| ID | 57490 |
| フルテキストURL | |
| 著者 |
Iwasaki, Masayuki
Research Institute for Interdisciplinary Science, Okayama University
ORCID
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Xu, Jie
Graduate School of Natural Science and Technology, Okayama University
Tani, Yukari
Graduate School of Natural Science and Technology, Okayama University
Fu, Liyan
Graduate School of Natural Science and Technology, Okayama University
Ikemoto, Yuichi
Graduate School of Natural Science and Technology, Okayama University
Ura, Yasuyuki
Department of Chemistry, Biology, and Environmental Science, Faculty of Science, Nara Women’s University
Nishihara, Yasushi
Research Institute for Interdisciplinary Science, Okayama University
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| 抄録 | A copper-catalyzed chloroamination of alkenes with chlorotrimethylsilane and N-fluorobenzenesulfonimide has been developed. The reactions were complete within 1 h at 120 degrees C by means of microwave heating. The present chloroamination proceeds with a perfect regioselectivity and is compatible with various functional groups. The preliminary mechanistic investigation revealed that the reaction involves a radical process. The utility of the present method was demonstrated by scalable, operationally simple and safe system.
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| キーワード | Chloroamination
Copper catalyst
Alkenes
|
| 発行日 | 2019-01-10
|
| 出版物タイトル |
Chemistry Letters
|
| 巻 | 48巻
|
| 号 | 3号
|
| 出版者 | Chemical Society of Japan
|
| 開始ページ | 281
|
| 終了ページ | 283
|
| ISSN | 03667022
|
| NCID | AA00603318
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| 資料タイプ |
学術雑誌論文
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| 言語 |
英語
|
| OAI-PMH Set |
岡山大学
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| 論文のバージョン | author
|
| DOI | |
| Web of Science KeyUT | |
| 関連URL | isVersionOf https://doi.org/10.1246/cl.180937
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| 助成機関名 |
日本学術振興会
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| 助成番号 | 16K17901
|
