Measurement of saturated solubilities and diffusion coefficients of pure gases to mineral oil

The present paper deals with measurements of the diffusion coefficients as well as the saturated solubilities of single component gases such as N(2), O(2) and CO(2) to a mineral oil. The method to determine the diffusivity is based upon measuring the pressure changes caused by the one-dimensional diffusion between the gas and the oil enclosed in an airtight container. For N(2) and O(2) the profiles of the measured pressure changes agree well with those predicted by diffusion theory, whereas that is not the case with CO(2). Although the reason why CO(2) does not seem to obey diffusion theory has yet to be studied, it may suggest the possibility that the diffusion coefficient varies with the pressure, considering that the range of pressure change in the diffusivity measurement was much obtained by this method fell within ±30% around the average. Moreover the solubility measurements have made clear that Henry's law holds true between the three pure gases and the oils tested, and that O(2) and CO(2) dissolve into the oil approximately two and ten times more, respectively, than N(2).