ID 61271
Author
Chen, Qiang Graduate School of Natural Science and Technology, Okayama University
Fu, Liyan Graduate School of Natural Science and Technology, Okayama University
You, Jingwen Graduate School of Natural Science and Technology, Okayama University
Nishihara, Yasushi Research Institute for Interdisciplinary Science, Okayama University ORCID Kaken ID publons researchmap
Abstract
Nickel-catalyzed decarbonylative alkynylation of acyl fluorides with terminal silylethynes under copper-free conditions is described. This newly developed method has a wide substrate scope, affording internal silylethynes in moderate to high yields. The formation of 1,3-diynes as homocoupled products and conjugate enones as carbonyl-retentive products were effectively suppressed.
Keywords
nickel catalysis
decarbonylation
silylalkynes
alkynylation
acyl fluorides
sila-Sonogashira–Hagihara reaction
Note
This fulltext is available in Oct. 2021.
Published Date
2020-10-28
Publication Title
Synlett
Publisher
Thieme Gruppe
ISSN
0936-5214
NCID
AA10731110
Content Type
Journal Article
language
英語
OAI-PMH Set
岡山大学
Copyright Holders
© 2020. Thieme.
File Version
author
DOI
Web of Science KeyUT
Related Url
isVersionOf https://doi.org/10.1055/s-0040-1705954