JaLCDOI 10.18926/19624
FullText URL Mem_Fac_Eng_OU_31_1_11.pdf
Author Zhang Chunxiao| Tanigawa Satoshi| Uchida, Tetsuya| Shimamura, Kaoru|
Abstract Poly[(benzo[1,2-d:5,4-d']bissthiazole-2,6-diyl)-1,4-phenylene](cis-PBZT)with a relatively high molecular weight was prepared by a new synthesis route. Properties of the synthesized polymer, such as thermostability, liquid crystallinity etc. were investigated and compared with those of trans-PBZT. cis-PBZT was crystallized from dilute solution and the electron microscopy showed that the precipitate was a rod-like crystal similar to that of trans form. In spite of rigid nature of the back bone, cis-PBZT showed poor crystallinity.
Publication Title Memoirs of the Faculty of Engineering, Okayama University
Published Date 1996-12-27
Volume volume31
Issue issue1
Start Page 11
End Page 17
ISSN 0475-0071
language 英語
File Version publisher
NAID 120002309203
JaLCDOI 10.18926/19622
FullText URL Mem_Fac_Eng_OU_31_1_5.pdf
Author Shimamura, Kaoru| Zhang Chunxiao| Uchida, Tetsuya|
Abstract Rigid polymer poly(p-phenylene benzobisthiazole) was crystallized from dilute solution. Electron microscopy showed that upon quenching, flat fibrils with several nm thick were produced. Subsequent heat treatment in solvent changed the fibril into "shish-kebab". On the other hand, by isothermal crystallization, an aggregate of parallel rod-like crystals was obtained. The molecular chains were accommodated normal to the rod. Based on the observation of crystal morphology, the isothermal crystallization mechanism was proposed. Because of regidity of polymer chains and wide distribution of the molecular length, the chain ends were inevitably included within the crystals resulting in crystal defects such as axial shift, lattice curvature and edge dislocation which were directly observed by lattice imaging.
Publication Title Memoirs of the Faculty of Engineering, Okayama University
Published Date 1996-12-27
Volume volume31
Issue issue1
Start Page 5
End Page 10
ISSN 0475-0071
language 英語
File Version publisher
NAID 120002309167