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ID 48102
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Author
Shiraga, Takuya
Mizukawa, Jun-ichi
Tanaka, Hideo
Abstract
An electro-oxidative method for generating silver acetylides from acetylenes with a Ag anode was developed. The reaction could be integrated into a Pd-catalysed electrochemical Sonogashira-type reaction. In the presence of the catalytic amount of Pd(OAc)(2) and 4-BzO-TEMPO, electro-generated silver acetylides reacted immediately with arylboronic acids to afford the corresponding coupling adducts in high yields.
Published Date
2010
Publication Title
Chemical Communications
Volume
volume46
Issue
issue48
Publisher
Royal Society of Chemistry
Start Page
9256
End Page
9258
ISSN
1359-7345
NCID
AA11071130
Content Type
Journal Article
Project
Research Center of New Functional Materials for Energy Production, Storage, and Transport
language
英語
Copyright Holders
© The Royal Society of Chemistry 2010
File Version
author
Refereed
True
DOI
Web of Sience KeyUT