Memoirs of the Faculty of Engineering, Okayama University 9巻 2号
1974-12-25 発行
Torii Sigeru
Department of Industrial Chemistry
Uneyama Kenji
Department of Industrial Chemistry
Ishihara Masakazu
Department of Industrial Chemistry
This paper describes mass spectral data from synthetic
intermediates of linaloyl oxide. The fragmentation of sulfur functional groups including compounds l-8 would provide fruitful evidences for structural assignment of acyclic and alicyclic monoterpenoid precursors. Since, 1,3-dithianyl group in l,2, and 3 can provide a base peak and the elimination of the sulfinyl group from 7 and 8 is considered to occur at the initial stage of the fragmentation.