ID | 66576 |
フルテキストURL | |
著者 |
Sato, Eisuke
Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
Ogita, Sayaka
Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
Mitsudo, Koichi
Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
ORCID
Kaken ID
publons
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Suga, Seiji
Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
ORCID
Kaken ID
researchmap
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抄録 | Cathodic reduction efficiently cleaved N-O bonds. The simple cathodic reduction of Weinreb amides in a divided cell afforded the corresponding amide in good yields. Cyclic voltammetry experiments and density functional theory calculations suggested that the direct reduction of the N-methoxy amide generates the methoxy radical and amide anion. The release of methanol derived from methoxy radical would be the driving force of the N-O bond cleavage.
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キーワード | N-Alkoxy Amide
Cathodic Reduction
Weinreb Amide
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発行日 | 2023-11-28
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出版物タイトル |
Electrochemistry
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巻 | 91巻
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号 | 11号
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出版者 | Electrochemical Society of Japan
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開始ページ | 112005
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ISSN | 1344-3542
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資料タイプ |
学術雑誌論文
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言語 |
英語
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OAI-PMH Set |
岡山大学
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著作権者 | © The Author(s) 2023.
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論文のバージョン | publisher
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DOI | |
Web of Science KeyUT | |
関連URL | isVersionOf https://doi.org/10.5796/electrochemistry.23-67079
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ライセンス | http://creativecommons.org/licenses/by/4.0/
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助成機関名 |
Japan Society for the Promotion of Science
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助成番号 | JP23K13748
JP22H02122
JP22K05115
JP21H05214
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