start-ver=1.4
cd-journal=joma
no-vol=8
cd-vols=
no-issue=6
article-no=
start-page=5454
end-page=5459
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2018
dt-pub=20180504
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Amine-Promoted anti-Markovnikov Addition of 1,3-Dicarbonyl Compounds with Terminal Alkynes under Rhenium Catalysis
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=Amines have been identified to greatly accelerate the intermolecular anti-Markovnikov addition of carbon nucleophiles to unactivated terminal alkynes. Using a combination of [ReBr(CO)3(thf)]2 and iPr2NEt, construction of cyclic all-carbon quaternary centers was achieved with various 1,3-ketoesters, diketones, and diesters with lower catalyst loading under milder conditions. The type of addition could be easily controlled by choice of additive, highlighting the unique features of rhenium catalysis
en-copyright=
kn-copyright=

en-aut-name=MuraiMasahito
en-aut-sei=Murai
en-aut-mei=Masahito
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=

en-aut-name=UemuraErika
en-aut-sei=Uemura
en-aut-mei=Erika
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=

en-aut-name=TakaiKazuhiko
en-aut-sei=Takai
en-aut-mei=Kazuhiko
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=3
ORCID=

affil-num=1
en-affil=Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
kn-affil=

affil-num=2
en-affil=Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
kn-affil=

affil-num=3
en-affil=Division of Applied Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
kn-affil=
en-keyword=rhenium
kn-keyword=rhenium
en-keyword=anti-Markovnikov addition
kn-keyword=anti-Markovnikov addition
en-keyword=1,3-dicarbonyl compound
kn-keyword=1,3-dicarbonyl compound
en-keyword=vinylidene
kn-keyword=vinylidene
en-keyword=amine
kn-keyword=amine
END