| ID | 58409 |
| フルテキストURL | |
| 著者 |
Murai, Masahito
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
ORCID
Kaken ID
publons
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Uemura, Erika
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Takai, Kazuhiko
Division of Applied Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
ORCID
Kaken ID
publons
researchmap
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| 抄録 | Amines have been identified to greatly accelerate the intermolecular anti-Markovnikov addition of carbon nucleophiles to unactivated terminal alkynes. Using a combination of [ReBr(CO)3(thf)]2 and iPr2NEt, construction of cyclic all-carbon quaternary centers was achieved with various 1,3-ketoesters, diketones, and diesters with lower catalyst loading under milder conditions. The type of addition could be easily controlled by choice of additive, highlighting the unique features of rhenium catalysis
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| キーワード | rhenium
anti-Markovnikov addition
1,3-dicarbonyl compound
vinylidene
amine
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| 発行日 | 2018-05-04
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| 出版物タイトル |
ACS Catalysis
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| 巻 | 8巻
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| 号 | 6号
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| 出版者 | American Chemical Society
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| 開始ページ | 5454
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| 終了ページ | 5459
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| ISSN | 2155-5435
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| NCID | AA12599706
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| 資料タイプ |
学術雑誌論文
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| 言語 |
英語
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| OAI-PMH Set |
岡山大学
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| DOI | |
| Web of Science KeyUT | |
| 関連URL | isVersionOf http://dx.doi.org/10.1021/acscatal.8b01338
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| 助成機関名 |
文部科学省
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| 助成番号 | 26248030
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