ID | 55378 |
フルテキストURL | |
著者 |
Murai, Masahito
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
ORCID
Kaken ID
publons
researchmap
Okada, Ryo
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Nishiyama, Atsushi
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Takai, Kazuhiko
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
ORCID
Kaken ID
publons
researchmap
|
抄録 | Use of a rhodium catalyst with (R)-(S)-BPPFA ligand allows efficient synthesis of sila[n]helicenes via dehydrogenative silylation of C-H bonds. By selecting the proper ligands, the current method provides the ability to prepare unsymmetrical sila[n]helicene derivatives without any oxidants. The resulting sila[6]helicene is a rare example of a five-membered ring-fused [6]helicene, which was isolated as a single pure enantiomer without substituents on the terminal benzene rings.
|
備考 | This is an Accepted Manuscript of an article published by American Chemical Society
|
発行日 | 2016-08-11
|
出版物タイトル |
Organic Letters
|
巻 | 18巻
|
号 | 17号
|
出版者 | American Chemical Society
|
開始ページ | 4380
|
終了ページ | 4383
|
ISSN | 1523-7060
|
NCID | AA11347843
|
資料タイプ |
学術雑誌論文
|
言語 |
英語
|
OAI-PMH Set |
岡山大学
|
論文のバージョン | author
|
PubMed ID | |
DOI | |
Web of Science KeyUT | |
関連URL | isVersionOf https://doi.org/10.1021/acs.orglett.6b02134
|
ライセンス | https://creativecommons.org/licenses/by-nc-nd/4.0/deed.ja
|
助成機関名 |
日本学術振興会
|
助成番号 | 26870389
|