ID | 58755 |
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著者 |
Fu, Liyan
Graduate School of Natural Science and Technology, Okayama University
Chen, Qiang
Graduate School of Natural Science and Technology, Okayama University
Wang, Zhenhua
Graduate School of Natural Science and Technology, Okayama University
Nishihara, Yasushi
Research Institute for Interdisciplinary Science, Okayama University
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抄録 | Palladium-catalyzed decarbonylative alkylation reactions of acyl fluorides have been developed using alkylboranes having β-hydrogens. A wide range of functional groups were well tolerated, even at the high temperature required for decarbonylation. This protocol provides a diverse C(sp2)–C(sp3) bond formation via a highly efficient decarbonylative process. The hemilabile bidentate ligand DPPE plays a crucial role for retardation of the undesired β-hydride elimination.
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備考 | This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Organic Letters, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.0c00542.
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発行日 | 2020-05-05
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出版物タイトル |
Organic Letters
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巻 | 22巻
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号 | 6号
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出版者 | American Chemical Society
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開始ページ | 2350
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終了ページ | 2353
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ISSN | 15237060
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NCID | AA11347843
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資料タイプ |
学術雑誌論文
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言語 |
英語
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論文のバージョン | author
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関連URL | isVersionOf https://doi.org/10.1021/acs.orglett.0c00542
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