| ID | 61271 |
| フルテキストURL | |
| 著者 |
Chen, Qiang
Graduate School of Natural Science and Technology, Okayama University
Fu, Liyan
Graduate School of Natural Science and Technology, Okayama University
You, Jingwen
Graduate School of Natural Science and Technology, Okayama University
Nishihara, Yasushi
Research Institute for Interdisciplinary Science, Okayama University
ORCID
Kaken ID
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| 抄録 | Nickel-catalyzed decarbonylative alkynylation of acyl fluorides with terminal silylethynes under copper-free conditions is described. This newly developed method has a wide substrate scope, affording internal silylethynes in moderate to high yields. The formation of 1,3-diynes as homocoupled products and conjugate enones as carbonyl-retentive products were effectively suppressed.
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| キーワード | nickel catalysis
decarbonylation
silylalkynes
alkynylation
acyl fluorides
sila-Sonogashira–Hagihara reaction
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| 備考 | This is an Accepted Manuscript of an article published by Thieme Gruppe.
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| 発行日 | 2020-10-28
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| 出版物タイトル |
Synlett
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| 出版者 | Thieme Gruppe
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| ISSN | 0936-5214
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| NCID | AA10731110
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| 資料タイプ |
学術雑誌論文
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| 言語 |
英語
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| OAI-PMH Set |
岡山大学
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| 著作権者 | © 2020. Thieme.
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| 論文のバージョン | author
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| DOI | |
| Web of Science KeyUT | |
| 関連URL | isVersionOf https://doi.org/10.1055/s-0040-1705954
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