ID | 62037 |
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Kurimoto, Yuji
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Yamashita, Jun
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
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Mitsudo, Koichi
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
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Sato, Eisuke
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Suga, Seiji
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
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Abstract | The first electrochemical synthesis of diarylphosphole oxides (DPOs) was achieved under mild conditions. The practical protocol employs commercially available and inexpensive DABCO as a hydrogen atom transfer (HAT) mediator, leading to various DPOs in moderate to good yields. This procedure can also be applied to the synthesis of six-membered phosphacycles, such as phenophosphazine derivatives. Mechanistic studies suggested that the reaction proceeds via an electro-generated phosphinyl radical.
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Note | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.1c00807 .
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Published Date | 2021-04-05
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Publication Title |
Organic Letters
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Volume | volume23
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Issue | issue8
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Publisher | American Chemical Society (ACS)
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Start Page | 3120
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End Page | 3124
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ISSN | 1523-7060
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NCID | AA11347843
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Content Type |
Journal Article
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language |
English
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OAI-PMH Set |
岡山大学
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File Version | author
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Related Url | isVersionOf https://doi.org/10.1021/acs.orglett.1c00807
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Funder Name |
Japan Society for the Promotion of Science
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助成番号 | JP18J21360
JP19K05477
JP19K05478
JP18H04455
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