p)K(a) values, was obtained. These two compounds and purchased diethyl- and dipropyl-2,2'-thiacyanine were examined for the spectrophotometric determination of an anionic surfactant, DBS. Of these, 3,3'-dihexyl-2,2'-thiacyanine (DHT) showed the best sensitivity. The calibration graph for DBS with DHT was linear up to 1×10(−5) M, and the detection limit was 4×10(−7) M. By a hydrophobic interaction, even a cationic surfactant, Zephiramine, and a nonionic surfactant, Triton X-100, could react with DHT. The ion-association constants for these surfactants with DHT were obtained.
en-copyright=
kn-copyright=
en-aut-name=GotoAkinori
en-aut-sei=Goto
en-aut-mei=Akinori
kn-aut-name=後藤晃範
kn-aut-sei=後藤
kn-aut-mei=晃範
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=高柳俊夫
kn-aut-sei=高柳
kn-aut-mei=俊夫
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学理学部
affil-num=2
en-affil=
kn-affil=岡山大学理学部
affil-num=3
en-affil=
kn-affil=岡山大学理学部
affil-num=4
en-affil=
kn-affil=岡山大学理学部
en-keyword=n-dialkyl-2,2'-thiacyanine dyes
kn-keyword=n-dialkyl-2,2'-thiacyanine dyes
en-keyword=surfactants
kn-keyword=surfactants
en-keyword=ion association
kn-keyword=ion association
en-keyword=spectrophotometry
kn-keyword=spectrophotometry
END
start-ver=1.4
cd-journal=joma
no-vol=105
cd-vols=
no-issue=5-6
article-no=
start-page=419
end-page=426
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1993
dt-pub=1993
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Adrenal secretion of catecholamines by inhalation of radon water in relation to an increase of the tissue perfusion rate in rabbits
kn-title=ラドン水吸入による家兎の副腎髄質カテコラミン分泌作用―組織循環増加作用との関わりについて―
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=To clarify the relationship between in the increase in subcutaneous tissue perfusion rate (TPR) upon inhalation of radon water and the vasoactive effects of radon, rabbits inhaled nebulized water containing 14,000-18,000 Bq/1 radon (radon group) taken from Ikeda Mineral Spring, Shimane Pref., Japan. Control rabbits inhaled radon water from the same springs which had been kept for over 10 radon half-life periods. TPR was evaluated 15 minutes after the beginning of inhalation by mass spectrometry. After inhalation for 90 minutes, plasma and adrenal glands were removed, and levels of adrenaline and noradrenaline were analyzed by high-performance liquid chromatography (THI mithod). Each group was divided into 4 subgroups according to intravenously injected medication as follows : 1) no medication (without adrenergic blocker), 2) phentolamine (α-blocker), 0.05mg/kg/min, 3) propranolol (non-selective β-blocker), 1mg/kg, and 4) atenolol (selective β1-blocker), 6mg/kg. In the radon group, plasma adrenaline and noradrenaline levels were significantly higher (p<0.01, p<0.05), and adrenaline and noradrenaline levels were significantly lower (p<0.01, P<0.01), than those in the control group. In the no medication and phentolamine subgroups, TPRs in the radon group were significantly higher than those in the control group (p<0.01, P<0.01). In the propranolol and atenolol subgroups, no significant change of TPR was found. It is suggested that catecholamines are secreted from the adrenal glands upon inhalation of radon water and that the β1-action of catecholamines contributes to the increase in tissue perfusion.
en-copyright=
kn-copyright=
en-aut-name=SuzukaIchio
en-aut-sei=Suzuka
en-aut-mei=Ichio
kn-aut-name=鈴鹿伊智雄
kn-aut-sei=鈴鹿
kn-aut-mei=伊智雄
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部心臓血管外科学教室
en-keyword=ラドン水
kn-keyword=ラドン水
en-keyword=副腎髄質
kn-keyword=副腎髄質
en-keyword=カテコラミン
kn-keyword=カテコラミン
en-keyword=組織循環
kn-keyword=組織循環
en-keyword=ホルミシス
kn-keyword=ホルミシス
END
start-ver=1.4
cd-journal=joma
no-vol=54
cd-vols=
no-issue=10
article-no=
start-page=953
end-page=957
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2004
dt-pub=20041222
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Determination of Trace Amounts of Ammonia in Air Using a Batchwise Collection/Concentration Method by Spectrophotometry
kn-title=簡易捕集濃縮/吸光光度法による大気中微量アンモニアの定量
en-subtitle=
kn-subtitle=
en-abstract=Ammonia in the atmosphere can be determined by an improved indophenol method with 1-naphthol. Ammonia dissolved in water reacts with sodium hypochlorite in the presence of sodium hydroxide and 1-naphthol to form an indophenol blue dye, which can be measured at 720 nm (maximum absorbance). Since ammonia in the atmosphere can be absorbed in purified water almost completely, a calibration graph using standard aqueous ammonium chloride solutions can be used. The calibration graph showed a good linearity (y = 0.37 × 10(5)x+0.027, R(2) = 0.9992) and the detection limit was 0.9 × 10(−6) M. For practical samples, the air was collected into a 50 ml plastic syringe with an air-tight cap containing 3.0 ml of purified water as the absorbing solution, followed by shaking it by hand. The method was successfully applied to the determination of ammonia in indoor and outdoor air samples.
kn-abstract=大気中のアンモニア定量法として1-ナフトールを用いるインドフェノール法を検討した．水溶液中のアンモニアは水酸化ナトリウム存在下で次亜塩素酸ナトリウム，1-ナフトールと反応し，インドフェノール型色素を生成する．この生成物の極大吸収波長である720 nmで吸光度を測定すること（1-ナフトール法）により，大気中のアンモニアを定量した．塩化アンモニウム標準溶液を用いる検量線は良好な直線性を示し（y＝0.37 × 105 x＋0.027，R(2)＝0.9992），検出限界は0.9 × 10(－6) Mであった．アセトンを10％ 加えることにより，均一溶液中で既報の約5倍の感度が得られた．2.0 × 10(－5) M塩化アンモニウム標準溶液を用いた場合の相対標準偏差は3.5％ と良好であった．実試料への応用として，超純水3.0 mlを入れた50 mlプラスチック製シリンジ（実体積: 69.1±0.3 ml）に大気試料を捕集し，シリンジにキャップをして4分間振り混ぜた．大気中のアンモニアは吸収溶液として用いた超純水にほぼ完全に捕集濃縮できた．吸収したアンモニアを1-ナフトール法で測定した．本法は室内，屋外の大気中微量アンモニア定量に十分な精度と感度を示した．
en-copyright=
kn-copyright=
en-aut-name=SuekaneTakashi
en-aut-sei=Suekane
en-aut-mei=Takashi
kn-aut-name=末包高史
kn-aut-sei=末包
kn-aut-mei=高史
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学大学院自然科学研究科理学系
affil-num=2
en-affil=
kn-affil=岡山大学大学院自然科学研究科理学系
affil-num=3
en-affil=
kn-affil=岡山大学大学院自然科学研究科理学系
en-keyword=ammonia
kn-keyword=ammonia
en-keyword=1-naphthol
kn-keyword=1-naphthol
en-keyword=air sample
kn-keyword=air sample
en-keyword=spectrophotometry
kn-keyword=spectrophotometry
END
start-ver=1.4
cd-journal=joma
no-vol=53
cd-vols=
no-issue=9
article-no=
start-page=1039
end-page=1043
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2004
dt-pub=20041224
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Synthesis of iminodi(methylphosphonic acid)-type chitosan resin and its adsorption behavior for trace metals
kn-title=イミノ二メチルホスホン酸型キトサン樹脂の合成と微量金属の捕集挙動
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A chitosan-based resin possessing the iminodi(methylphosphonic acid) moiety (IDP-type chitosan resin) was synthesized by using cross-linked chitosan as a base material. The adsorption behavior of trace metal ions on the IDP-type chitosan resin was systematically investigated using a mini-column (1 ml of the resin) packed with the resin. The concentrations of metal ions in the effluents were measured by ICP-MS and ICP-AES. The resin could adsorb four metals, such as In(III), Sn(II), Th(IV), and U(VI), by almost 100% over a wide pH range (1∼7). Uranium(VI) and thorium could not be eluted with nitric acid and hydrochloric acid (1∼6 M); other metal ions were easily and readily eluted with 1 M nitric acid. The IDP-type chitosan resin synthesized in this work can be applied to the separation of U(VI) and Th(IV) from other metal ions.
en-copyright=
kn-copyright=
en-aut-name=YamakawaSatoko
en-aut-sei=Yamakawa
en-aut-mei=Satoko
kn-aut-name=山川聡子
kn-aut-sei=山川
kn-aut-mei=聡子
aut-affil-num=1
ORCID=
en-aut-name=OshitaKoji
en-aut-sei=Oshita
en-aut-mei=Koji
kn-aut-name=大下浩司
kn-aut-sei=大下
kn-aut-mei=浩司
aut-affil-num=2
ORCID=
en-aut-name=AkhmadSabarudin
en-aut-sei=Akhmad
en-aut-mei=Sabarudin
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=4
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=5
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=2
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=3
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=4
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=5
en-affil=
kn-affil=岡山大学理学部化学科
en-keyword=chitosan resin
kn-keyword=chitosan resin
en-keyword=iminodi(methylphosphonic acid (IDP)
kn-keyword=iminodi(methylphosphonic acid (IDP)
en-keyword=uranium(VI)
kn-keyword=uranium(VI)
en-keyword=thorium(IV)
kn-keyword=thorium(IV)
en-keyword=heavy metals
kn-keyword=heavy metals
END
start-ver=1.4
cd-journal=joma
no-vol=55
cd-vols=
no-issue=9
article-no=
start-page=707
end-page=713
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2006
dt-pub=20061117
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Development of Computer-Controlled Flow Injection Instruments and Its Application to Determination of Nitrate, Nitrite, and Ammonium Ions in Environmental Samples
kn-title=コンピュータ制御されたフローインジェクション分析装置の開発と環境水中の硝酸イオン，亜硝酸イオン，アンモニウムイオン定量への応用
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Flow injection analysis (FIA) systems with low power consumption and personal-computer control were developed by using solenoid pumps and an LED detector. Both programs for controlling the system and acquiring measurement data were written using LabVIEW. The FIA system was applied to the determination of nitrite ion in river-water samples based on diazotization and coupling reactions. Linear calibration graphs were obtained with the combination of pump(s) and photometric detector in the concentration range of nitrite ion at 0.5∼3.0 × 10−6 M. Nitrate and nitrite ions were also determined simultaneously by the system by using a Cd/Cu reduction column and a by-pass flow. Determination of ammonia in river-water samples was also realized by the system with a modified indophenol reaction.
en-copyright=
kn-copyright=
en-aut-name=JoichiYasutaka
en-aut-sei=Joichi
en-aut-mei=Yasutaka
kn-aut-name=城市康隆
kn-aut-sei=城市
kn-aut-mei=康隆
aut-affil-num=1
ORCID=
en-aut-name=NarongLenghor
en-aut-sei=Narong
en-aut-mei=Lenghor
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=高柳俊夫
kn-aut-sei=高柳
kn-aut-mei=俊夫
aut-affil-num=3
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=4
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=5
ORCID=
en-aut-name=UraNobuo
en-aut-sei=Ura
en-aut-mei=Nobuo
kn-aut-name=浦信夫
kn-aut-sei=浦
kn-aut-mei=信夫
aut-affil-num=6
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=2
en-affil=
kn-affil=岡山大学大学院自然科学研究科機能分子化学専攻
affil-num=3
en-affil=
kn-affil=岡山大学大学院自然科学研究科機能分子化学専攻
affil-num=4
en-affil=
kn-affil=岡山大学大学院自然科学研究科機能分子化学専攻
affil-num=5
en-affil=
kn-affil=岡山大学大学院自然科学研究科機能分子化学専攻
affil-num=6
en-affil=
kn-affil=株式会社相馬光学
en-keyword=Flow injection analysis
kn-keyword=Flow injection analysis
en-keyword=LabVIEW control
kn-keyword=LabVIEW control
en-keyword=solenoid pumps
kn-keyword=solenoid pumps
en-keyword=nitrate ion
kn-keyword=nitrate ion
en-keyword=nitrite ion
kn-keyword=nitrite ion
en-keyword=ammonia
kn-keyword=ammonia
END
start-ver=1.4
cd-journal=joma
no-vol=55
cd-vols=
no-issue=9
article-no=
start-page=715
end-page=720
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2006
dt-pub=20061117
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Highly Efficient and Automatic Collection/Concentration with Chelating Resin for Inductively Coupled Plasma Atomic Emission Spectroscopy
kn-title=誘導結合プラズマ発光分析のためのキレート樹脂を用いる高効率自動前処理濃縮
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=An automatically controlled collection/concentration system for ICP-AES was developed. Elements were collected with small chelating disks and chelating resin with the iminodiacetate moiety packed in a line filter. This column was installed in a 6-way valve on the pretreatment system, which could be connected on line to ICP-AES. The flow rate was 1 ml min−1 and conditioning of the chelating disk was carried out by flowing 0.5 M ammonium acetate (pH 5.5) for 2 min, sampling for 5 min and washing for 1 min. Elution was done by passing through 2 M HNO3 at 1.3 ml min−1 for 1 min. Bi, Cd, Co, Cr, Cu, Mn, Ni, Pb and V could be determined with 5.0 ml of the sample solution. The enrichment factors were 3∼15 times and the collection efficiencies were better than 80%. The detection limits (LOD) were from 0.003 for Mn to 0.311 for Bi, which were several 10 to 100-times lower than that of normal LOD of ICP-AES. This method was successfully applied to the determination of these metals in tap and river-water samples.
en-copyright=
kn-copyright=
en-aut-name=YamamotoTakako
en-aut-sei=Yamamoto
en-aut-mei=Takako
kn-aut-name=山本貴子
kn-aut-sei=山本
kn-aut-mei=貴子
aut-affil-num=1
ORCID=
en-aut-name=AkhmadSabarudin
en-aut-sei=Akhmad
en-aut-mei=Sabarudin
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=
en-aut-name=NoguchiOsamu
en-aut-sei=Noguchi
en-aut-mei=Osamu
kn-aut-name=野口修
kn-aut-sei=野口
kn-aut-mei=修
aut-affil-num=3
ORCID=
en-aut-name=TakayanagiToshio
en-aut-sei=Takayanagi
en-aut-mei=Toshio
kn-aut-name=高柳俊夫
kn-aut-sei=高柳
kn-aut-mei=俊夫
aut-affil-num=4
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=5
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=6
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学理学部化学科
affil-num=2
en-affil=
kn-affil=岡山大学大学院自然科学研究科機能分子化学専攻
affil-num=3
en-affil=
kn-affil=岡山大学大学院自然科学研究科機能分子化学専攻
affil-num=4
en-affil=
kn-affil=岡山大学大学院自然科学研究科機能分子化学専攻
affil-num=5
en-affil=
kn-affil=岡山大学大学院自然科学研究科機能分子化学専攻
affil-num=6
en-affil=
kn-affil=岡山大学大学院自然科学研究科機能分子化学専攻
en-keyword=automated collection/concentration
kn-keyword=automated collection/concentration
en-keyword=chelating disk and chelating resin
kn-keyword=chelating disk and chelating resin
en-keyword=ICP-AES
kn-keyword=ICP-AES
en-keyword=heavy metals
kn-keyword=heavy metals
END
start-ver=1.4
cd-journal=joma
no-vol=24
cd-vols=
no-issue=4
article-no=
start-page=505
end-page=508
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2008
dt-pub=20080410
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Spectrophotometric Determination of 1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide Hydrochloride by Flow Injection Analysis
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride (EDC·HCl) is a very useful agent to form amide bonds (peptide bonds) in an aqueous medium. A simple and fast detection system was developed using the reaction with pyridine and ethylenediamine in acidic aqueous solution and spectrophotometric flow injection analysis. The absorbances
were measured at 400 nm and the reaction was accelerated at 40˚C. The calibration graph showed good linearity from 0 to 10% of EDC·HCl solutions: the regression equation was y = 3.15 × 104x (y, peak area; x, % concentration of EDC·HCl). The RSD was under 1.0%. Sample throughput was 15 h–1. This method was applied to monitoring the EDC·HCl concentration that remained after the anhydration of phthalic acid in water, esterification of acetic acid in methanol or dehydration condensation of malonic acid and ethylenediamine in water.
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=KunihikoSeno
kn-aut-sei=Kunihiko
kn-aut-mei=Seno
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=KazukiMatsumura
kn-aut-sei=Kazuki
kn-aut-mei=Matsumura
aut-affil-num=2
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=3
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
affil-num=4
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=24
cd-vols=
no-issue=5
article-no=
start-page=631
end-page=635
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2008
dt-pub=20080510
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Minimization of Sample Volume with Air-segmented SampleInjection and the Simultaneous Determination of TraceElements by ICP-MS
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=The application of inductively coupled plasma mass spectrometry (ICP-MS) to forensic chemistry was studied. The
developed method, air-segmented sample injection (ASSI) coupled with ICP-MS, allowed the determination of about 25
elements at the sub-ppb level with only 0.2 ml of a sample solution. The optimum sample flow rate was found to be 0.4
ml min–1, along with a sample suction time of 30 s. The proposed method was validated by determining trace elements in river-water certified reference material (SLRS-4) issued by National Research Council Canada. The analytical results of the proposed method were in good agreement with the certified values. This method was successfully applied to a human hair sample, the volume of which was 3 ml.
en-copyright=
kn-copyright=
en-aut-name=NoguchiOsamu
en-aut-sei=Noguchi
en-aut-mei=Osamu
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=
en-aut-name=OshimaMitsuko
en-aut-sei=Oshima
en-aut-mei=Mitsuko
kn-aut-name=大島光子
kn-aut-sei=大島
kn-aut-mei=光子
aut-affil-num=2
ORCID=
en-aut-name=MotomizuShoji
en-aut-sei=Motomizu
en-aut-mei=Shoji
kn-aut-name=本水昌二
kn-aut-sei=本水
kn-aut-mei=昌二
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=109
cd-vols=
no-issue=1-2
article-no=
start-page=25
end-page=33
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1997
dt-pub=19970228
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Clinical studies on choroidal circulatory disturbance : Relationship between central cerous chorioretinopathy and choroidal circulatory disturbance
kn-title=脈絡膜循環障害に関する臨床的研究―中心性漿液性脈絡網膜症と脈絡膜循環障害の関連について―
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=In order to know frequency of choroidal circulatory disturbance, 126 eyes with central serouse chorioretinopathy followed-up between Jan. 1985 and Dec. 1990 were retrospectively investigated by fundus fluorescein angiography. Appearance of choroidal circulatory disturbance was divided into two types. The type 1 showed choroidal filling delay at late retinal venous phase. The type 2 showed mosaic pattern of choroidal background at late retinal venous phase. Among the 126 eyes, 3 eyes were type 1 (2.4%) and 57 eyes were type 2 (45.2%), totaling 60 eyes (47.6%). Sixty-three eyes with normal part of branch retinal vein occlusion matching in sex and age were selected as controls. In the controls, no eye was type 1 (0%) and 8 eyes were type 2 (12.7%), totaling 8 eyes (12.7%). Distinctly, proportion of the type 2 was higher in central serous chorioretinopathy than in branch retinal vein occlusion. In conclusion, the pathogenesis of central serous chorioretinopathy is related to choroidal circulatory disturbance and especially mosaic pattern (type 2) was found to be a new type of circulatory disturbance.
en-copyright=
kn-copyright=
en-aut-name=KawanishiYouko
en-aut-sei=Kawanishi
en-aut-mei=Youko
kn-aut-name=河西葉子
kn-aut-sei=河西
kn-aut-mei=葉子
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部眼科学教室
en-keyword=中心性漿液性脈絡網膜症
kn-keyword=中心性漿液性脈絡網膜症
en-keyword=フルオレセイン螢光造影
kn-keyword=フルオレセイン螢光造影
en-keyword=充盈遅延
kn-keyword=充盈遅延
en-keyword=モザイク模様
kn-keyword=モザイク模様
END
start-ver=1.4
cd-journal=joma
no-vol=106
cd-vols=
no-issue=7-8
article-no=
start-page=907
end-page=915
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1994
dt-pub=199408
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Establishment of antigen specific T cell clones from asthmatic patients including evaluation of cytokine production
kn-title=気管支喘息における抗原特異的 T cell clone の樹立とサイトカイン産生能に関する研究
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=To clarify the pathogenesis of bronchial asthma, we establishied T cell clones specific for Candida antigen and for mite antigen from the peripheral blood of three asthmatic patients. Flow cytometric analysis was performed on these clones. The surface phenotype of all clones was helper/inducer type. These clones were analyzed for the ability to produce interferon gammma (IFN-γ) and interleukin 4 (IL-4). The T cell clone established from tne patient who showed late asthmatic response (LAR) after bronchial inhalation of Candida, as well as the clones from the patient who showed IAR and LAR after inhalation of housedust mite, produced a higher amount of IFN-γ and lower amount of IL-4. The T cell clone established from the patient who were under corticosteroid therapy and showed IAR after inhalation of Candida produced lower amounts of IFN-γ and IL-4, which seemed to be inhibition of cytokine production from antigen specific T cell clone by corticosteroids. These findings indicate that T cell clones established from the patients who showed LAR produced a large amount of IFN-γ, suggesting that IFN-γ plays an important role in allergic reactions of LAR.
en-copyright=
kn-copyright=
en-aut-name=MiyaharaNobuaki
en-aut-sei=Miyahara
en-aut-mei=Nobuaki
kn-aut-name=宮原信明
kn-aut-sei=宮原
kn-aut-mei=信明
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部第二内科学教室
en-keyword=antigen specific T cell clone
kn-keyword=antigen specific T cell clone
en-keyword=IFN-γ
kn-keyword=IFN-γ
en-keyword=bronchial asthma
kn-keyword=bronchial asthma
en-keyword=late asthmatic response (LAR)
kn-keyword=late asthmatic response (LAR)
END
start-ver=1.4
cd-journal=joma
no-vol=106
cd-vols=
no-issue=7-8
article-no=
start-page=743
end-page=750
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1994
dt-pub=199408
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Studies on the occurrence of bronchial asthma Part 2. Lymphocytes activated by Cytomegalovirus
kn-title=気管支喘息の発症に関する研究 第2編 喘息患者におけるサイトメガロウイルス抗原によるリンパ球幼若化反応の検討
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=The possible role of virus infection in the occurrence and attack of asthma was examined by measuring the lymphocyte transformation test to CMV in 44 asthmatic and 14 healthy subjects and analyzed their relation to the clinical parameters. CMV-induced lymphocyte reactivity (CMV-LR) in adult asthmatics was significantly higher than that in the healthy controls. A positive correlation was observed between CMV-LR titer and CMV-complement fixation (CMV-CF) antibody titers (r=0.35). In adult asthmatics, the CMV-LR in the high IgE titer (100U/ml≦) group was significantly higher than that in the low IgE titer (<100U/ml) group.
These findings suggest that CMV is an important factor in the pathogenesis of adult asthma mediated by lymphocytes and probably IgE, although the precise mechanism in still unknown.
en-copyright=
kn-copyright=
en-aut-name=OkamotoMakoto
en-aut-sei=Okamoto
en-aut-mei=Makoto
kn-aut-name=岡本誠
kn-aut-sei=岡本
kn-aut-mei=誠
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部第二内科学教室
en-keyword=bronchial asthma
kn-keyword=bronchial asthma
en-keyword=viral infection
kn-keyword=viral infection
en-keyword=Cytomegalovirus
kn-keyword=Cytomegalovirus
en-keyword=IgE
kn-keyword=IgE
en-keyword=CMV-LTT
kn-keyword=CMV-LTT
END
start-ver=1.4
cd-journal=joma
no-vol=108
cd-vols=
no-issue=7-8
article-no=
start-page=215
end-page=223
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1996
dt-pub=19960831
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Serum levels of macrophage colony stimulating factor and other acute phase reactants after open heart surgery
kn-title=開心術後における Macrophage Colony-Stimulating Factor と急性相反応物質の血中動態について
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=To clarify the phathophysiological role of macrophage colony stimulating factor (M-CSF) in the healing processes of inflammation, we studied chronological changes in serum concentrations of M-CSF and other reactants during the acute phase of inflammation in patients who underwent open heart surgery, since these patients showed a precise point of tissue damage. The number of neutrophilic leukocytes increased in the very early postoperative stage, reached a peak 48 h after surgery and declined to the basal level at day 14. The chronological changes in serum C-reactive protein level after surgery were similar to these of neutrophic leukocytes. Serum M-CSF concentrations increased gradually, reached a peak 7 days after surgery and remained at that level until day 14. Based on these phenomena, it is assumed that M-CSF plays a pathophysiological role in the healing processes of an inflammation. Measurement of the serum concentration of M-CSF would be useful for evaluating the process of inflammation.
en-copyright=
kn-copyright=
en-aut-name=ChikakiyoHirokazu
en-aut-sei=Chikakiyo
en-aut-mei=Hirokazu
kn-aut-name=近清裕一
kn-aut-sei=近清
kn-aut-mei=裕一
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部公衆衛生学教室
en-keyword=M-CSF
kn-keyword=M-CSF
en-keyword=開心術
kn-keyword=開心術
en-keyword=白血球数
kn-keyword=白血球数
en-keyword=急性相反応物質
kn-keyword=急性相反応物質
en-keyword=サイトカイン
kn-keyword=サイトカイン
END
start-ver=1.4
cd-journal=joma
no-vol=112
cd-vols=
no-issue=9-12
article-no=
start-page=183
end-page=189
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2000
dt-pub=20001225
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=An investigation into the factors of smoking cessation in male smokers
kn-title=男性喫煙者の禁煙実行要因に関する研究
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=This syudy was designed to clarify what factors influenced the ability to stop smoking in male smokers, from the viewpoint of life-style guidance and primary care. Of the people who attended abult health examinations between 1993 and 1998 in Okayama Ctiy, 987 male smokers were selected and categorized according to the number of cigarettes per day into three groups. The relation was analyzed statistically between the three groups and the life-style related factors : age, the degree of obesity, sleep, snacks, salt, exercise and alcohol. The results showed significant differences in age, the degree of obesity, sleep, salt, exercise. Second, the relation between threse three groups and the experience and duration of smoking cessation was analyzed. The results showed a significant differnce in the experience of smoking cessation, but no significant differnce in duration of smoking cessation. The conclusions are as follows : 1. Male smokers, who do not activedy try to improve of their life-style related factors, have fewer experiences of smoking cessation, 2. Male smokers who try to improve their life-style habits have a similar period od smoking cessation to those who do not. 3. Long term support for all male smokers to continue to be non-smoking is important.
en-copyright=
kn-copyright=
en-aut-name=KawadaYuichi
en-aut-sei=Kawada
en-aut-mei=Yuichi
kn-aut-name=川田諭一
kn-aut-sei=川田
kn-aut-mei=諭一
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学医学部衛生医学講座
en-keyword=喫煙本数
kn-keyword=喫煙本数
en-keyword=生活習慣
kn-keyword=生活習慣
en-keyword=健康意識
kn-keyword=健康意識
en-keyword=健康意欲
kn-keyword=健康意欲
en-keyword=禁煙経験
kn-keyword=禁煙経験
en-keyword=再喫煙
kn-keyword=再喫煙
END
start-ver=1.4
cd-journal=joma
no-vol=118
cd-vols=
no-issue=1
article-no=
start-page=41
end-page=45
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2006
dt-pub=20060501
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Two cases of acute pulmonary embolism after esophageal cancer operation
kn-title=早期診断し得た食道癌術後静脈血栓塞栓症の2例
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=We encountered two cases of pulmonary embolism (PE)/venous thrombs (DVT) after surgery for esophageal cancer. The first case was a 58-year-old male. He underwent a subtotal esophagectomy and reconstruction using the stomach via the subcutaneus route. His postoperative course was stable; however, 13 days after the operation､ he had an elevated fever and pulmonary thrombi were observed on CT-scan screening. Scintigraphy confirmed the thrombi. An inferior vena cava filter (IVCF) was inserted and anti-coagulation therapy using heparin was started. His fever subsided, and 35 days after the operation, the thrombi disappeared. He was discharged thereafter and is being followed up using warfarin. The second case was a 74-year-old male. He also underwent subtotal esophagectomy and reconstruction using the stomach via the subcutaneus route. A central line was inserted via right femoral vein; however, the artery was injured and pressurization to the vessel was needed. His post-operative course was stable and symptom-free; however, ultrasound screening detected DVT in his right femoral vein. IVCF was mserted and anti-coagulation therapy was begun, thrombi disappeared 8 days after the therapy.
en-copyright=
kn-copyright=
en-aut-name=KanazawaTakashi
en-aut-sei=Kanazawa
en-aut-mei=Takashi
kn-aut-name=金澤卓
kn-aut-sei=金澤
kn-aut-mei=卓
aut-affil-num=1
ORCID=
en-aut-name=WatababeNobuyuki
en-aut-sei=Watababe
en-aut-mei=Nobuyuki
kn-aut-name=渡辺信之
kn-aut-sei=渡辺
kn-aut-mei=信之
aut-affil-num=2
ORCID=
en-aut-name=NaomotoYoshio
en-aut-sei=Naomoto
en-aut-mei=Yoshio
kn-aut-name=猶本良夫
kn-aut-sei=猶本
kn-aut-mei=良夫
aut-affil-num=3
ORCID=
en-aut-name=KobayashiMasahiko
en-aut-sei=Kobayashi
en-aut-mei=Masahiko
kn-aut-name=小林正彦
kn-aut-sei=小林
kn-aut-mei=正彦
aut-affil-num=4
ORCID=
en-aut-name=ShirakawaYasuhiro
en-aut-sei=Shirakawa
en-aut-mei=Yasuhiro
kn-aut-name=白川靖博
kn-aut-sei=白川
kn-aut-mei=靖博
aut-affil-num=5
ORCID=
en-aut-name=YamatsujiTomoki
en-aut-sei=Yamatsuji
en-aut-mei=Tomoki
kn-aut-name=山辻知樹
kn-aut-sei=山辻
kn-aut-mei=知樹
aut-affil-num=6
ORCID=
en-aut-name=KobayashiNaoya
en-aut-sei=Kobayashi
en-aut-mei=Naoya
kn-aut-name=小林直哉
kn-aut-sei=小林
kn-aut-mei=直哉
aut-affil-num=7
ORCID=
en-aut-name=FujiwaraTohsiyoshi
en-aut-sei=Fujiwara
en-aut-mei=Tohsiyoshi
kn-aut-name=藤原俊義
kn-aut-sei=藤原
kn-aut-mei=俊義
aut-affil-num=8
ORCID=
en-aut-name=MatsubaraNagahide
en-aut-sei=Matsubara
en-aut-mei=Nagahide
kn-aut-name=松原長秀
kn-aut-sei=松原
kn-aut-mei=長秀
aut-affil-num=9
ORCID=
en-aut-name=IwagakiHiromi
en-aut-sei=Iwagaki
en-aut-mei=Hiromi
kn-aut-name=岩垣博巳
kn-aut-sei=岩垣
kn-aut-mei=博巳
aut-affil-num=10
ORCID=
en-aut-name=MatsuokaJunji
en-aut-sei=Matsuoka
en-aut-mei=Junji
kn-aut-name=松岡順治
kn-aut-sei=松岡
kn-aut-mei=順治
aut-affil-num=11
ORCID=
en-aut-name=TanakaNoriaki
en-aut-sei=Tanaka
en-aut-mei=Noriaki
kn-aut-name=田中紀章
kn-aut-sei=田中
kn-aut-mei=紀章
aut-affil-num=12
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 消化器・腫瘍外科学
affil-num=2
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 消化器・腫瘍外科学
affil-num=3
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 消化器・腫瘍外科学
affil-num=4
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 消化器・腫瘍外科学
affil-num=5
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 消化器・腫瘍外科学
affil-num=6
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 消化器・腫瘍外科学
affil-num=7
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 消化器・腫瘍外科学
affil-num=8
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 消化器・腫瘍外科学
affil-num=9
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 消化器・腫瘍外科学
affil-num=10
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 消化器・腫瘍外科学
affil-num=11
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 消化器・腫瘍外科学
affil-num=12
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 消化器・腫瘍外科学
en-keyword=食道癌 (esophageal cancer)
kn-keyword=食道癌 (esophageal cancer)
en-keyword=肺塞栓症 (pulmonary embolism)
kn-keyword=肺塞栓症 (pulmonary embolism)
en-keyword=深部静脈血栓症 (deep venous thrombs)
kn-keyword=深部静脈血栓症 (deep venous thrombs)
END
start-ver=1.4
cd-journal=joma
no-vol=118
cd-vols=
no-issue=3
article-no=
start-page=209
end-page=213
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20070104
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=ボツリヌスC型とD型神経毒素を支配するバクテリオファージの遺伝子解析と溶原化の分子機構
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=阪口義彦
kn-aut-sei=阪口
kn-aut-mei=義彦
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=林哲也
kn-aut-sei=林
kn-aut-mei=哲也
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=黒川顕
kn-aut-sei=黒川
kn-aut-mei=顕
aut-affil-num=3
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=中山恵介
kn-aut-sei=中山
kn-aut-mei=恵介
aut-affil-num=4
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島健志郎
kn-aut-sei=大島
kn-aut-mei=健志郎
aut-affil-num=5
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=藤永由佳子
kn-aut-sei=藤永
kn-aut-mei=由佳子
aut-affil-num=6
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大西真
kn-aut-sei=大西
kn-aut-mei=真
aut-affil-num=7
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大坪栄一
kn-aut-sei=大坪
kn-aut-mei=栄一
aut-affil-num=8
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=服部正平
kn-aut-sei=服部
kn-aut-mei=正平
aut-affil-num=9
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=小熊惠二
kn-aut-sei=小熊
kn-aut-mei=惠二
aut-affil-num=10
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 病原細菌学
affil-num=2
en-affil=
kn-affil=宮崎大学フロンティア科学実験総合センター 生命科学研究部門生命環境科学分野
affil-num=3
en-affil=
kn-affil=奈良先端科学技術大学院大学情報科学研究科 比較ゲノム
affil-num=4
en-affil=
kn-affil=宮崎大学医学部医学科 感染症学
affil-num=5
en-affil=
kn-affil=北里大学生命科学研究所
affil-num=6
en-affil=
kn-affil=大阪大学微生物病研究所附属感染症国際研究センター
affil-num=7
en-affil=
kn-affil=国立感染症研究所 細菌第一部
affil-num=8
en-affil=
kn-affil=東京大学分子細胞生物学研究所 分子情報・制御
affil-num=9
en-affil=
kn-affil=北里大学生命科学研究所
affil-num=10
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 病原細菌学
en-keyword=バクテリオファージ
kn-keyword=バクテリオファージ
en-keyword=ボツリヌス毒素
kn-keyword=ボツリヌス毒素
en-keyword=挿入配列
kn-keyword=挿入配列
en-keyword=プラスミド
kn-keyword=プラスミド
en-keyword=プロファージ
kn-keyword=プロファージ
END
start-ver=1.4
cd-journal=joma
no-vol=119
cd-vols=
no-issue=1
article-no=
start-page=17
end-page=20
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20070501
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Molecular mechanism on Cdk5-dependent insulin secretion
kn-title=Cdk5によるインスリン分泌の制御機構
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=魏范研
kn-aut-sei=魏
kn-aut-mei=范研
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=長嶋一昭
kn-aut-sei=長嶋
kn-aut-mei=一昭
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島登志男
kn-aut-sei=大島
kn-aut-mei=登志男
aut-affil-num=3
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=佐伯恭範
kn-aut-sei=佐伯
kn-aut-mei=恭範
aut-affil-num=4
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=陸雲飛
kn-aut-sei=陸
kn-aut-mei=雲飛
aut-affil-num=5
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=松下正之
kn-aut-sei=松下
kn-aut-mei=正之
aut-affil-num=6
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=山田祐一郎
kn-aut-sei=山田
kn-aut-mei=祐一郎
aut-affil-num=7
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=御子柴克彦
kn-aut-sei=御子柴
kn-aut-mei=克彦
aut-affil-num=8
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=清野裕
kn-aut-sei=清野
kn-aut-mei=裕
aut-affil-num=9
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=松井秀樹
kn-aut-sei=松井
kn-aut-mei=秀樹
aut-affil-num=10
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=富澤一仁
kn-aut-sei=富澤
kn-aut-mei=一仁
aut-affil-num=11
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 細胞生理学
affil-num=2
en-affil=
kn-affil=京都大学大学院医学研究科 糖尿病栄養内科
affil-num=3
en-affil=
kn-affil=理化学研究所 発生神経生物研究チーム
affil-num=4
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 細胞生理学
affil-num=5
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 細胞生理学
affil-num=6
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 細胞生理学
affil-num=7
en-affil=
kn-affil=京都大学大学院医学研究科 糖尿病栄養内科
affil-num=8
en-affil=
kn-affil=理化学研究所 発生神経生物研究チーム
affil-num=9
en-affil=
kn-affil=京都大学大学院医学研究科 糖尿病栄養内科
affil-num=10
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 細胞生理学
affil-num=11
en-affil=
kn-affil=岡山大学大学院医歯薬学総合研究科 細胞生理学
en-keyword=Insulin
kn-keyword=Insulin
en-keyword=Cdk5
kn-keyword=Cdk5
en-keyword=Calcium
kn-keyword=Calcium
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2006
dt-pub=20060324
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Celsiorは犬心臓において一般的心筋保護液よりも心臓力学的エネルギー学的心筋保護効果が優れている
kn-title=Celsior Preserved Cardiac Mechanoenergetics Better than Popular Solutions in Canine Hearts
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=OshimaYu
en-aut-sei=Oshima
en-aut-mei=Yu
kn-aut-name=大島祐
kn-aut-sei=大島
kn-aut-mei=祐
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1968
dt-pub=19680331
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=悪性腫瘍における乳酸脱水素酵素とそのIsozymeに関する研究
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島由紀子
kn-aut-sei=大島
kn-aut-mei=由紀子
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1971
dt-pub=19711231
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=本邦人胎児聴器骨化過程の超軟X線およびAlizarin red骨染色による観察
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島昭夫
kn-aut-sei=大島
kn-aut-mei=昭夫
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1983
dt-pub=19830331
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=脈絡膜における神経分布に関する研究 第1報 モノアミン作動性神経の蛍光顕微鏡による観察 第2報 ノルアドレナリン神経終末の分布密度の検討
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島浩一
kn-aut-sei=大島
kn-aut-mei=浩一
aut-affil-num=1
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=10
cd-vols=
no-issue=
article-no=
start-page=12
end-page=20
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1987
dt-pub=19871228
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=切花数の時期的変動からみたカーネーション品種の特性
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=安井公一
kn-aut-sei=安井
kn-aut-mei=公一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=土居川俊二
kn-aut-sei=土居川
kn-aut-mei=俊二
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島昭夫
kn-aut-sei=大島
kn-aut-mei=昭夫
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=9
cd-vols=
no-issue=
article-no=
start-page=15
end-page=19
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1986
dt-pub=19860801
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=STS処理がキク切花の貯蔵寿命に及ぼす影響
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=安井公一
kn-aut-sei=安井
kn-aut-mei=公一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島昭夫
kn-aut-sei=大島
kn-aut-mei=昭夫
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=松浦次郎
kn-aut-sei=松浦
kn-aut-mei=次郎
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=8
cd-vols=
no-issue=
article-no=
start-page=20
end-page=23
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1985
dt-pub=19850627
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=電照ギク栽培における摘心後の栄養 生長期間と切花長
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=安井公一
kn-aut-sei=安井
kn-aut-mei=公一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島昭夫
kn-aut-sei=大島
kn-aut-mei=昭夫
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=松浦次郎
kn-aut-sei=松浦
kn-aut-mei=次郎
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=7
cd-vols=
no-issue=
article-no=
start-page=27
end-page=30
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1984
dt-pub=19840702
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=弱毒ウイルス接種によるトマトのモザイク病防除試験
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=安井公一
kn-aut-sei=安井
kn-aut-mei=公一
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島昭夫
kn-aut-sei=大島
kn-aut-mei=昭夫
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=松浦次郎
kn-aut-sei=松浦
kn-aut-mei=次郎
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=5
cd-vols=
no-issue=
article-no=
start-page=22
end-page=27
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1983
dt-pub=19830312
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=本学付属農場における露地栽培トマトの適正施肥量
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島昭夫
kn-aut-sei=大島
kn-aut-mei=昭夫
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=松浦次郎
kn-aut-sei=松浦
kn-aut-mei=次郎
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=安井公一
kn-aut-sei=安井
kn-aut-mei=公一
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=4
cd-vols=
no-issue=
article-no=
start-page=43
end-page=47
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1982
dt-pub=19820227
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=トマト栽培における基肥・追肥割合と収量構成
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島昭夫
kn-aut-sei=大島
kn-aut-mei=昭夫
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=松浦次郎
kn-aut-sei=松浦
kn-aut-mei=次郎
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=安井公一
kn-aut-sei=安井
kn-aut-mei=公一
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=3
cd-vols=
no-issue=
article-no=
start-page=23
end-page=28
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1980
dt-pub=19801220
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=ナス果実の収穫時期と総収量・し好性
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島昭夫
kn-aut-sei=大島
kn-aut-mei=昭夫
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=藤原稔司
kn-aut-sei=藤原
kn-aut-mei=稔司
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=安井公一
kn-aut-sei=安井
kn-aut-mei=公一
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=2
cd-vols=
no-issue=
article-no=
start-page=29
end-page=32
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1979
dt-pub=197912
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=カボチャの生育に対するケイ酸の影響
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=カボチャの生育および病害抑制に対するケイ酸質肥料の影響について検討し、次の結果を得た。1) ケイ酸質肥料の施肥は、カボチャの茎葉重を増加したが、カボチャの収量に対する効果は認められなかった。そしてウドンコ病に対するケイ酸の抑制効果も認められなかった。2) この栽培試験においてケイ酸質肥料添加の効果が認められなかった原因は、土壌中における添加可給態ケイ酸の形態変化によるものと推定された。
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=三宅靖人
kn-aut-sei=三宅
kn-aut-mei=靖人
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=景山詳弘
kn-aut-sei=景山
kn-aut-mei=詳弘
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=宗友義美
kn-aut-sei=宗友
kn-aut-mei=義美
aut-affil-num=3
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=松浦次郎
kn-aut-sei=松浦
kn-aut-mei=次郎
aut-affil-num=4
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島昭夫
kn-aut-sei=大島
kn-aut-mei=昭夫
aut-affil-num=5
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
affil-num=4
en-affil=
kn-affil=岡山大学
affil-num=5
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=2
cd-vols=
no-issue=
article-no=
start-page=25
end-page=28
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1979
dt-pub=197912
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=水耕トマトの密植低段栽培における品種比較試験
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=景山詳弘
kn-aut-sei=景山
kn-aut-mei=詳弘
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島昭夫
kn-aut-sei=大島
kn-aut-mei=昭夫
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=斉藤克己
kn-aut-sei=斉藤
kn-aut-mei=克己
aut-affil-num=3
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=藤原稔司
kn-aut-sei=藤原
kn-aut-mei=稔司
aut-affil-num=4
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
affil-num=4
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=1
cd-vols=
no-issue=
article-no=
start-page=4
end-page=6
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1978
dt-pub=197812
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=水耕トマトの密植低段栽培における栽植密度
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=景山詳弘
kn-aut-sei=景山
kn-aut-mei=詳弘
aut-affil-num=1
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=大島昭夫
kn-aut-sei=大島
kn-aut-mei=昭夫
aut-affil-num=2
ORCID=
en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=松浦次郎
kn-aut-sei=松浦
kn-aut-mei=次郎
aut-affil-num=3
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
affil-num=3
en-affil=
kn-affil=岡山大学
END
start-ver=1.4
cd-journal=joma
no-vol=43
cd-vols=
no-issue=1
article-no=
start-page=1
end-page=9
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=1974
dt-pub=1974
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=Studies on the Ecology on Insects Sterilized Artifically(Gamma Radiation) : VII.Influence of Gamma Rays Radiation from 137Cs on the Oriental Fruit Fly in Amami-Oshima Island
kn-title=人工不妊昆虫の生態に関する研究 VII.奄美大島のミカンコミバエに及ぼす137Csガンマー線の影響
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=奄美大島産ミカンコミバエ蛹を岡山で羽化させ,トウモロコシ粉を主体とする半合成飼料を用いて飼育し,蛹化2日前の蛹へ137Csガンマー線を4,6,8KR照射して各種の実験を行なった. (1)4,6,8KRを照射した蛹は,正常のものと大差なく高い羽化率を示し,奇型の出現も少ない. (2)羽化2日前の蛹へ8KRを照射すると雄・雌成虫とも完全不妊となる. しかし,それらは正常雄・雌より生存日数がやや短かい傾向を示す. (3)10個の正常雌に対して正常雄10個とその20倍の8KR不妊化雄200個を組み合わせるとほとんど完全な不妊効果が示される. 15倍の150個以下では若干の孵化幼虫が発育して次代の成虫となる. (4)上記雄・雌成虫は正常の雌・雄と組み合わされたとき,比較的高い不妊を示す. (5)生存日数がやや短かいという欠点を補正するために,6KR不妊化雄をつくると,もちろん完全不妊ではない. また次代に発育ができた成虫も不妊性があまり期待できない. しかし6KR不妊化雄を正常雄の20倍,すなわち200個以上組み入れると比較的に高い不妊が得られる. (6)我が国における他の研究と比較して,X線,60Coおよび137Csガンマー線は実用的には大体おなじ線盤8KRでミカンコミバエを完全不妊にできることがわかった. (7)なお解剖観察によって8KR不妊化雄の不妊原因は精巣そのもの,精子の雌への移動,精子の活動力などの異常によるよりも優性致死変異に起因するものと推察された。
en-copyright=
kn-copyright=
en-aut-name=KiyokuMasao
en-aut-sei=Kiyoku
en-aut-mei=Masao
kn-aut-name=清久正夫
kn-aut-sei=清久
kn-aut-mei=正夫
aut-affil-num=1
ORCID=
en-aut-name=TsukudaRitsuko
en-aut-sei=Tsukuda
en-aut-mei=Ritsuko
kn-aut-name=佃律子
kn-aut-sei=佃
kn-aut-mei=律子
aut-affil-num=2
ORCID=
affil-num=1
en-affil=
kn-affil=岡山大学
affil-num=2
en-affil=
kn-affil=岡山大学
END