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ID 46985
フルテキストURL
著者
Kuninobu, Yoichiro Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
Nakahara, Takahiro Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
Yu, Peng Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
Takai, Kazuhiko Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
抄録
Treatment of aromatic aldimines with terminal alkenes in the presence of a rhenium catalyst, [HRe(CO)(4)](n), gives 2-alkenylbenzylamines in good to excellent yields. This reaction proceeds via the insertion of the alkene into a C-H bond at the ortho-position of the imino group of the aromatic aldimine followed by sequential beta-hydride elimination from the formed alkyl rhenium intermediate and then by hydrogenation of the imino group of the aldimine.
キーワード
Rhenium
Insertion
Hydrogen transfer
Aldimine
Alkene
発行日
2011-01-01
出版物タイトル
Journal of Organometallic Chemistry
696巻
1号
出版者
Elsevier Science SA.
開始ページ
348
終了ページ
351
ISSN
0022-328X
NCID
AA00704122
資料タイプ
学術雑誌論文
言語
English
OAI-PMH Set
岡山大学
著作権者
© 2011 Elsevier B.V. All rights reserved.
論文のバージョン
author
査読
有り
DOI
Web of Sience KeyUT