このエントリーをはてなブックマークに追加
ID 55377
FullText URL
Author
Iwasaki, Masayuki Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University
Topolovčan, Nikola Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University
Hu, Hao Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University
Nishimura, Yugo Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University
Gagnot, Glwadys Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University
nakorn, Rungsaeng Na Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University
Yuvacharaskul, Ramida Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University
Nakajima, Kiyohiko Department of Chemistry, Aichi University of Education
Nishihara, Yasushi Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University
Abstract
Palladium-catalyzed carbothiolation of terminal alkynes with azolyl sulfides affords various 2-(azolyl)alkenyl sulfides with perfect regio- and stereoselectivities. The present addition reaction proceeded through a direct cleavage of carbon-sulfur bonds in azolyl sulfides. The resulting adducts that are useful intermediates in organic synthesis are further transformed to multisubstituted olefins containing azolyl moieties.
Note
This is an Accepted Manuscript of an article published by American Chemical Society
Published Date
2016-03-21
Publication Title
Organic Letters
Volume
volume18
Issue
issue7
Publisher
American Chemical Society
Start Page
1642
End Page
1645
ISSN
1523-7060
NCID
AA11347843
Content Type
Journal Article
language
英語
OAI-PMH Set
岡山大学
Copyright Holders
https://creativecommons.org/licenses/by-nc-nd/4.0/deed.ja
File Version
author
PubMed ID
DOI
Web of Sience KeyUT
Related Url
https://doi.org/10.1021/acs.orglett.6b00503