このエントリーをはてなブックマークに追加
ID 11538
Eprint ID
11538
フルテキストURL
タイトル(別表記)
Effects of ultrasonic treatment on the preparation of transparent glass-ceramic phosphor
著者
井上 輝英 岡山大学
中島 瑞穂 岡山大学
難波 徳郎 岡山大学
三浦 嘉也 岡山大学
抄録
The effects of ultrasonic surface treatment (UST) on the crystallization behavior and optical emission properties were investigated for the transparent glass-ceramics prepared from calcium aluminosilicate glasses co-doped with Eu(2+), Nd(3+). The glass-ceramics A were prepared by sintering a glass 45CaO・45Al(2)O(3)・10SiO(2) (mol%) containing 0.5Eu(2)O(3)+1Nd(2)O(3) under a 2% H(2)+98% Ar reducing atmosphere. In the glass-ceramics A, three crystalline phases, CaAl(2)O(4) (CA), CaAl(4)O(7) (CA2) and Ca(2)Al(2)SiO(7) (CAS) were commonly confirmed by X-ray diffraction. No drastic change in the amount of the precipitated crystalline phases was observed even in the case using UST of CA powders. It was suggested that the optical emission properties of the glass-ceramics A was responsible for the CA2 crystals. The glass-ceramics B were also prepared from a 51CaO・42Al(2)O(3)・7SiO(2) glass. The CA crystals were separately precipitated in the glass-ceramics B. In particular, a large amount of CA was successfully produced by stirring the UST suspension to prevent the sedimentation of the UST particles. The glass-ceramic B so-prepared showed strong photoluminescence but weak phosphorescence compared with other glass-ceramics B, indicating that the photoluminescence and phosphorescence were originated in different electron-trapping levels. The amount of the trap levels associated with the long lasting phosphorescence, such as oxygen vacancies, was probably small in the glass-ceramic B prepared with the stirring UST.
キーワード
ultrasonic surface treatment (UST)
surface crystallization
glass-ceramics
long lasting phosphorescence
calcium aluminosilicate glass
発行日
2002-03-22
出版物タイトル
岡山大学環境理工学部研究報告
出版物タイトル(別表記)
Journal of the Faculty of Environmental Science and Technology, Okayama University
7巻
1号
出版者
岡山大学環境理工学部
出版者(別表記)
Faculty of Environmental Science and Technology, Okayama University
開始ページ
113
終了ページ
118
ISSN
1341-9099
NCID
AN10529213
資料タイプ
紀要論文
関連URL
http://www.okayama-u.ac.jp/user/est/homeJapan.html
言語
Japanese
論文のバージョン
publisher
査読
無し
Eprints Journal Name
fest