JaLCDOI 10.18926/fest/11617
タイトル(別表記) Synthesis of Polythiophen Cluster in Lattice Space of Hexagonal Faujasite
フルテキストURL 002_137_143.pdf
著者 三宅 通博| 松田 元秀| 八木 克仁| 上原 啓史| 佐藤 満雄|
抄録 Encapsulation of thiophen and bithiophen in two kinds of hexagonal faujasites (Na-EMT and H-EMT) with various concentration of Cu(2+) ions have been investigated and characterized by means of themoanalytic and spectroscopic methods. From the results, it was found that the progress of polymerization of thiophen and bithiophen in the lattice space depended on Cu(2+) contents, and the encapsulation of thiophen in Na-EMT and H-EMT with Cu(2+) ions yielded polythiophen clusters with electron states of bipolaron. On the other hand, polythiophen clusters synthesized by the encapsulation of bithiophen in H-EMT were found to be mostly polaron states.
キーワード encapsulation cluster host-guest reaction hexagonal faujasite polythiophen
出版物タイトル 岡山大学環境理工学部研究報告
発行日 1997-01-10
開始ページ 137
終了ページ 143
ISSN 1341-9099
言語 Japanese
論文のバージョン publisher
NAID 120002313756