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ID 19967
Eprint ID
19967
FullText URL
Author
Wada Eiko
Motomizu, Shoji
Abstract
A simple, sensitive and separative method for the photometric determination of inorganic anions was developed on the basis of suppressed electroosmosis by using a common silica capillary and a simple migrating solution. During the analysis of analyte anions by capillary zone electrophoresis, electroosmotic flow in a silica capillary was suppressed by using low-pH migrating solutions containing sodium sulfate. The stacking effect of sulfate ion was utilized for analyte concentration. Four kinds of inorganic analyte anions examined were detected in sharp signals, and the separation of a nitrate and a nitrite ion was improved by using the low-pH migrating solution with no decrease in detection sensitivity. Calibration graphs for nitrate and nitrite ions showed good linearity in the concentration ranges from about 10(-5) to 10(-4)mol dm(-3), with the detection limit for nitrate ion 4×10(-6)mol dm(-3). Separations of organic anions, such as aromatic sulfonate and carboxylate ions, were also examined; many of them were well separated by the proposed migrating solution. Those organic anions did not interfere with the determination of the inorganic anions.
Keywords
Capillary zone electrophoresis
inorganic anion
direct photometric detection
suppressed electroosmosis
stacking effect
Published Date
1996-08-10
Publication Title
Analytical Sciences
Volume
volume12
Issue
issue4
Publisher
日本分析化学会
Publisher Alternative
Japan Society for Analytical Chemistry
Start Page
575
End Page
579
ISSN
0910-6340
NCID
AA10500785
Content Type
Journal Article
Official Url
http://www.journalarchive.jst.go.jp/english/jnlabstract_en.php?cdjournal=analsci1985&cdvol=12&noissue=4&startpage=575
language
英語
Copyright Holders
日本分析化学会
File Version
publisher
Refereed
True
DOI