ID | 11538 |
JaLCDOI | |
Sort Key | 13
|
タイトル(別表記) | Effects of ultrasonic treatment on the preparation of transparent glass-ceramic phosphor
|
フルテキストURL | |
著者 |
井上 輝英
岡山大学
中島 瑞穂
岡山大学
三浦 嘉也
岡山大学
|
抄録 | The effects of ultrasonic surface treatment (UST) on the crystallization behavior and optical emission properties were investigated for the transparent glass-ceramics prepared from calcium aluminosilicate glasses co-doped with Eu(2+), Nd(3+). The glass-ceramics A were prepared by sintering a glass 45CaO・45Al(2)O(3)・10SiO(2) (mol%) containing 0.5Eu(2)O(3)+1Nd(2)O(3) under a 2% H(2)+98% Ar reducing atmosphere. In the glass-ceramics A, three crystalline phases, CaAl(2)O(4) (CA), CaAl(4)O(7) (CA2) and Ca(2)Al(2)SiO(7) (CAS) were commonly confirmed by X-ray diffraction. No drastic change in the amount of the precipitated crystalline phases was observed even in the case using UST of CA powders. It was suggested that the optical emission properties of the glass-ceramics A was responsible for the CA2 crystals. The glass-ceramics B were also prepared from a 51CaO・42Al(2)O(3)・7SiO(2) glass. The CA crystals were separately precipitated in the glass-ceramics B. In particular, a large amount of CA was successfully produced by stirring the UST suspension to prevent the sedimentation of the UST particles. The glass-ceramic B so-prepared showed strong photoluminescence but weak phosphorescence compared with other glass-ceramics B, indicating that the photoluminescence and phosphorescence were originated in different electron-trapping levels. The amount of the trap levels associated with the long lasting phosphorescence, such as oxygen vacancies, was probably small in the glass-ceramic B prepared with the stirring UST.
|
キーワード | ultrasonic surface treatment (UST)
surface crystallization
glass-ceramics
long lasting phosphorescence
calcium aluminosilicate glass
|
出版物タイトル |
岡山大学環境理工学部研究報告
|
発行日 | 2002-03-22
|
巻 | 7巻
|
号 | 1号
|
出版者 | 岡山大学環境理工学部
|
出版者(別表記) | Faculty of Environmental Science and Technology, Okayama University
|
開始ページ | 113
|
終了ページ | 118
|
ISSN | 1341-9099
|
NCID | AN10529213
|
資料タイプ |
紀要論文
|
OAI-PMH Set |
岡山大学
|
言語 |
日本語
|
論文のバージョン | publisher
|
NAID | |
Eprints Journal Name | fest
|