ID | 34217 |
フルテキストURL | |
著者 |
Asaji, Tetsuo
Department of Chemistry, Graduate School of Integrated Basic Sciences, College of Humanities and Sciences, Nihon University
Ishida, Hiroyuki
Department of Chemistry, Faculty of Science, Okayama University
Kaken ID
publons
researchmap
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抄録 | The crystal structures in two solid phases, i.e. phase II stable between 146 and 253 K and phase IV below 136 K, of the title compound [phenazine-chloranilic acid (1/1), C12H8N2 center dot C6H2Cl2O4, in phase II, and phenazinium hydrogen chloranilate, C12H9N2+center dot C6HCl2O4-, in phase IV], have been determined. Both phases crystallize in P2(1), and each structure was refined as an inversion twin. In phase II, the phenazine and chloranilic acid molecules are arranged alternately through two kinds of O-H center dot center dot center dot N hydrogen bonds. In phase IV, salt formation occurs by donation of one H atom from the chloranilic acid molecule to the phenazine molecule; the resulting monocation and monoanion are linked by N-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds.
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備考 | Digital Object Identifer:10.1107/S0108270106049468
Published with permission from the copyright holder. This is the institute's copy, as published in the ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, Jan 2007, Volume 63, Pages 17-20. Publisher URL:http://dx.doi.org/10.1107/S0108270106049468 Direct access to Thomson Web of Science record Copyright © 2007 International Union of Crystallography |
発行日 | 2007-01
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出版物タイトル |
Acta Crystallographica Section C
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巻 | 63巻
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号 | 1号
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出版者 | Blackwell Publishing
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開始ページ | o17
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終了ページ | o20
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ISSN | 0108-2701
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NCID | AA10631943
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資料タイプ |
学術雑誌論文
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言語 |
英語
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著作権者 | © 2007 International Union of Crystallography
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論文のバージョン | author
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査読 |
有り
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DOI | |
Web of Science KeyUT | |
Submission Path | crystallography/1
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