start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20070324
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=タンタル上のアルキン配位子交換反応の機構研究
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=研究内容
シリルアルキン錯体の合成とその反応性。
アルキン交換反応の速度式と活性化パラメータの算出。
アルキン交換反応の新規錯体合成への応用。
en-copyright=
kn-copyright=

en-aut-name=OshikiToshiyuki
en-aut-sei=Oshiki
en-aut-mei=Toshiyuki
kn-aut-name=押木俊之
kn-aut-sei=押木
kn-aut-mei=俊之
aut-affil-num=1
ORCID=

affil-num=1
en-affil=
kn-affil=岡山大学
en-keyword=アルキン交換反応
kn-keyword=アルキン交換反応
en-keyword=タンタル
kn-keyword=タンタル
en-keyword=シリルアルキン錯体
kn-keyword=シリルアルキン錯体
END

start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20070605
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=錯体触媒による革新的化学品製造技術の開発
en-subtitle=
kn-subtitle=
en-abstract=本研究は、新エネルギー・産業技術総合開発機構平成18 年度産業技術研究助成事業「水－有機多相系を制御する新規錯体触媒プロセスによるシンプル水和反応の開発」として平成20 年3 月まで総額2873 万円の助成を受けて実施中です。
kn-abstract=水和反応は原理的に副生成物が出ないため、本質的に環境への負荷が少ない反応です。この反応に適用できる高活性触媒を開発し、しかも溶媒なしでアミド製造が実現できたことは大きなイノベーションです。さらに、これを出発点として、他の化学品を省エネルギー型水和反応により製造する技術開発を民間企業との連携により現在進めています。岡山大学では、このような自然と人間の共生を目指した研究を通じて、我が国の産業技術開発を担う人材育成に取り組んでいます。
en-copyright=
kn-copyright=

en-aut-name=OshikiToshiyuki
en-aut-sei=Oshiki
en-aut-mei=Toshiyuki
kn-aut-name=押木俊之
kn-aut-sei=押木
kn-aut-mei=俊之
aut-affil-num=1
ORCID=

en-aut-name=IshidukaAkinori
en-aut-sei=Ishiduka
en-aut-mei=Akinori
kn-aut-name=石塚章斤
kn-aut-sei=石塚
kn-aut-mei=章斤
aut-affil-num=2
ORCID=

affil-num=1
en-affil=
kn-affil=岡山大学

affil-num=2
en-affil=
kn-affil=岡山大学
en-keyword=錯体触媒
kn-keyword=錯体触媒
en-keyword=水和反応
kn-keyword=水和反応
en-keyword=ビタミンB3
kn-keyword=ビタミンB3
en-keyword=アミド類
kn-keyword=アミド類
END

start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2007
dt-pub=20070912
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=水-有機多相系を制御する新規錯体触媒プロセスによるシンプル水和
反応の開発
en-subtitle=
kn-subtitle=
en-abstract=新エネルギー・産業技術総合開発機構平成18年度 第2回産業技術研究助成事業
kn-abstract=極性官能基をもつニトリルやエステルを錯体触媒により水和（加水分解）し、工業的に重要なアミドや脂肪酸を得るための究極のシンプルな新規製造プロセスの開発が目的です。その実現のためには、水と油（有機化合物）の多相系を「科学的」及び「工学的」に制御することが必要です。本研究では、新たに開発する多相系制御技術を協奏的に活用し、化学産業で強く求められている環境調和の省エネルギー型水和プロセスの完成を目指します。
en-copyright=
kn-copyright=

en-aut-name=OshikiToshiyuki
en-aut-sei=Oshiki
en-aut-mei=Toshiyuki
kn-aut-name=押木俊之
kn-aut-sei=押木
kn-aut-mei=俊之
aut-affil-num=1
ORCID=

affil-num=1
en-affil=
kn-affil=岡山大学
en-keyword=有機多相系の制御
kn-keyword=有機多相系の制御
en-keyword=2元機能型錯体触媒
kn-keyword=2元機能型錯体触媒
en-keyword=新規性・優位性
kn-keyword=新規性・優位性
END

start-ver=1.4
cd-journal=joma
no-vol=58
cd-vols=
no-issue=2
article-no=
start-page=50
end-page=55
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2011
dt-pub=201102
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=問われる産と学の決断と勇気
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=

en-aut-name=OshikiToshiyuki
en-aut-sei=Oshiki
en-aut-mei=Toshiyuki
kn-aut-name=押木俊之
kn-aut-sei=押木
kn-aut-mei=俊之
aut-affil-num=1
ORCID=

affil-num=1
en-affil=
kn-affil=岡山大学大学院自然科学研究科機能分子化学専攻
END

start-ver=1.4
cd-journal=joma
no-vol=164
cd-vols=
no-issue=1
article-no=
start-page=552
end-page=555
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2011
dt-pub=20110430
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=2-Diphenylphosphanyl-4-pyridyl(dimethyl) amine as an effective ligand for the ruthenium(II) complex catalyzed homogeneous hydration of nitriles under neutral conditions
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=New homogeneous catalyst comprised of [Ru(methallyl)(2)(cod)] (cod = 1,5-cyclooctadiene) (1) and 2-diphenylphosphanyl-4-pyridyl(dimethyl) amine (2) is shown to efficiently catalyze the hydration of various nitriles under neutral conditions. The hydration proceeds in the presence of 0.5 mol% of the ruthenium catalyst at 80 degrees C in 1,2-dimethoxyethane solution and the corresponding amide is obtained within few hours without the formation of by products. Comparison of some phosphine ligands for the hydration reveals that the dimethylamino moiety of 2 improves the catalytic performance dramatically.
en-copyright=
kn-copyright=

en-aut-name=MuranakaMakoto
en-aut-sei=Muranaka
en-aut-mei=Makoto
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=

en-aut-name=HyodoIsao
en-aut-sei=Hyodo
en-aut-mei=Isao
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=

en-aut-name=OkumuraWataru
en-aut-sei=Okumura
en-aut-mei=Wataru
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=

en-aut-name=OshikiToshiyuki
en-aut-sei=Oshiki
en-aut-mei=Toshiyuki
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=4
ORCID=

affil-num=1
en-affil=
kn-affil=Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University

affil-num=2
en-affil=
kn-affil=Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University

affil-num=3
en-affil=
kn-affil=Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University

affil-num=4
en-affil=
kn-affil=Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
en-keyword=Hydration
kn-keyword=Hydration
en-keyword=Nitrile
kn-keyword=Nitrile
en-keyword=Amides
kn-keyword=Amides
en-keyword=Homogeneous catalysis
kn-keyword=Homogeneous catalysis
en-keyword=Ruthenium
kn-keyword=Ruthenium
en-keyword=Phosphine
kn-keyword=Phosphine
END

start-ver=1.4
cd-journal=joma
no-vol=74
cd-vols=
no-issue=4
article-no=
start-page=327
end-page=334
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2020
dt-pub=202008
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Cytotoxic Effects of Alcohol Extracts from a Plastic Wrap (Polyvinylidene Chloride) on Human Cultured Liver Cells and Mouse Primary Cultured Liver Cells
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=An increasing accumulation of microplastics and further degraded nanoplastics in our environment is suspected to have harmful effects on humans and animals. To clarify this problem, we tested the cytotoxicity of two types of plastic wrap on human cultured liver cells and mouse primary cultured liver cells. Alcohol extracts from plastic wrap, i.e., polyvinylidene chloride (PVDC), showed cytotoxic effects on the cells. Alcohol extracts of polyethylene (PE) wrap were not toxic. The commercially available PVDC wrap consists of vinylidene chloride, epoxidized soybean oil, epoxidized linseed oil as a stiffener and stabilizer; we sought to identify which component(s) are toxic. The epoxidized soybean oil and epoxidized linseed oil exerted strong cytotoxicity, but the plastic raw material itself, vinylidene chloride, did not. Our findings indicate that plastic wraps should be used with caution in order to prevent health risks.
en-copyright=
kn-copyright=

en-aut-name=YamamotoKen-ichi
en-aut-sei=Yamamoto
en-aut-mei=Ken-ichi
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=

en-aut-name=KagawaHiroko
en-aut-sei=Kagawa
en-aut-mei=Hiroko
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=

en-aut-name=ArimotoSakae
en-aut-sei=Arimoto
en-aut-mei=Sakae
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=

en-aut-name=TanXian Wen
en-aut-sei=Tan
en-aut-mei=Xian Wen
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=4
ORCID=

en-aut-name=YasuiKento
en-aut-sei=Yasui
en-aut-mei=Kento
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=5
ORCID=

en-aut-name=OshikiToshiyuki
en-aut-sei=Oshiki
en-aut-mei=Toshiyuki
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=6
ORCID=

en-aut-name=SakaguchiMasakiyo
en-aut-sei=Sakaguchi
en-aut-mei=Masakiyo
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=7
ORCID=

affil-num=1
en-affil=Department of Cell Biology, Okayama University Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
kn-affil=

affil-num=2
en-affil=Okayama University Hospital
kn-affil=

affil-num=3
en-affil=Division of Pharmaceutical Sciences, Okayama University Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
kn-affil=

affil-num=4
en-affil=Department of Cell Chemistry, Okayama University Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
kn-affil=

affil-num=5
en-affil=Department of Cell Biology, Okayama University Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
kn-affil=

affil-num=6
en-affil=Department of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
kn-affil=

affil-num=7
en-affil=Department of Cell Biology, Okayama University Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
kn-affil=
en-keyword=plastic wrap
kn-keyword=plastic wrap
en-keyword=plasticizer,
kn-keyword=plasticizer,
en-keyword=cytotoxicity,
kn-keyword=cytotoxicity,
en-keyword=liver cells
kn-keyword=liver cells
en-keyword=in vitro
kn-keyword=in vitro
END

start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=
dt-pub=
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=有機エレクトロニクス材料の中規模製造工程の開発
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=

en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=押木俊之
kn-aut-sei=押木
kn-aut-mei=俊之
aut-affil-num=1
ORCID=

affil-num=1
en-affil=
kn-affil=岡山大学大学院自然科学研究科機能分子化学専攻
END

start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
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end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=
dt-pub=
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=高濃度ギ酸から水素を製造する化学触媒法
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=

en-aut-name=OshikiToshiyuki
en-aut-sei=Oshiki
en-aut-mei=Toshiyuki
kn-aut-name=押木俊之
kn-aut-sei=押木
kn-aut-mei=俊之
aut-affil-num=1
ORCID=

affil-num=1
en-affil=
kn-affil=岡山大学大学院自然科学研究科機能分子化学専攻
END

start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=
dt-pub=
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Toward Industrial Applications of Homogeneous Catalysts
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=

en-aut-name=OshikiToshiyuki
en-aut-sei=Oshiki
en-aut-mei=Toshiyuki
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=

affil-num=1
en-affil=
kn-affil=Okayama University, Collaborative Research Center
END

start-ver=1.4
cd-journal=joma
no-vol=
cd-vols=
no-issue=
article-no=
start-page=
end-page=
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=
dt-pub=
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=地域の産学連携による省エネ型次世代触媒技術の開発
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=
en-copyright=
kn-copyright=

en-aut-name=
en-aut-sei=
en-aut-mei=
kn-aut-name=押木俊之
kn-aut-sei=押木
kn-aut-mei=俊之
aut-affil-num=1
ORCID=

affil-num=1
en-affil=
kn-affil=岡山大学大学院自然科学研究科（工学系）
END